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乙酰化

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The acetated and hydrogenated urushiol dimer has been separated,and studied by hetero-J resolved 2D-NMR,homo- and heteronuclearchemical shift correlation 2D-NMR and long-range coupled chemicalshift correlation 2D-NMR.The results show that the urushiol dimerare most diphenyl and alkyl phenyl ether structures.Furthermore,IR and MS data also has conformed this structures.

本文将酶催化预聚后的生漆,催化加氢后,乙酰酯化,再进行离心旋转薄层层析,分离得到二聚体主要组分,用异核J分辨谱,同核化学位移相关,异核化学位移相关,远程偶合异核化学位移相关等2D—NMR技术,全面研究了其结构,得到了联苯型和烷基芳醚型聚合结构的结论。

Permethylation analysis, periodate oxidation,Smith degradation, acetolysis and partial acid bydrolysis revealed the main chains of XP as mannose of (1-6)-linkages and its side chains were mannose of (1-2)linkages.

甲基化分析、过碘酸盐氧化、Smith降解、乙酰解和部分酸水解显示XP的主链是1→6连接的甘露糖,侧链是1→2连接的甘露糖。1H及13CNMR谱表明所有糖苷键均为a型,结合元素分析XP基本是酵母甘露多糖和蛋白质以及锌的络合物。

However, there is no difference for NAT2 rapid and slow acetylator between two groups.

吃红烧鱼因素在NAT2的快速酶中,特别是在野生纯合型中直肠腺瘤复发的相对危险度有增高趋势,提示了NAT2〓4等位基因编码快酶型NAT,可能在红烧鱼产生的杂环胺类化合物中代谢中加速其N-乙酰基化代谢过程,从而加速其代谢为终致癌物而与肠粘膜上皮细胞的DNA产生加成物,损伤其遗传物质。

Nevertheless, Smoking could interact with wild type of NAT2 and increase the relative risk of rectal adenoma recurrence significantly. It is suggested that NAT2 might involve the metabolism of pre-carcinogen generating from tobacco and alter the susceptibility of cancer. Meanwhile, the NAT2〓4 alleles encode rapid acetylator of NAT2 would increase the risk of adenoma recurrence among those high-risk people with habit of fried fish intake.

吃红烧鱼因素在NAT2的快速酶中,特别是在野生纯合型中直肠腺瘤复发的相对危险度有增高趋势,提示了NAT2〓4等位基因编码快酶型NAT,可能在红烧鱼产生的杂环胺类化合物中代谢中加速其N-乙酰基化代谢过程,从而加速其代谢为终致癌物而与肠粘膜上皮细胞的DNA产生加成物,损伤其遗传物质。

In the bromization reaction of LA,the reaction conditions such as reaction temperature,drop time of Br_2 and reaction medium were optimized.

以来源于生物质资源的乙酰丙酸为原料,通过改进的溴化和水解反应合成了5-HLA。

Universal indicator paper,special indicator paper,ammonium fluoride,ammonium hydrogen difluoride,nbenzyldimethylamine,disinfectant paper,nacetylphenylhydrazine,mcresol purple,bromocresol green,fluorescein,eosin Y,ninhydrin,phenedons,potassium phthalate,pamimobenzene sulphonic acid anhydrous.

广泛试纸,精密试纸,氟化铵,氟化氢铵,N苄基二甲胺,消毒试纸,N乙酰苯肼,间甲酚紫,溴甲酚绿,荧光素,曙红Y,水合茚三酮,菲尼酮S,苯甲酸氢钾,无水对氨基苯磺酸。

A process for the carbonylation of allylic butenyl ether (for example, methyl crotyl ether, 3-methoxybutene-1 and mixtures thereof) or mixture of butadiene and alcohol and production of beta-gamma unsaturated carboxylic acid esters (for example, methyl-3-pentenoate) utilizing a rhodium-containing catalyst for example, dicarbonylacetylacetonate rhodium(I or the like promoted with an iodide-containing compound (for example, HI, AlI3, SnI4, TiI4, CrI3, and CoI2 or the like).

一种将烯丙型丁烯基醚(如甲基巴豆基醚、3-甲氧基丁烯-1及其混合物)或者丁二烯与醇的混合物羰基化的方法,以及由含碘化物化合物(如HI、AlI3、SnI4、TiI4、CrI3和CoI2或等效物)促进,用含铑催化剂如二羰基乙酰丙酮酸铑(I或其等效物制备β-γ不饱和羧酸酯(如甲基-3-戊烯酸酯)的方法。

N-Carbobenzoxy-L-homoserinelactone was prepared via N-alkylation reaction of L-methionine and iodoacetamide with benzyl chloroformate as amino protecting agent.

以L-蛋氨酸为原料,氯甲酸苄酯为氨基保护试剂,与碘乙酰胺(I2微量)内酯化反应,合成N-苄氧羰基-L-高丝氨酸内酯。

AIM: To investigate the effect of PD98059, a specific repressor of extracellular signal regulated kinase1/2 (ERK1/2), on the proliferation of the murine lymphocytes. METHODS: Lymphocytes were isolated from lymphoid nodes of BALB/c mouse. After stained with carboxy fluorescein diacetate, succinimidyl ester, the cells were stimulated with polyclonal activators, concanavalin and phorbol 12,13 dibutyrate plus ionomycin.

分离小鼠淋巴结细胞,藉羧基荧光素乙酰乙酸染色,用多克隆刺激剂刀豆A蛋白或者佛波醇酯加离子霉素刺激,以流式细胞术分析PD98059对淋巴细胞增殖的影响;利用碘化丙锭染色分析PD98059对细胞周期的影响。

Objective To investigate the alterations in activity of N-acetyl-β-glucosaminidase in experimental hepatic fibrotic rats.

目的 研究肝纤维化大鼠模型N-乙酰-β氨基葡萄糖苷酶活性的变化及与羟脯氨酸和透明质酸的相关性。

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