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The enzyme assays indicated that Pseudomonas sp. ND6 NahG exhibits broad substrate specificities and metabolizes salicylate, acetylsalicylate, sulfosalicylate, 3-methylsalicylate, 5-methylsalicylate and 5 chlorosalicylate.

酶学实验表明,ND6菌株的水杨酸羟化酶具有广泛的底物特异性,它不仅能代谢水杨酸,还能代谢多种水杨酸的衍生物,如乙酰水杨酸、黄基水杨酸、3-甲基水杨酸、5-甲基水杨酸和5-氯水杨酸等。

In this paper, acetylsalicylic acid, cyclohexanone Preparation of micro-content of the experimental design, in different reaction conditions were carried out under analysis to optimize the improvements and chemical experiments on the basis of conventional experimental and micro-experimental comparison, being The experimental results consistent with the premise, fully reflects the micro-chemistry experiments to save time, save the amount of reagents, as well as many advantages such as reducing environmental pollution.

本文阐述了乙酰水杨酸、环己酮微型化制备实验的设计内容,在不同反应条件下进行了对照分析,从而进行优化改进,并就基础化学实验中常规实验与微型实验进行比较,在得到一致的实验结果的前提下,充分体现了微型化学实验节省时间、节省试剂用量、以及减少环境污染等诸多优点。

With the occurrence of H2/Pd-C and ethyl formic ester,the reduction of the nitro group and the formylation of the amino group could be finished in one step.

但是在甲酸乙酯存在下,用H2/Pd-C对Ⅶ的硝基进行还原,得到的Ⅷ中的氨基可当即被甲酰化,使由Ⅶ到Ⅳ的两步反应一步完成。

Permethylation analysis, periodate oxidation,Smith degradation, acetolysis and partial acid bydrolysis revealed the main chains of XP as mannose of (1-6)-linkages and its side chains were mannose of (1-2)linkages.

甲基化分析、过碘酸盐氧化、Smith降解、乙酰解和部分酸水解显示XP的主链是1→6连接的甘露糖,侧链是1→2连接的甘露糖。1H及13CNMR谱表明所有糖苷键均为a型,结合元素分析XP基本是酵母甘露多糖和蛋白质以及锌的络合物。

However, there is no difference for NAT2 rapid and slow acetylator between two groups.

吃红烧鱼因素在NAT2的快速酶中,特别是在野生纯合型中直肠腺瘤复发的相对危险度有增高趋势,提示了NAT2〓4等位基因编码快酶型NAT,可能在红烧鱼产生的杂环胺类化合物中代谢中加速其N-乙酰基化代谢过程,从而加速其代谢为终致癌物而与肠粘膜上皮细胞的DNA产生加成物,损伤其遗传物质。

Nevertheless, Smoking could interact with wild type of NAT2 and increase the relative risk of rectal adenoma recurrence significantly. It is suggested that NAT2 might involve the metabolism of pre-carcinogen generating from tobacco and alter the susceptibility of cancer. Meanwhile, the NAT2〓4 alleles encode rapid acetylator of NAT2 would increase the risk of adenoma recurrence among those high-risk people with habit of fried fish intake.

吃红烧鱼因素在NAT2的快速酶中,特别是在野生纯合型中直肠腺瘤复发的相对危险度有增高趋势,提示了NAT2〓4等位基因编码快酶型NAT,可能在红烧鱼产生的杂环胺类化合物中代谢中加速其N-乙酰基化代谢过程,从而加速其代谢为终致癌物而与肠粘膜上皮细胞的DNA产生加成物,损伤其遗传物质。

A process for the carbonylation of allylic butenyl ether (for example, methyl crotyl ether, 3-methoxybutene-1 and mixtures thereof) or mixture of butadiene and alcohol and production of beta-gamma unsaturated carboxylic acid esters (for example, methyl-3-pentenoate) utilizing a rhodium-containing catalyst for example, dicarbonylacetylacetonate rhodium(I or the like promoted with an iodide-containing compound (for example, HI, AlI3, SnI4, TiI4, CrI3, and CoI2 or the like).

一种将烯丙型丁烯基醚(如甲基巴豆基醚、3-甲氧基丁烯-1及其混合物)或者丁二烯与醇的混合物羰基化的方法,以及由含碘化物化合物(如HI、AlI3、SnI4、TiI4、CrI3和CoI2或等效物)促进,用含铑催化剂如二羰基乙酰丙酮酸铑(I或其等效物制备β-γ不饱和羧酸酯(如甲基-3-戊烯酸酯)的方法。

Paraacetaminophenyl-β-hydroxyethylsulfone can be used as raw material to produce the target product 2-sulfonic-4-(β-sulphatoethyl-sulphone) phenylamine through sulfonationating and hydrolytic reactions.

本文研究了以对乙酰氨基苯基-β-羟乙基砜为原料,经磺化和水解反应,制得产品2-磺酸-4-苯胺的合成工艺,以及2-磺酸-4-乙基砜基硫酸酯苯胺钠盐后处理的最佳操作工艺。

Keratin mutation predisposes to mouse liver fibrosis and unmasks differential effects of the carbon tetrachloride and thioacetamide models.

角蛋白突变诱发小鼠肝脏纤维化,揭示四氯化碳和硫代乙酰胺模型的的差别效应

Treatment of sucrose alkyl 4,6-orthoacetate hexaacetates I with water or alcohol in the presence of an acid catalyst afforded derivatives of sucrose acetates by selectively blocking specific hydroxyl group in sucrose and acetyl migration.

4,6-原乙酸蔗糖六乙酸酯在酸催化下水解和醇解,选择性地保护了蔗糖分子中的某些羟基,并通过乙酰基由C~4→C~6迁移的异构化反应合成了一系列蔗糖乙酸酯。

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这一模式非常关注商人的网络信用基础。

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