乙酰基

The reaction of calcium L-threonate with hydrogen bromide in acetic acid readily yields (2S, 3S)-2, 4 -dibromo-3 -hydroxy butanoic acid which was further converted into methyl (2s, 3S)-2,4-dibromo-3-hydroxybutanoate by treatment of methanol.

在化合物12上引入氨基甲酰基可用二氯磷异氰酸酯、氯乙酰异氰酸酯或氯磺酰异氰酸酯，随之引入的二氯磷酰基、氯乙酰基或氯磺酰基可分别用碳酸氢钠、N-甲基二硫代氨基甲钠或亚硫酸钠脱去。

Through using Mythylene DinitrAmine as rude product, the knowledge of its reaction properties in different phases have been increased, Through using Mythylene BisAcetAmide as rude product, intermediates which include 1,3-Diacetyl -4,5-dihydroxy -1,3-diazacyclopentane and 1,3-Diacetyl- 4,5-diacetoxy-l,3-diaza cyclopentane have been obtained. 2,4,6,8-tetracetyl- 2,4,6,8-tetraaza bicyclo[3,3,0]octane which can be used to produce Bicyclo-HMX by nitrolysis was also produced. Through using Mythylene BisFormAmide as rude product, intermediates which include 1,3-Diformyl-4,5-dihydroxy- 1,3-diazacyclopentane and 1,3-Diformyl- 4,5-diacetoxy-l,3-diazacyclopentane have been abtained.

以亚甲基二硝胺为初始原料，加深了对亚甲基二硝胺在不同反应相反应特征的认识；以亚甲基二乙酰胺为初始原料，制备了中间体1，3-二乙酰基-4，5-二羟基-1，3-二氮杂环戊烷和1，3-二乙酰基-4，5-二乙酰氧基-1，3-二氮杂环戊烷，最终制备了可被直接硝解为双环HMX的2，4，6，8-四乙酰基-2，4，6，8-四氮杂双环[3，3，0]辛烷；以亚甲基二甲酰胺为初始原料，制备了中间体1，3-二甲酰基-4，5-二羟基-1，3-二氮杂环戊烷和1，3-二甲酰基-4，5-二乙酰氧基-1，3-二氮杂环戊烷。

Eight novel N,N′-naphthalene acyl substituted aromatic acylamino thiocarbamide s(Ⅱ1~Ⅱ8) were synthesized from aryl acylhydrazine and α-naphthalene acyl isothiocyanate, which was obtained by the reaction of potassium thiocyanate with α-naphthalene acyl chloride obtained from 2-naphthylacetic acid and thionyl chloride in anhydrous benzene.

通过α-萘乙酸和SOCl2在无水苯中反应制得α-萘乙酰氯，与硫氰酸钾反应生成α-萘乙酰基异硫氰酸酯，再与芳基酰肼进行加成反应，合成8种新型N，N′-萘乙酰基取代芳乙酰胺基硫脲类化合物(Ⅱ1～Ⅱ8)。

Formyl-3-acetyl-4-methyl-5-carbobenzoxypyrrole (6) was synthesized via the selective oxidation of 2,4-dimethyl-3-acetyl-5-carbobenzoxypyrrole (5), which was produced from acetylacetic benzylester (1) via nitrosation, reduction and addition-cyclization with acetylacetone. The total yield of the product was about 34%.

以乙酰乙酸苄酯(1)为原料，经过亚硝化、还原、与乙酰丙酮加成环化生成2， 4-二甲基－3-乙酰基－5-苄氧羰基吡咯(5)，通过选择性氧化反应制得目标化合物2-甲酰基－3-乙酰基－4-甲基－5-苄氧羰基吡咯(6)，反应的总收率约为34%。

Eight novel N,N′-naphthalene acyl substituted aromatic acylamino thiocarbamides(Ⅱ1~Ⅱ8) were synthesized from aryl acylhydrazine and α-naphthalene acyl isothiocyanate, which was obtained by the reaction of potassium thiocyanate with α-naphthalene acyl chloride obtained from 2-naphthylacetic acid and thionyl chloride in anhydrous benzene.

通过α-萘乙酸和SOCl2在无水苯中反应制得α-萘乙酰氯，与硫氰酸钾反应生成α-萘乙酰基异硫氰酸酯，再与芳基酰肼进行加成反应，合成8种新型N，N′-萘乙酰基取代芳乙酰胺基硫脲类化合物(Ⅱ1～Ⅱ8)。

In order to decrease toxicities of retinods and enhance pharmacal effects and gain the relative derivatives with better curing effect and selectivity, structures of retinoic acids were modified by inducing glycosyl groups in this paper.

方法一是在氢氧化钾存在下，以4-二甲氨基吡啶做相转移催化剂，将溴代-O-乙酰基葡萄糖(5a)、溴代-O-乙酰基木糖(5b)、溴代-O-乙酰基乳糖(5c)和溴代-O-乙酰基麦芽糖(5d)分别与异维A酸反应制得1-O-异维A酰-乙酰基单糖(6a，6b)和1-O-异维A酰-乙酰基二糖(6c，6d)，收率为53～65%。

In this paper, the improvement of synthetic method of 2-acetylaminotropone is introduced. 3-Acetyltropolone reacted with low concen-tration methylamine solution and solvent was directly evaporated in reduce pres-sure to give 2-acetyl-7 -methylaminotropone in good yield. The compound reacted with phenyltrimethylammonium tribromide to give two new compounds.

本文介绍2-乙酰基-7-甲胺基酮合成方法的改进——用挥发性小的低浓度甲胺溶液与3-乙酰基酚酮反应；和采用直接减压蒸除溶剂法分离产品，得到较好产率的2-乙酰基-7-甲胺基酮；用化合物与三溴化苯基三甲铵反应，得到两种至今未见文献报道的新化合物。

The synthesis of alkylcyclohexylbenzoic acid: take the synthesis of ethylcyclohexylbenzoic acid as a typical example. With the AlCl3 as the catalyst, cis+trans acetylcyclohexylbenzene is synthesized from the reaction of acetyl chloride, cyclohexene and benzene.

烷基环己基苯甲酸的合成研究：主要研究了乙基环己基苯甲酸的合成，以乙酰氯、环己烯、苯为原料，三氯化铝为催化剂，合成乙酰基环己基苯，用水合肼、氢氧化钾、一缩二乙二醇经过高温加热还原羰基(Wolff-黄鸣龙还原)，将所得到的乙基环己基苯用乙酰氯进行傅克酰基化得到乙基环己基苯乙酮，所得中间体经过处理之后直接得到反式产物，将反式异构体的乙酰基氧化得到反式烷基环己基苯甲酸。

Base played a crucial role in this reaction: in the Pd2/L1 catalyzed α-arylation of ethyl malonate, K3PO4 is the base of choice; in the α-arylation of ethyl acetoacetate, K2CO3 is the most effective base.

在这类催化反应中，碱的选择具有重要的影响：以K3PO4为碱， Pd2/L1催化体系在丙二酸二乙酯的α-芳基化中，富电子溴代芳烃显示较好的活性； Pd2/L1催化的乙酰乙酸乙酯α-芳基化时，以 K2CO3为碱，催化体系显示较好的活性，这个催化体系可控制反应得到α-芳基乙酰乙酸乙酯，而不是脱乙酰基的产物。

Base played a crucial role in this reaction: in the Pd2/L1 catalyzed α-arylation of ethy malonate, K3PO4 is the base of choice; in the α-arylation of ethyl acetoacetate, K2CO3 is the most effectiv base.

在这类催化反应中，碱的选择具有重要的影响：以K3PO4为碱，Pd2/L1催化体系在丙二酸二乙酯的α-芳基化中，富电子溴代芳烃显示较好的活性；Pd2/L1催化的乙酰乙酸乙酯α-芳基化时，以K2CO3为碱，催化体系显示较好的活性，这个催化体系可控制反应得到α-芳基乙酰乙酸乙酯，而不是脱乙酰基的产物。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。