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For the synthesis of NHC precursors, there are also several routes: condensation of glyoxal, amines and paraformaldehyde; alkylation of imidazole or monosubstituted imidazole with alkyl halide; annulation of ortho esters and 1,2-diamines; ring closure of hydrazines or amides with acetic anhydride; reduction of thiones with Na/K in THF.

关于N-杂环卡宾前体的合成途径主要有:乙二醛、伯胺和多聚甲醛的缩合反应;卤代烷与咪唑及其取代咪唑的烷基化反应;原甲酸酯与1,2-二胺的成环反应;肼或酰胺与酸酐的环化反应;用Na/K对环硫脲化合物的还原反应。

The composing of CPA is: 25% DMSO,17% formamide, 10% propane-1, 2-diol and 6% PEG.

联合玻璃化保护剂的组成为:25%DMSO、17%甲酰胺、10%1,2-丙二醇和6%聚乙二醇。

Past the kitchen, toilet use antibacterial, cleaning agents, basically trimer cyanuric chloride Department of halogenated compounds, the main components and to hydantoin as an active ingredient of two products.

以往厨房、厕所使用的抗菌、洗净剂,基本上是以氯化三聚异氰系化合物为主成分和以卤化乙内酰脲为有效成分的两种制品。

Benzyloxy benzoyldimethylsulfoxide was prepared by the reaction of ethyl 4-benzyloxybenzoate and dimethyl sulfoxide in the presence of sodium hydride, followed by Pummerer reaction with concentrated hydrochloric acid to afford eo-hydroxy-co-thio-methyl-(4/-benzyloxy) acetophenone, which reacted with urea, thiosemicarbazide, semicarbazide hydrochloride and o-phenylenediamine to give imidazolidine-2,4-dione, l,2,4-triazine-3- one and quinoxaline derivatives, respectively.

本文用4-苄氧基苯甲酸乙酯和二甲亚砜为原料,在氢化钠存在下反应,合成了(4′-苄氧基)-苯甲酰基-二甲亚砜。研究了该亚砜在浓盐酸的存在下发生的Pummerer重排反应,用重排产物ω-羟基-ω-甲硫基-(4′-苄氧基)-苯乙酮分别与尿素、氨基脲、氨基硫脲和邻苯二胺反应合成了2,4-咪唑啉-二酮、1,2,4-三嗪-3-酮、喹喔啉等含氮杂环化合物。

Monochloroethylene carbonate is prepared by chlorination of ethylene carbonate with sulfuryl chioride ,a solution of monochloroethylene carbonate in ethylene carbonate is reacted with triethylamine to give vinylene carbonate.A parameter design method was applied to select the optimum synthesis conditions.63.3% and 78% yields superior to the conventional for monochloroethylene carbonate and vinylene carbonate were obtained respectively,and the process was also simplified .

以碳酸乙烯酯为原料,用磺酰氯作为氯化剂生成一氯代碳酸乙烯酯,三乙胺为脱卤化剂在碳酸乙烯酯溶剂中合成碳酸亚乙烯酯,对一氯代碳酸乙烯酯和碳酸亚乙烯酯制备的工艺参数进行优化,收率分别达到63.3%和78%,均超过了传统方法,且简化了工艺,缩短了反应时间,易于工业化生产。

The enzymatic resolution of 1-phenylethylamine by amidation reaction in organic medium was studied.

在有机相中,对酶催化条件下的1-苯基乙胺酰胺化反应进行了研究。

The new surfactant was synthesized from the main starting materials such as lauric acid, p-cresol, chlorosulphonic acid and ethylene diamine, by 5 classic reactions which are acyl chlorination, esterification, Fries rearrangement, sulfonation and condensation, with total yield of 58%.

作者以十二酸、对甲酚、氯磺酸、乙二胺等为主要原料,共采取了酰氯化、酯化、Fries重排、磺化和缩合等5步经典的单元反应,合成了该表面活性剂,总收率为58%,并探讨了各步反应的条件对收率的影响。

In this paper several methods including acylamide dehydration, metal cyanide replacement, etherification and isoxazole method for synthesis of 3,3-diethoxyethylcyanide were reviewed.

综述了3,3-二乙氧基丙腈的合成方法,包括酰胺脱水、金属氰化物取代、醚化和异恶唑法,用于工业化生产较为满意的合成路线是以1,1,3,3-四乙氧基丙烷为原料的异恶唑法。

Dendrimers with stearyl groups on the periphery are synthesized by amidation using dendrihmers with NH2 on the periphery and stearyl chloride as raw materials.

以乙二胺和丙烯酸甲酯为原料,甲醇为溶剂,通过Michael加成及酰胺化反应,合成端基为胺基的树枝状大分子。

A series of ABEPS were synthesized from long chain fatty acids, benzene, polyglycol and 1, 3-propane sultone by the procedure of Friedel-Crafts acylation, Huang-Minlon reduction, Williamson and sulfonation reaction, and these compounds had never been reported in the past time.

以长链羧酸、苯、多缩乙二醇和丙烷磺内酯为初始原料,依次经Friedel-Crafts酰基化反应、Huang-Minlon还原、Blank反应、Williamson成醚以及磺化反应等过程,合成了系列未见报道的ABEPS。

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