乙酰化

Results show that, by using thionyl chloride and N,N-dimethyl formamide as chlorinating reagent and dichloromethane as solvent and taking -15℃ as reaction temperature, Z-iomer crystals with pale white color and stable to temperature can be obtained with an overall yield of 70%.

以2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酸为原料，经盐酸化、氯代等反应合成了Z-2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酰氯盐酸盐；氯代时以用亚硫酰氯和N，N-二甲基甲酰胺的混合物代替五氯化磷作氯化剂，并考察了温度和溶剂对氯代产物中Z-异构体和E-异构体收率的影响。

The synthesis of l-(4-acetylaminophenyl)-2-bromo-1-propanone was discussed, and the mechanism and possible factors were analyzed. Hence the routine was determined, in which l-(4-acetylaminophenyl)- 1-propanone was reacted with Bromine dissolved in ethanol, so that the a -bromination can be carried on, resulted in the yield of up to 70.4%.

探讨了1-(4-乙酰胺基苯基)-2-溴代-1-丙酮的合成方法，分析了反应机理和影响因素，确定将1-(4-乙酰氨基苯基)-1-丙酮溶解在乙醇中以溴的乙醇溶液进行α-溴化的合成路线，产率可达70.4％。

The key intermediate 3-methylaminopiperidine was synthesized from 3-methylaminopyridine by two methods,formylation and lithium aluminium hydride reduction or condensation with triethyl orthoformate and sodium borohydride reduction,and then hydr...

以3-氨基吡啶为原料，分别通过甲酰化反应、氢化铝锂还原和原甲酸三乙酯缩合、硼氢化钠还原两种方法得到3-甲胺基吡啶，最后经催化氢化得到中间体3-甲胺基哌啶。

The key intermediate 3- methylaminopiperidine was synthesized from 3-methylaminopyridine by two methods, formylation and lithium aluminium hydride reduction or condensation with triethyl orthoformate and sodium borohydride reduction, and then hydrolysis.

以3-氨基吡啶为原料，分别通过甲酰化反应、氢化铝锂还原和原甲酸三乙酯缩合、硼氢化钠还原两种方法得到3-甲胺基吡啶，最后经催化氢化得到中间体3-甲胺基哌啶。

In order to supply basic thermodynamic data for the separation design of acetyl acetone from the isomerization reaction of isopropenyl acetate,vapor-liquid equilibrium data of isopropenyl acetate-acetyl acetone system under 101.3 kPa was measured using Ellis equilibrium still.

为了给乙酸异丙烯酯异构化生产乙酰丙酮工艺的产物分离设计提供基础热力学数据，用埃利斯平衡蒸馏器测定了101.3 kPa下乙酸异丙烯酯-乙酰丙酮体系的汽液平衡数据，结果表明，该二元体系未形成共沸物，实验数据通过了Herrington面积法的热力学一致性检验。

Fibrous hydrous zirconia, spinnable hydrous zirconia chelated by acetylacctone and modifiedhydrous zirconia were synthesized from zirconium oxychlorid(ZrOCl_2·8H_2O) and then applied toprepare ZrO_2/PVA electrospinning hybrid fibers, ZrO_2/PVA continuous hybrid fiber and ZrO_2/PVPhybrid microsphere respectively. The chemical structure, properties, microstructure and formationmechanism of the corresponding materials were investigated.

论文以无机盐ZrOCl_2·8H_2O为原料，合成出纤维状的ZrO_2水合物、乙酰丙酮配位的可纺性ZrO_2水合物和正丁醇改性的ZrO_2水合物，分别与PVA和PVP杂化复合，制备出ZrO_2／PVA杂化电纺纤维、ZrO_2／PVP杂化连续纤维和ZrO_2／PVP杂化微球，并对相关材料的组成、结构、性能及形成机理等进行了深入分析和研究。

It is found that when the molar ratio of sulphoxide,pyridine and acetyl bromide is 1∶0.6∶0.4,the catalytic effect on the ring-enlargment is the best,and the yield and purity of the final product can reach 76% and 97% respectively at a pH of 1.8 in toluene under refluxing for about 3.5h.

通过正交实验可得出以下结论：当N，N′-双脲-亚砜为2.5∶1，乙酰溴-亚砜为0.4∶1，吡啶-乙酰溴为1.5∶1，回流时间为3.5h，酸化pH值为1.8时，扩环反应结果最好，总收率可达76%，纯度97%以上。

A series of polys based on pyromellitic dianhydride, biphenylyl tetracarboxylic dianhydride, thiodiphthalic dianhydride bis benzene dianhydride and oxydiphthalic dianhydride were prepared in different solvents.

以所合成的AB_2单体为原料，合成了一系粘度较低、溶解性良好，带端酚羟基、苯甲酰基、乙酰基、氰代苯基和苯酰苯亚胺基的芳香族超支化聚酰亚胺，通过核磁波谱、红外光谱分析和元素分析对其结构进行确证。

acetyl chloride, a novel fluorescence derivatization reagent, has been developed for the determination of sterols and stanol .

采用荧光衍生化试剂2-(9-咔唑)乙酰氯，对天然产物谷甾醇、豆甾醇、菜油甾醇及谷甾烷醇的柱前衍生化条件，包括催化剂的种类、反应温度、衍生化时间等进行了考察，结果表明：催化剂选用三乙胺，反应温度80℃，时间20min，衍生产物具有恒定的最大检测响应值。

Four substances including 2-methyl ethyl acetoacetate and barley straw extract distilled from bulrush as well as cetyl trimethyl ammonium bromide and isothiazo lintone were used for the comparison experiment in inhibiting the growth of Microcystis aeruginosa in various phases. Result showed that inputting chemicals in the lag phase has better effect than in the log phase, and adding in lag phase can effectively inhibit the algae growth. Although feeding allelopathic substance at log phase can lead to certain restraining effect, it cannot result in the effective inhibition of algae growth, which can be well achieved by feeding CTAB and isothiazo lintone below 10mgl/L during log phase.

研究用从芦苇中提取的2-甲基乙酰乙酸乙酯和大麦秸浸出液两种化感物质以及十六烷基溴化钱和异噻唑啉酮等四种药剂对不同生长期的铜绿微囊藻进行了对比抑制试验，结果显示在铜绿微囊藻生长的迟缓期投加试验药剂效果比在对数期投加效果都好，在迟缓期投加四种药剂，都有很好的抑藻效果；在铜绿微囊藻生长的对数期投加化感物质，虽然有一定的抑藻率，但效果较差，而在藻对数期投加10mg/L以下的CTAB和异噻唑啉酮能达到很好的水华抑制效果。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。