乙酰丙酮

Keywords isopropenyl acetate;acetyl acetone;vapor-liquid equilibrium

乙酸异丙烯酯；乙酰丙酮；汽液相平衡

Results:There was no significant difference in mensuration between microwave disgestion-acetylacetone-formaldehyde spectrophotometry method and international standard Kjeldahl determination.

结果：微波消解-乙酰丙酮甲醛分光光度法与国标凯氏定氮法相比测定结果差异无显著性，该方法线性范围在5~100μg/10 m l，相关系数r=0.9997，检出限为0.546μg/10 m l，相对标准偏差为1.29%~2.21%，加标回收率

The graft copolymerization of vinyl monomer onto carbon black with,respectively,ceric ions, n butylithium,acetylacetonate copper complex and manganic pyrophosphate complex as initiator were studied.

讨论了分别在铈离子体系，正丁基锂体系，过渡金属离子乙酰丙酮铜以及焦磷酸络锰体系的作用下，炭黑与乙烯基单体的接枝聚合。

In the paper, a series of metallorganic compounds have been studied by the quantum-chemical calculation with proper basis sets, including:1. a series of carbonyl complexes.2. dibenzene chromium and its derivatives3. ferrocene and its derivatives4. a series of metallic complexes with acetylacetoneWe optimized the geometric configurations of a series carbonyl complexes including Ni4 Fe5, Cr6 with density functional theory B3LYP method at the different levels and confirmed the stable geometry by vibrational analyses. Then we calculated the nuclear magnetic resonance spectra with GIAO method provided by GAUSSION98 program at the different levels.

本文用量子化学计算程序，用密度泛函B3LYP方法，在恰当基组水平上，用GAUSSIAN98程序提供的GIAO方法研究了系列金属有机化合物的核磁共振谱：一、羰基配合物系列：二、二苯铬及其衍生物系列：三、二茂铁及其衍生物系列：四、乙酰丙酮的配合物系列：我们用密度泛函B3LYP方法，在不同基组水平上对第一过渡系羰基化合物的系列配合物进行了结构优化，通过振动分析确定其稳定构型，然后再用密度泛函B3LYP方法在不同基组水平上，用GAUSSIAN98程序提供的GIAO方法计算其核磁共振谱。

Catalytic oxidation ; p nitrotoluene ; p nitrobenzoic acid ; Co 2

催化氧化；对硝基甲苯；对硝基苯甲酸；乙酰丙酮钴

Octylene was synthesized via tetramerization of ethylene at the presence of a catalyst system consisted of chromium acaet as primary catalyst, methylaluminoxane as cocatalyst, bis amine as ligand under high pressure. The effects of different PNP ligands on catalyst activity and selectivity to 1-octene were investigated.

在乙酰丙酮铬、甲基铝氧烷、配体三元催化体系中，以乙烯为原料在高压下齐聚生成1-辛烯，主要考察N原子上取代基不同的PNP配体对催化剂活性及1-辛烯选择性的影响。

Serum total cholesterol was determined by isopropanol withdrawing and ferric-glacial acetic acid -sulfuric acid developing method, serum triglyecride by isopropanol withdrawing and acetylacetone developing method,serum high density lipoprotein-cholesterol by magnesium phosphotungstate mehod, respectively. Serum low density lipoprotein-cholesterol was calculated by the equation: LDL-C=TCh--0.2 TG.

采用异丙醇抽提、三氯化铁-冰醋酸-硫酸显色法检测血清总胆固醇，用异丙醇抽提、乙酰丙酮显色法检测血清甘油三酯，用磷钨酸镁法检测血清高密度脂蛋白-胆固醇，用等式LDL-C=TCh--0.2TG计算血清低密度脂蛋白-胆固醇。

With the in-situ single-stage self-metallization protocol,surface-silvered polyimide film has been prepared using pyromellitic dianhydride/ 4,4\'-oxydianiline-based polyimide as the matrix and (1,1,1-trifluoro-2,4-pentadionato)silveras the silver precursor.

在原位一步自金属化法中，以均苯四甲酸酐/4，4\'-二胺基二苯醚基聚酰亚胺为基体，以三氟乙酰丙酮银作为银的母体制备出了表面金属化的聚酰亚胺银复合薄膜。

The results show that the zirconium sol has good spinnability when n: n= 1:3, reaction time is 6h and aging temperature is 15℃. The ZrO_2precursor fibers are made from hydrous zirconia chelated by acetylacetone. The sintercd fibers arecomposed of metastable tetragonal phase and sized about 15μm in diameter. Moreover, there aremany pores inside the fibers, but no cracks.4. ZrO_2/PVP hybrid fibers were prepared by blending the spinnable zirconium sol and 10 wt%PVP solution.

结果表明，当n(ZrOCl_2·8H_2O)：n(H_2O_2)=1：3，反应时间6h，陈化温度15℃时可得纺丝性能良好的锆溶胶，ZrO_2前驱体连续纤维的组成主要为经乙酰丙酮配位的ZrO_2水合物，热处理后的ZrO_2纤维的相结构为亚稳四方相，纤维的直径为15μm左右，纤维中存在大量的纳米级气孔，但无明显裂纹。4。

Fibrous hydrous zirconia, spinnable hydrous zirconia chelated by acetylacctone and modifiedhydrous zirconia were synthesized from zirconium oxychlorid(ZrOCl_2·8H_2O) and then applied toprepare ZrO_2/PVA electrospinning hybrid fibers, ZrO_2/PVA continuous hybrid fiber and ZrO_2/PVPhybrid microsphere respectively. The chemical structure, properties, microstructure and formationmechanism of the corresponding materials were investigated.

论文以无机盐ZrOCl_2·8H_2O为原料，合成出纤维状的ZrO_2水合物、乙酰丙酮配位的可纺性ZrO_2水合物和正丁醇改性的ZrO_2水合物，分别与PVA和PVP杂化复合，制备出ZrO_2／PVA杂化电纺纤维、ZrO_2／PVP杂化连续纤维和ZrO_2／PVP杂化微球，并对相关材料的组成、结构、性能及形成机理等进行了深入分析和研究。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。