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In this paper, the synthesis of polyamide acid resin, with 4, 4′-diam-inodiphenyl ether and pyromellitic dianhyride as monomers and dimethylacetamide as solvent, is reported; the preparation of polyimide fiber from PAA resin by dry- spinning method is described; and the effects of various factors of operating conditions upon the mechanical properties of the fiber is discussed.

本文报导了用4,4′—二氨基二苯醚与苯均四酸酐作单体,在N,N′—二甲基乙酰胺溶剂中合成聚酰胺酸树脂,以及用该树脂经干纺法制备纤维和制备过程中各项参数对纤维力学性能的影响。

A HPLC method for determination of phenylephrine hydrochloride, paracetamol, caffeine anhydrous ,salicylamide and brompheniramine maleate in Liufenkamin tablets was established.

建立了HPLC法测定柳酚咖敏片中盐酸去氧肾上腺素、对乙酰氨基酚、无水咖啡因、水杨酰胺、马来酸溴苯那敏的含量。

Results After screening, 59 subtracted library clones were isolated which were specific for strain VIB72, and the DNA sequences of these clones were determined. Seventeen fragments showed high homology to the genes of known functions in other bacteria. This includes soluble lytic murein transglycosylase, mobilization protein, transposase (IS66), resistance-related protein (metallo-beta-lactamase and acetyltransferase family), toxin protein (DT-201 and alveicin A immunity protein), ATP-dependent endonuclease of OLD family like protein, SocE and GTP-binding protein HflX (high frequency of lysogenization).

通过对差减文库筛选,分离到59个对菌株VIB72的克隆,并对这些克隆的DNA序列进行了测定。17个基因片断与其它细菌的已知功能的基因有较高的同源性,其中包括可溶性溶胞壁质转糖基酶、转移蛋白MobA和MobC、转座子IS66、抑制相关蛋白(金属β-内酰胺酶和乙酰转移酶家族)、毒素蛋白(DT-201和alveicin A免疫蛋白)、与OLD 家族相似的ATP依赖性核酸内切酶以及SocE 和GTP结合蛋白HflX。

Benzoylated phenyl a - and B - 2 - thio - D - fructofuranosides were synthesized and coupled with protected sucrose acceptor to synthesize a - D - fructofuranoside - linkage stereospecifically by employing NIS/AgOTf as catalysts.

在果糖的合成研究中,合成了四苯甲酰基苯基果糖硫苷,并首次将其用作糖苷化反应的给体,在NIS/AgOTf的促进之下,与乙酰化保护的蔗糖受体反应,从而以高产率立体专一地合成了α构型的呋喃果糖苷。

The oxylated SEBS and acetylated SEBS were obtained byFriedel-Crafts reactions using the mild catalyst of 〓/〓 complex.

通过SEBS的草酰化及其产物的水解或SEBS的乙酰化及其产物的氧化可以得到单分散的羧化SEBS。

Respectively, glutamic acid derivatized β-CD has been synthesized with epoxy chloropropane as the intermediate, a water-insoluble yellow liquid was got after the acetylating of the by using acetic anhydride, which was used as a novel gas chromatographic CSP; A water-soluble β-CD polymer cross-linked with epoxy chloropropane has been synthesized, and the derivatives of β-CD polymer were synthesized by its alkylating and acetylating. The different β-CD derivatives were coated on silica capillary columns by dynamic method, the chromatographic properties and retention behaviors of the fused silica capillary columns were studied, the results showed that the β-CD derivatives had good stereoselectivity and separation results to some compounds, especially to various positional isomers and enantiomers.

本文还分别以环氧氯丙烷为中间体,合成了七{2,6-二-O-[3-(1,3-二羟基丙氨酸)]}-β-环糊精,再用醋酸酐将其乙酰化,得到了一种淡黄色粘稠液体,合成了一种新型的环糊精衍生物;以环氧氯丙烷作交联剂合成了一种水溶性的β-环糊精聚合物,再将其烷基化和酰基化,合成了β-环糊精聚合物的不同衍生物,用动态法将不同类型的β-环糊精衍生物涂渍在石英毛细管柱上,通过对所制备柱柱性能的测试和对一系列化合物的分离和保留行为的研究,结果表明所合成的β-环糊精衍生物对各类化合物,特别是对位置异构体和对映异构体具有较好的分离效果,显示了很强的立体选择性。

In the last reaction of the citric acid cycle, malate is dehydrogenated to regenerate the oxaloacetate necessary for the entry of acetyl-CoA into the cycle

在三羧酸循环的最后一个反应中,苹果酸脱氢重新生成草酰乙酸以供乙酰辅酶A进入循环所必需

They are insoluble in water, ethanol, methanol, acetone, chloroform and benzene, but soluble in DMA, DMF and DMSO.

它们溶于N,N-二甲基甲酰胺、N,N-二甲基乙酰胺和二甲基亚矾等溶剂,但不溶于水、乙醇、甲醇、丙酮、氯仿和苯。

To dye the different types of fibers by the same dye, universal dyes based on naphthalene ring system are prepared by the diazo coupling reaction of 7-acetamide-4-hydroxy-2-oaphtialene-β-(N,N-dimethylaminoethyl)solfonamide and m-aminobenzene-β-hydroxyethyl sulfone sulfunate.

为了实现用同一支染料对不同类型的纤维进行染色的目的,通过间氨基苯基-β-羟乙基砜硫酸酯与7-乙酰氨基-4-羟基-2-萘-β磺酰胺的重氮化偶合反应合成了含萘环的通用染料,其结构通过质谱分析进行了表征。

A plausible process of this reaction is as following: Aldehyde was in equilibrium with the enol form, aldehyde reacted with aniline catalyzed by 2,2,2-trichloroacetic acid to afford imine, the generated imine immediately reacted with enol to form intermediate via intramolecular cyclization.

我们发现一分子芳基叠氮和一分子三苯基磷反应生成一分子磷亚胺,后者与由两分子取代的苯氧乙酰氯原位生成的烯酮反应生成4-亚烷基-β-烷基-内酰胺,其串联过程涉及烯酮亚胺的形成及其与烯酮的[2+2]的环加成反应。

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