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乙酯基

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Methoxy sec-ethyl acetate, Ethyl acetate, Ethyl forate,α-Pinene,β-Pinene, Camphene, Junipene, Limonene, P-Cymene, Linalool and Terpinole are regarded as the key flavorous components, which result in the peculiar smell and taste in fruits of Rubus L..

综合分析表明,甲氧基次乙基乙酸酯、乙酸乙酯、甲酸乙酯、α-蒎烯、β-蒎烯、莰烯及桧烯、柠檬烯、对伞花烃、芳樟醇、萜品醇类等化合物是四种悬钩子类果实的主要香味成分。

From the reaction mechanism, which involved formation of benzodiazepinium ethoxycarbonylmethylate, the reaction mechanism, which involved formation of benzodiazepinium ethoxycarbonyl- methylate followed by cycloaddition reaction, was tentatively proposed.

通过研究反应过程中分离出的副产物反丁烯酸二乙酯III和4,5-二氢吡唑-3,4,5-三羧酸乙酯IV,初步提出了反应经过乙氧羰基甲基化苯并二氮杂卓翁中间体V再发生环加成反应的机制。

Benzyloxy benzoyldimethylsulfoxide was prepared by the reaction of ethyl 4-benzyloxybenzoate and dimethyl sulfoxide in the presence of sodium hydride, followed by Pummerer reaction with concentrated hydrochloric acid to afford eo-hydroxy-co-thio-methyl-(4/-benzyloxy) acetophenone, which reacted with urea, thiosemicarbazide, semicarbazide hydrochloride and o-phenylenediamine to give imidazolidine-2,4-dione, l,2,4-triazine-3- one and quinoxaline derivatives, respectively.

本文用4-苄氧基苯甲酸乙酯和二甲亚砜为原料,在氢化钠存在下反应,合成了(4′-苄氧基)-苯甲酰基-二甲亚砜。研究了该亚砜在浓盐酸的存在下发生的Pummerer重排反应,用重排产物ω-羟基-ω-甲硫基-(4′-苄氧基)-苯乙酮分别与尿素、氨基脲、氨基硫脲和邻苯二胺反应合成了2,4-咪唑啉-二酮、1,2,4-三嗪-3-酮、喹喔啉等含氮杂环化合物。

The main products are: phosphorous trichloride 300,000 tons / year, phosphorus oxychloride 100,000 tons / year, phosphorus pentachloride 50,000 tons / year, 10,000 tons trichloroisocyanuric parathion / year chloromethyl ether 5000 tons / year, triethyl phosphite 10,000 tons / year, triphenyl phosphite 5000 tons / year, three phosphoric acid ethyl butoxy 2000 tons / year.

主要产品有:三氯化磷30万吨/年、三氯氧磷10万吨/年、五氯化磷5万吨/年、三氯硫磷1万吨/年、氯甲基甲醚5000吨/年、磷酸三乙酯10000吨/年、磷酸三苯酯5000吨/年、磷酸三丁氧基乙酯2000吨/年。

From Cacalia deltophylla (collected from Luqu County, Gansu Province), 22 compounds were isolated, of which 15 compounds have been identified. Among them, two compounds are new. They are named as 3-methyl-4-hydro-8-acetyl-furanonaphth-9-one and 1hydroxy-2-methoxy-3-acetyl-4, 8-dimethyl-5, 8-dihydro-naphthalene.

从采自甘肃省碌曲县的三角叶蟹甲草全草的甲醇提取物的石油醚部分和乙酸乙酯部分中,采用同样方法分离得到22个化合物,鉴定了其中的15个化合物,其中有2个为新化合物,分别命名为3-甲基-4-氢-8-乙酰基-呋喃萘-9-酮(2)和1-羟基-2-甲氧基-3-乙酰基-4,8-二甲基-5,8-二氢-萘(3)。

Analyse and compare what adopt a variety of pair of methods, the Michael addition reaction of ester of acerbity second of second of hydroxyl of protection of benzyl of the response of close nucleus addition that uses second nitrile and ester of formic acid second certainly, chloridize, cyanogen, reaction that take off carboxyl generates 3- benzyl oxygen radical the fifth of the ten Heavenly Stem the method of 2 nitrile, detailed discussion the action that wait and the by-product that arise possibly reach the reactant in each pace reaction, activator, dissolvent avoid a method.

通过对多种方法的分析和比较,确定采用乙腈和甲酸乙酯的亲核加成反应、氯化苄保护羟基、氰乙酸乙酯的Michael加成反应、脱羧反应生成3-苄氧基戊二腈的方法,并具体的讨论了每一步反应中反应物、催化剂、溶剂等的功能和可能产生的副产物及避免方法。

In this paper, the applications of the environmental friendly solid acid catalysts for esterification were studied and the activities of these catalysts were discussed, by which the solid acid ferric sulfate x-hydrate was used first as catalyst in the synthesis of dimethyl fumarate and ethyl chloroacetate and solid super acid SO42-/Fe2O3 was used first as catalyst in the synthesis of ethyl p-nitrobenzoate.

本文研究了对环境友好的固体酸催化剂在酯化反应中的应用,首次以固体酸Fe_2(SO_4)_3·xH_2O为催化剂合成了新型防霉剂富马酸二甲酯和化工原料氯乙酸乙酯,以固体超强酸5O_4~(2-)/Fe_2O_3为催化剂合成了医药中间体对硝基苯甲酸乙酯,并探讨了这些催化剂的催化活性。

In this catalyst system, the Knoevenagel condensations of a series of aromatic aldehydes with malononitrile or ethyl cyanoacetate were programmed and a mechanism was postulated as well. When aromatic aldehydes reacted with ethyl cyanoacetate, the corresponding alkenes proved to be E-isomers by 1H NMR.

在该反应体系中考察了一系列芳香醛和丙二氰、氰基乙酸乙酯的缩合反应,并推测了Knoevenagel缩合反应的机理,芳香醛与氰基乙酸乙酯缩合产物经1H NMR检测为E式烯烃。

Bromo-5-formyl -3-methylpyrrole is an important intermediate of tolyporohin. On the base of introducing the present research and development of tolypo- rohin and pyrroles ramification at home and abroad, an emphasis was made on synthesis of 2-Bromo-5-formyl -3-methylpyrrole and the technical conditions of all steps, which was described as follows. Diethyl 3,5-dimethylpyrrole-2,4-dicarboxylate was made by nitrification, reduction and cycle of ethyl acetoacetate.

由于2-溴-5-甲酰基-3-甲基吡咯是合成托尼卟吩的重要中间体,本文在阐述了当前托尼卟吩及吡咯衍生物的国内外研究和开发的基础上,重点研究了2-溴-5-甲酰基-3-甲基吡咯的合成,并对各步反应进行了工艺研究,具体合成步骤如下:本文通过对乙酰乙酸乙酯的亚硝化、还原、成环,反应生成吡咯单环衍生物2,4-二乙氧羰基-3,5-二甲基吡咯。

Synthesis of methylene-4,4'-di catalyzed by zinc oxide Various metal oxide were investigated in the synthesis of methylene-4,4'-di from ethyl carbamate, and a serious of ZnO/SiO2 catalysts were prepared by deposition-precipitation method.

氧化锌为催化剂合成4,4'-二环己基甲烷二氨基甲酸乙酯以氨基甲酸乙酯和4,4'-二环己基甲烷二胺的反应体系为研究对象,在考察多种金属氧化物活性的基础上,使用沉积沉淀法制备了一系列硅胶负载氧化锌催化剂,并对其催化性能进行了研究。

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