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乙酰基

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3-Nitrodiphenylamine is generally synthesized by the Ullmann condensation of N-(3-nitrophenyl) acetamide with bromobenzene.

摘 要:间-乙酰氨基硝基苯与溴苯发生Ullmann缩合反应是制备3-硝基二苯胺最常用的方法。

We provide intermediates of Methylphenidate HCl: 2-Phenyl-2-(2-Piperidyl) Acetamide; 2-Phenyl-2-(2-Piperidyl) Acetic Acid; Series of Benzoic Acid、Benzonitrile; Other pharmaceutical intermediates.

提供盐酸利他林中间体:2-苯基-2-(2-哌啶基)乙酰胺;2-苯基-2-(2-哌啶基)乙酸;苯甲酸、苯甲腈系列及其他医药中间体。

It crystallizes in the monoclinic space group C2/c, with a=1.6953(3)nm, b=1.9241(4)nm, c=1.7760(4)nm,β=94.75(3)°. Each Gd ion is coordinated by two oxygen atoms from two different radicals NITPh(OCH3)3 and six oxygen atoms from three hfac molecules to form eight-coordinated dodecahedron geometry.

Gd离子采取八配位的模式,两个氮氧自由基作为单齿端基配体分别以氮氧基团的氧原子与Gd离子配位,三个六氟乙酰丙酮阴离子分别以两个氧原子与Gd离子配位,构成十二面体。

In this report, the 59Tc labelling of Annexin V fragment modified with HYNIC (HYNIC-Anx13) using Tricine, EDDA or EDDA/Tricine as coligands was described. The effect of various factors on 99Tc labelling was investigated. Biodistribution studies in normal mice and gamma imaging of apoptosis in rats induced by cyclophosphamide were performed.

为探讨99Tc标记的HYNIC-Anx13用于细胞凋亡显像的可能性,分别以N-[三甲基]甘氨酸,乙二胺-N,N'-二乙酸和EDDA/Tricine为协同配体,对经6-肼基烟酰基修饰的膜联蛋白V片段(HYNIC-Anx13)的99Tc标记条件和主要影响因素进行了研究,并完成了HYNIC-Anx13的99Tc标记物在正常小鼠体内的生物分布和大鼠细胞凋亡模型的显像实验。

Glycoside of lectins was mainly composed of D-mannose, D-glucose and N-GlcNAc. However, Lec3 also contain some fucose.

研究表明三种凝集素的糖基主要由甘露糖,葡萄糖,N-乙酰氨基葡萄糖构成,Lec3糖基中还含有部分岩藻糖。

Our use Co2 as a catalyst in this work, exploring new way to produce nitrobenzoic acid from nitrotoluene under the prue oxygen in basic medium.

本文探讨了以乙酰丙酮钴为催化剂,分子氧为氧源,在NaOH-CH_3OH的反应环境下,氧化硝基甲苯制备硝基苯甲酸的新方法。

It starts with an aldol-type condensation in which a solution of the now commercially available E -[3-(4-fluorophenyl)-1-(1-methylethyl)-1 H-indol-2-yl]-2-propenal, 4 , 5 in THF is added to the preformed sodium-lithium salt of tert -butyl acetoacetate 5 at room temperature in THF.

它从一个醛型缩合其中一个解决现在的电子商业可-[3-(4-fluorophenyl)-1-(1-methylethyl)-1吲哚-2-基]-2-丙烯醛、4,5年增加了预四氢呋喃钠-锂盐叔丁基乙酰四氢呋喃在常温5。

He first synthesis of the precursor 45b of Tuxpanolide was accomplished fromβ-alkoxy aldehyde and β-acetoxy-γ-butyrolactone by the Aldol reaction.

uxpanolide的合成前体45b的首次不对称合成:以β-烷氧基开链醛和β-乙酰氧基-γ-丁内酯参与的Aldol醛醇缩合反应首次得到了前体化合物45b。

The first asymmetric synthesis of trans-β-hydroxy-γ-butyrolactones:-(3R, 4R, 5S)-4-(1-acetoxy-isopropyl)-3-hydroxy-butyrolactone 65a was achieved starting from isobutylaldehyde through nine steps. The key steps involve the construction of three chiral carbon centers by the Sharpless's asymmetric epoxidation and Substrate directable chemical reaction.

以异丁醛为起始原料,经过九步反应首次设计合成了具有三个手性中心的trans-β-羟基-γ-丁内酯:-(3R,4〓,5S)-4-(1-乙酰氧基-异丙基)-3-羟基-丁内酯65a,关键步骤是Sharpless不对称环氧化和底物定向不对称合成反应。

The second synthetic strategy commenced from butane-1,4-diol 50, which underwent monobenzylation, Swern oxidation, enolization followed by acetylation and debenzylation to yield an intermediate 46 in an overall yield of 54% in a 4-step procedure.

第二条路线从1,4-丁二醇50开始,这个化合物经过单苄基化、Swern氧化、烯醇化随后乙酰化和脱苄基化共4步反应得到中间体46,总产率54%。

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