乙酰化

The optimum reaction conditions are as follows: diphenylmethanethiol : methyl chloroacetate is 1:1.5, and the reaction carried out at 100℃ for 4 h, 2- acetamide can be carried out in the room temperature for 20 h, the yield of 2- acetamide was 76%, hydrogen dioxide: 2- acetamide is 1:1, and the reaction carried out at 60℃ for 3 h, the yield of modafinil was 79%, the total yield of reaction can be reached 48%.

研究表明，采用氯乙酸甲酯作为醚化试剂，反应时间4h，反应温度100℃，二苯甲硫醇：氯乙酸甲酯=1：1.5，室温下氨解反应20h，二苯甲硫乙酰胺收率76%；采用过氧化氢作为氧化试剂，反应时间3h，反应温度60℃，过氧化氢：二苯甲硫乙酰胺=1：l，莫达非尼收率79%，反应总收率可达48%。

In this thesis, a convenient and efficient synthesis of highly functionalizeddihydropyrido[2,3-d]pyrimidines via a double [5 + 1] annulation strategy startingfrom easily available α-alkenoyl-α-carbamoyl ketene--acetals 1 and cheapreagents (NH4OAc, DMF, and POCl3) has been developed.

本论文探索了一种简便有效的合成高度官能化的二氢吡啶并[2，3-d]嘧啶的方法，此方法由易得的α-乙酰基-α-氨基乙酰基二硫缩烯酮1和便宜的试剂(醋酸铵，二甲基甲酰胺和三氯氧磷)通过两步[5 + 1]加成而实现。

This reaction is catalyzed by the enzyme acetyl CoA carboxylase which has biotin as a prosthetic group, a common feature in CO2-binding enzymes.

乙酰CoA的羧化为不可逆反应，是脂肪酸合成的限速步骤，故乙酰CoA羧化酶的活性高低控制着脂肪酸合成的速度。

The activity of pyruvate carboxylase depends on the presence of acetyl CoA so that more oxaloacetate os made when acetyl CoA levels rise.

丙酮酸羧化酶的活性依赖于乙酰-CoA 的存在。因此，当乙酰-CoA，水平上升时，会产生更多的草酰乙酸。

Amino to acetyl phenol, in have technology of two kinds of production domestic and internationally, acetic anhydride craft of the United States, acyl changes temperature to have 75 ℃ only, acyl changes mother liquor not apply mechanically, deputy reaction is little, of production thick tasting is kind of white almost, purificatory craft is very simple, activated carbon dosage only 2~3%, the Kun that its product does not have glow material almost in different third alcohol inferior the sealed impurity of amine impurity and minim, settleclear lightness it may not be a bad idea, the product quality that acetic anhydride craft produces is good, but close rate low, cost is high.

对乙酰氨基酚，在国内外有两种生产工艺，美国的醋酐工艺，酰化温度只有75℃，酰化母液不套用，副反应少，生产的粗品几乎是类白色，精制工艺就非常简单，活性炭用量仅2~3%，其产品在异丙醇中几乎无红光物质的醌亚胺杂质及微量的未知杂质，澄明度也好，醋酐工艺生产的产品质量好，但收率低、成本高。

The synthesis of fructone from ethyl acetoacetate and ethylene glycol using sulfonated activated carbon as solid acid catalyst was investigated.

以活性炭磺化制得新型固体磺酸磺化炭为催化剂，对乙酰乙酸乙酯和乙二醇合成苹果酯的催化工艺进行了系统研究。

The first committed step in fatty acid biosynthesis is the carboxylation of acetyl CoA to form malonyl CoA using CO2 in the form of bicarbonate HCO3-.

在脂肪酸的从头合成过程中，参入脂肪酸链的二碳单位的直接提供者并不是乙酰CoA，而是乙酰CoA的羧化产物——丙二酸单酰CoA(malonyl-CoA)。

The α-monobromination of 2-pentone,4-methyl acetophenone,4-methoxyacetophenone,6-methoxy-2-acetylnaphthane,2,2,5,5-tetramethyl-3-hexanone,cyclooctanone,cyclododecanone with respectively,were studied.

研究了离子液体三溴化1-丁基-3-甲基咪唑[Br3]对2-戊酮、4-甲基苯乙酮、4-甲氧基苯乙酮、6-甲氧基-2-乙酰基萘、2，2，5，5-4-甲基-3-己酮、环辛酮、环十二酮、丁醛等羰基化合物的α-溴化反应。

The resultedα-methylamine was protected by acetyl chloride, and then was chlorosulfonated bychlorosulforic acid at -5℃-0℃followed by treatment with aqueous ammonia givingcompound A in 52.3% yield.

甲基胺再用乙酰基进行保护后，以HSO3Cl为试剂进行氯磺化反应，再用浓氨水进行反应，制得了乙酰基保护的苯磺酰胺类化合物。

Part I, the Friedel-Crafts acylation on DAA and methyl dehydroabietic acid was carried out with acetyl chloride, benzoyl chloride or phthalic anhydride as acylating regents, anh- ydrous aluminum chloride as catalyst and with different solvents to compare with, we have got t- hree new compounds.

第一部分，分别以脱氢松香酸和脱氢松香酸甲酯为底物，乙酰氯、苯甲酰氯、邻苯二甲酸酐为酰化试剂，无水三氯化铝作催化剂，采用不同的溶剂及反应条件进行傅克酰基化反应，得到3个新化合物。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。