乙酰化

Enzymatic synthesis of cefaclor from 7\|aminodesacetoxymethyl\|3\|chlorocephalosporanic acid (7\|ACCA) and phenylglycine derivatives using penicillin G acylase was studied.

以7-氨基去乙酰氧甲基-3-氯头孢烷酸(7-ACCA)和苯甘氨酸衍生物为底物，利用青霉素酰化酶酶促合成头孢克罗。

In this research, liposoluble chlorogenic laurate was synthesized by acylation with lauroyl chloride in the presence of triethylamine in non-water phase.

本研究对CGA进行了分子修饰，即在非水相中，以三乙胺为催化剂，对其进行月桂酰氯酰化，制备了脂溶性的绿原酸月桂酸酯。

Various reaction parameters such as ratio of ethyl acetoacetate to ethylene glycol,catalyst amount,reaction time and water-carrying reagent amount were studied.

讨论了酯醇比、催化剂用量、反应时间、带水剂用量对酯化率的影响。最佳反应条件为：n：n=1：1.8，催化剂用量为乙酰乙酸乙酯质量的2%，带水剂用量为20mL，反应时间3h。

The influence of reed produced allelopathy material eathyl-2-methyl acetoacetate on respiration action, photosynthesis action and antioxidant enzymes system of Microcystis aeroginosa were studied.

研究了芦苇产生的化感物质2-甲基乙酰乙酸乙酯对铜绿微囊藻呼吸作用、光合作用和抗氧化酶体系的影响。

School "of acetaminophen refined the process of acylation of the multimedia simulation design" system.

学院《对乙酰氨基酚的酰化精制过程的多媒体仿真设计》系统开发。

A series of 2-acetylformanilides were prepared,followed by thiolation with Lowesson reagent to afford 2-acetylthioformanilides,which further reacted with Mn3·2H2O in glacial acetic acid under microwave irradiation to afford 2-acetyl benzothiazole s.

合成了一系列的硫代酰胺，研究了它们在微波辐射醋酸锰作用下发生氧化自由基环化反应，成功地合成了一系列2-乙酰基苯并噻唑衍生物，其结构经红外光谱、核磁共振谱和质谱得到了证实

Subsequently,enol methylation of P in basic condition completed the synthesis of malyngamide O.Applied this route to the synthesis of malyngamides Q and R,the chiral unsaturated acid was connected with the vinyl chloride part by amidation,then the resulting product was converted into the corresponding aldehyde,followed by aldol condensation of the aldehyde with the chlorotitanium enolate of pyrrolidone to complete the skeleton of malyngamides Q and R,then the synthesis of them was completed via enol methylation in acid condition.

该合成路线拓展应用到malyngamides Q和R的合成时，首先用酰胺键将手性不饱和脂肪酸和烯氯片段连接，再转化成相应的醛，与乙酰基吡咯酮进行TiCl_4催化的aldol反应即得到malyngamides Q和R的骨架结构，再经过酸催化的烯醇甲基化反应完成了Q和R的全合成。

Methods: A model to evaluate lymphocyte proliferation stimulated with a polyclonal activator, concanavalin A, was established by vital dye carboxyl fluorescin diacetate succinmidyl ester labeling technique. Effects of the different doses of anisomycin on the lymphocyte proliferation were estimated by flow cytometry and MTT methods. The propidium iodide labeling technique was applied to assay the effect of the different doses of anisomycin on changes of the lymphocyte cell-cycle stimulated by ConA or by phorbol ester plus Ionomycin. The percentage of the expression level of CD69 and CD25 on the activated lymphocytes was evaluated by fluorescin-conjugated monoclonal antibody double labeling technique.

以活体染料羧基荧光素乙酰乙酸琥珀酰亚胺酯染色，建立在多克隆刺激剂刀豆蛋白A刺激下评价小鼠淋巴细胞增殖的模型，通过流式细胞术和MTT法分析茴香霉素在不同剂量下对淋巴细胞增殖的作用；采用碘化丙锭染色分析茴香霉素对ConA或佛波醇酯加离子霉素刺激的小鼠淋巴细胞周期变化的作用；利用荧光标记的单克隆抗体双染技术和流式细胞术观察茴香霉素对小鼠CD3~+T细胞早期及中期活化标志分子CD69和CD25表达的影响。

The intermediate which obtained from oximation of 7a-e reacted withmethyl N-(2-bromomethylphenyl)-N-methoxycarbamate to synthesize oxime ether methyl carbamate 3a-e.

以邻位卤代苯甲醛和3-丁烯-2-醇为原料通过钯催化&一锅法&反应合成了2-乙酰基茚7a-e，7a-e 肟化之后和N-(2-溴甲基苯基)-N-甲氧基氨基甲酸甲酯反应合成了肟醚类氨基甲酸甲酯3a-e，进一步胺解之后得到了肟醚类氨基甲酰甲胺3f-j。

To dye the different types of fibers by the same dye, universal dyes based on naphthalene ring system are prepared by the diazo coupling reaction of 7-acetamide-4-hydroxy-2-oaphtialene-β-(N,N-dimethylaminoethyl)solfonamide and m-aminobenzene-β-hydroxyethyl sulfone sulfunate.

为了实现用同一支染料对不同类型的纤维进行染色的目的，通过间氨基苯基－β-羟乙基砜硫酸酯与7-乙酰氨基－4-羟基－2-萘－β磺酰胺的重氮化偶合反应合成了含萘环的通用染料，其结构通过质谱分析进行了表征。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。