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D limonene was distributed among the culture flasks (200 mg/L). The flasks were incubated at 28oC on a rotary shaker (r/min=120) for 5 days. On completion, the culture broth were successively extracted with EtOAc. The extract was quantitatively measured by gas chromatography mass spectrometry analysis, The results showed that biocatalytic reactions were comprised of oxidation, including hydroxylation and ketonization which occurred at different positions of the D limonene, as well as hydrogenation, hydrolyzation, esterification and cyclic cleavage. These bacteria strains possess the distinctive biocatalytic capacities towards the D limonene. A series of terpenoids, including sesqui , di and tri terpernoids were also observed,which was accounted for D limonene had influence on the metabolites of marine bacteria.

以2216E为培养基,添加200mg/L的柠檬烯,在28℃,以120 r/min摇瓶培养5 d,用乙酸乙酯提取培养液,经GC MS分析其转化产物,结果显示,这些细菌能在柠檬烯的不同位置进行羟基化、羰基化等,并伴随有还原、水解、酯化、开环等反应,但转化能力和转化程度不同;在产物中,还检测到系列结构不同的其它萜类:包括倍半萜、二萜以及三萜等,这些萜类化合物的产生跟柠檬烯的加入有关,说明柠檬烯能影响细菌代谢产物的产生。

A GC headspace injection method for the determination of residual organic solvents such as methanol, ethanol, acetonitrile, dichloromethane, ethylacetate, 4 methyl 2 pentanone, toluene, DMF, chloroform and tetrahydrofuran in tazobactam was established.

建立了气相色谱顶空进样法测定三唑巴坦中甲醇、乙醇、乙腈、二氯甲烷、乙酸乙酯、甲基异丁基酮、甲苯、N ,N′-二甲基甲酰胺、氯仿和四氢呋喃等有机溶剂的残留量。

Silicone ; hard coating ; silicone resin ; methyltriethoxy silicone ; tetraethoxy silicane ; transparent plastic

有机硅;硬质涂料;硅树脂;甲基三乙氧基硅烷;正硅酸乙酯;透明塑料

The structural assignment of Ⅱwas supported by spectral data and was confirmed by the identification of the compound as the product obtained by synthesis from triethyl orthoacetate and 2- cyanot hioacetamide.

结构的指定得到由光谱数据的支持,确认结构是通过原乙酸三乙酯和2-氰基-硫代乙酰胺合成得到的化合物。

Distearyl pentaerythritol diphosphite has been synthesized with pentaerythritol, triethyl phosphite and stearic alcohol.

以季戊四醇、亚磷酸三乙酯和十八醇为原料,在实验室合成了二硬脂基季戊四醇二亚磷酸酯。

The absorption and transport of umbelliferone, osthole, columbianadin, columbianetin acetate, angelolA and angelolB are passive diffusion as the dominating process in Caco2 cell monolayer model.

为了考察独活中香豆素类化学成分在整体口服实验中能否被吸收和吸收程度,本文首先采用Caco2细胞单层模型[8]研究独活中的主要化学成分伞形花内酯、甲氧基欧芹素、二氢欧山芹素、二氢欧山芹醇乙酯、当归醇A和当归醇B的吸收和转运。6种香豆素类成分的化学结构见图1。

In general, 80% or more of caffeine in raw tea can be removed by water-BA partition method, and the recovery of esterified catechins is about 70%.

水-丁基乙酯分配萃取方法一般可移除生茶粉中80%的咖啡因,而酯化型儿茶素也能回收大约70%。

Treatment of sucrose alkyl 4,6-orthoacetate hexaacetates I with water or alcohol in the presence of an acid catalyst afforded derivatives of sucrose acetates by selectively blocking specific hydroxyl group in sucrose and acetyl migration.

4,6-原乙酸蔗糖六乙酸酯在酸催化下水解和醇解,选择性地保护了蔗糖分子中的某些羟基,并通过乙酰基由C~4→C~6迁移的异构化反应合成了一系列蔗糖乙酸酯。

A new type of polyaspartic esters secondary amine called PAE-b was prepared from prime amine 4,4'-methylenebis and dialkyl maleates via a Michael Addition Reaction.

通过伯胺4,4'-二氨基环己基甲烷与马来酸二乙酯的Michael加成反应,合成1种新型聚天门冬氨酸酯仲胺。

Application of reverse micella enzyme system in oil industry;2. Synthesis of ethyl oleate catalyzed by Lipex lipase in AOT/isooctane reverse micella r system was studied.

在二-(2-乙基己基)琥珀酸酯磺酸钠和异辛烷构建的逆胶束体系中,以Lipex脂肪酶为催化剂,合成了油酸乙酯,考察了各影响因素对其产率的影响,并进行了脂肪酶紫外荧光检测和体系粒度分析。

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