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The results show that for collectors of the same kind, their selectivity is in linear relationship with HOMO energy and can be predicted well. For collectors of different kinds, it can be concluded from shape of HOMO and atomic HOMO density that the selectivity of ethoxycarbonyl thionocarbamates is better than the one of xanthogen formates.

结果表明:对于同种类型的捕收剂,其选择性与HOMO能量呈线性关系,依据HOMO能量能较准确地预测这两种捕收剂的选择性能;对于不同种类的捕收剂,通过对HOMO形状以及组成原子的HOMO密度的讨论可知,乙氧羰基硫氨酯类捕收剂的选择性能要比黄原酸甲酸酯类捕收剂的强。

The research indicated that under the compound use of hydroquinone and methyl quinone or independent use of phenothiazines or nitrogen oxygen free radical made the polymerization retarder, opposite-methyl-phenylsulfon made the esterification catalyst, toluol made the backflow including water condition, the acid mellowly compared to when it was 1.15, the production rate of the synthesis methylacrylic acid polyethylene glycol single methyl ether (400) ester may achieve 98.9%, was extremely similar to the overseas product functional group structure.

研究表明,在氢醌、甲醌复合使用或者单独使用吩噻嗪、氮氧自由基哌啶酮作阻聚剂,对甲苯磺酸作酯化催化剂、甲苯作回流带水的条件下、酸醇比为1.5时,合成的甲基丙烯酸聚乙二醇单甲醚(400)酯产率可以达到98.9%,与国外产品官能团结构十分相似。

A series of p-toluene sulfonylamido acetacylhydrazone derivatives were synthesized from p-toluenesulfonyl chloride which reacted with glycine to get the intermediate p-toluene sulfonylamido glycine, then through the esterification, hydrazinolysis to afford another intermediate p-toluene sulfonylamido acethydrazide, which condensed with different aldehydes to obtain the target compounds that were characterized by IR, 1H NMR, 13C NMR spectra and elemental analysis.

魏太保 ;冷艳丽;王永成;张建辉;张有明*摘要:以对甲苯磺酰氯为原料,通过与氨基乙酸反应得到中间体对甲苯磺酰氨基乙酸,再经酯化、肼解得到对甲苯磺酰氨基乙酰肼,然后与相应的醛缩合得一系列对甲苯磺酰胺基乙酰腙类化合物。其结构经元素分析, IR, 1H NMR和13C NMR确证。

N-Carbobenzoxy-L-homoserinelactone was prepared via N-alkylation reaction of L-methionine and iodoacetamide with benzyl chloroformate as amino protecting agent.

以L-蛋氨酸为原料,氯甲酸苄酯为氨基保护试剂,与碘乙酰胺(I2微量)内酯化反应,合成N-苄氧羰基-L-高丝氨酸内酯。

The formation of charge transfer complex was studied in the first part. The second part includes the synthesis and characterization of the acrylated unsaturated polyester and the kinetic studies on the Ar-UPE/ triethylene divinyl ether (DVE-3) photocuring system, the rheology and properties of film after photocuring. The third part includes the synthesis and characterization of the urethane modified unsaturated polyester and the kinetic studies on the PU-UPE/DVE-3 photocuring system, the rheology and properties of film after photocuring. The fourth part includes the synthesis and characterization of the vinyl ether end capped polyurethane and the kinetic studies on the VE-PU/DVE3 photocuring system, the rheology and properties of film after photocuring.

整个研究工作分为四个部分:一是电荷转移复合物的研究;二是丙烯酰氧基化不饱和聚酯的合成,表征,Ar-UPE/二缩乙二醇二乙烯基醚(DVE-3)体系光固化动力学研究以及Ar-UPE/DVE-3体系流变性能和光固化后涂膜综合性能的研究;三是氨酯改性的不饱和聚酯的合成,表征,PU-UPE/DVE-3体系光固化动力学研究以及该体系光固化后涂膜综合性能的研究;四是乙烯基醚封端的聚氨酯的合成,表征,VE-PU/马来酸二甲酯体系光固化动力学研究以及VE-PU/DMA体系流变性能和光固化后涂膜综合性能的研究。

Water; Glycerin; Sodium Laureth Sulfate; Polyethylene; Acrylates/C10-30 Alkyl Acrylate Crosspolymer; Lauryl Glucoside; Phenoxyethanol; Microcrystalline Wax; Fragrance; Methylparaben; Menthyl Lactate; Sodium Hydroxide; Tetrasodium EDTA; Cellulose; Lactose; Sodium Ascorbyl Phosphate; Acrylates/Ammonium Methacrylate Copolymer; Hydroxypropyl Methylcellulose; Mica; Talc; Titanium Dioxide; Tocopheryl Acetate; Triethyl Citrate; Cucumis Sativus Fruit Extract; Citrus Grandis Fruit Extract; Panax Ginseng Root Extract; Zingiber Officinale Root Extract; Iron Oxides; Red 30; Yellow 5; Yellow 5 Lake

水;甘油;钠Laureth硫酸盐;聚乙烯; Acrylates/C10-30烷基丙烯酸酯Crosspolymer ;十二烷基糖苷; Phenoxyethanol ;微晶蜡;香水; Methylparaben ;薄荷乳酸;氢氧化钠; Tetrasodium乙二胺四乙酸;纤维素;乳糖;钠抗坏血酸磷酸酯;丙烯酸酯/铵甲基丙烯酸共聚物;羟丙基甲基纤维素;云母;滑石粉;二氧化钛; Tocopheryl醋酸;三柠檬酸;黄瓜水果提取物;柚皮果提取物;人参根提取物;生姜根提取物;铁氧化物;红30 ;黄河5 ;黄河5湖

Water; Glycerin; Sodium Laureth Sulfate; Polyethylene; Acrylates/C10-30 Alkyl Acrylate Crosspolymer; Lauryl Glucoside; Phenoxyethanol; Microcrystalline Wax; Fragrance; Methylparaben; Menthyl Lactate; Sodium Hydroxide; Tetrasodium EDTA; Cellulose; Lactose; Sodium Ascorbyl Phosphate; Acrylates/Ammonium Methacrylate Copolymer; Hydroxypropyl Methylcellulose; Mica; Talc; Titanium Dioxide; Tocopheryl Acetate; Triethyl Citrate; Cucumis Sativus Fruit Extract; Citrus Grandis Fruit Extract; Panax Ginseng Root Extract; Zingiber Officinale Root Extract; Iron Oxides; Red 30; Yellow 5; Yellow 5 Lake.

成分Ingredients 水;甘油;钠Laureth硫酸盐;聚乙烯; Acrylates/C10-30烷基丙烯酸酯Crosspolymer ;十二烷基糖苷; Phenoxyethanol ;微晶蜡;香水; Methylparaben ;薄荷乳酸;氢氧化钠; Tetrasodium乙二胺四乙酸;纤维素;乳糖;钠抗坏血酸磷酸酯;丙烯酸酯/铵甲基丙烯酸共聚物;羟丙基甲基纤维素;云母;滑石粉;二氧化钛; Tocopheryl醋酸;三柠檬酸;黄瓜水果提取物;柚皮果提取物;人参根提取物;生姜根提取物;铁氧化物;红30 ;黄河5 ;黄河5湖

Comb-shaped copolymer of polycarboxylate containing carboxyl,sulfonic groups(-SO3M),polyethylene glycol(-OC2H4-) was synthesized by monomers of sodium 2-acrylamido-2-methylpropane sulphonate,acrylic acid,polyethylene glycol monoester acrylate under certain conditions.

本文通过2-丙烯酰胺-2甲基丙基磺酸钠与丙烯酸、聚乙二醇单丙烯酸酯在一定条件下发生聚合反应合成含有羧基、磺酸基(—SO3M)、聚氧乙烯链(—OC2H4—)等侧链的高性能减水剂PC。

Segmented polyester polyurethaneurea based n 4, 4'-disphenylmethane diisocyanate, ethylene diamine and polybutylene adipate elastomers and their deuterated polymers were studied by means of IR spectroscopy.

用红外光谱法对基於4,4'-二苯基甲烷二异氰酸酯、乙二胺和聚己二酸丁二醇酯的嵌段聚酯型聚脲氨酯弹性体及其氘化產物进行了研究。

Results indicated that pesticides show different variability in certain extent in relative response between different matrixes. Certain pesticides are matrix-dependent such as chlorothalonil, paraoxon, deltamethrin, methamidophos, acephate etc, among them, chlorothalonil have better relative response in acidic matrixes (as orange, tomato, grape, kiwi fruit) but have serious suppression in scallion, onion, garlic, leek, lotus root etc.

结果表明,各农药相对响应值具有不同程度差异,个别农药显示了较强的基质依赖特点(如百菌清、对氧磷、溴氰菊酯、甲胺磷、乙酰甲胺磷);其中百菌清在酸性基质橙子、番茄、葡萄、猕猴桃、蘑菇中稳定,其基质对百菌清起到了保护性作用,且能够抑制或减少溴氰异构体2向异构体1的转化;而在大葱、洋葱、蒜、藕、梨等基质中存在显著的降解或抑制作用。

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