乙酯基

It is the first time to report that C8-acetyl is displaced by long chain fatty acyl for triester-aconitines in the ester-exchange reactions.

三酯型乌头生物碱的C位乙酰基被各种长链脂肪酰基取代的酯交换反应为首次报道。

In view of rising feedstock and energy costs, BASF will further increase prices for its acrylic acid and acrylic esters (glacial acrylic acid; methyl acrylate, ethyl acrylate, n-butyl acrylate, 2-ethyl hexyl acrylate), as contracts permit.

在原料和能源成本，巴斯夫公司将进一步提高其丙烯酸和丙烯酸酯（冰丙烯酸，丙烯酸甲酯，丙烯酸乙酯，丁酯丙烯酸2乙基己基丙烯酸酯），价格为合同许可。

New compounds of the type of N--N'-(2,4-dichlorophenyloxyacetyl)-semicarbazides were synthesized by a series of reactions of preparing organic isocyanates by Curtius rearrangement with 2,4- dichloro aryloxyacetic acid hydrazide using one-pot procedures.

以芳香取代酸为原料，用Curtius重排的方法合成异氰酸酯，直接与2，4-二氯苯氧乙酰肼作用，一锅法合成了4种N-取代芳基-N'-(2，4-二氯苯氧乙酰基)氨基脲类化合物。

In this thesis, 1, 5-diaryl-3-pyrazilidinones, 1, 5-diaryl-3-hydroxypyrazoles and 3-(2, 3, 4, 6-tetraacetyl-β-D-glucopyranos-1-yl)-1, 5-diaryl-1H-pyrazoles are designed and synthesized.1, 5-diaryl-3-pyrzolidinones were obtained by condensation of 3-arylpropenates and phenylhydrazine or fluorophenylhydrazine under the catalysis of sodium methylate and the yields were about 55-80%.

在本文中，设计合成了1，5-二芳基-3-吡唑烷酮化合物、1，5-二芳基-3-吡唑烷酮化合物和3-(2，3，4，6-四乙酰基-β-D-吡喃葡萄糖-1-基)-1，5-二芳基吡唑化合物。以3-芳基-2-丙烯酸酯为原料，与芳基肼在醇钠的催化作用下，反应可以生成1，5-二芳基-3-吡唑烷酮，产率在55%以上。

Naphthalene acetyl chloride was prepared firstly by the reaction betweenα-naphthylacetic acid and SOCl2 in anhydrous benzene, then reacted with potassium thiocyanate to obtainα-naphthalene acetyl isosulfocyanate, as taking an addition reaction with p-chloro benzoyl hydrazine the novel compound N-naphthalene acetyl-N'-p-chloro benzoylamino thiocarbamide was finally synthesized.

通过α-萘乙酸和SOCl2在无水苯中反应制得α-萘乙酰氯，然后与硫氰酸钾反应生成α-萘乙酸基异硫氰酸酯，再与对氯苯甲酰肼进行加成反应，生成新型化合物N-萘乙酰基－N'-对氯苯甲酰氨基硫脲。

In the presence of ethanol- HCl solution, arylamine-HCl and w=37% aqueous formaldehyde solution or the condensation product of arylamine and formaldehyde are directly reacted with ethyl 3-oxo-2-phenylmethylenebutyrate to form l-aryl-2-phenyl-3-carbethoxy-4-piperidone.

2－苯亚甲基－3－丁酮酸乙酯与芳香胺和w＝37％甲醛水溶液或芳胺和甲醛的缩合物在氯化氢－无水乙醇存在下可直接发生的Mannich反应，得到1－对位取代芳基－2－苯基－3－羰乙氧基－哌啶－4－酮。

The condensation of aromatic aldehydes with active methylene compounds like malononitrile, cyanoacetamide and ethyl cyanoacetate has been found to proceed very efficiently at room temperature giving excellent yields, but the condensation of heteroaromatic,α,β-unsaturated and aliphatic aldehydes with active methylene compounds proceeded smoothly in 50~65℃ with good yields and the reactions of aromatic, aliphatic ketones as well as p-phthalaldehyde with malononitrile also proceeded in 75~85℃ with moderate yields.

芳香醛与活泼亚甲基化合物如丙二腈、氰基乙酸乙酯、氰基乙酰胺的缩合在室温下即能顺利进行，获得了很高的收率；而对于杂环芳醛、α，β-不饱和的醛以及脂肪醛与活泼亚甲基化合物的缩合，需在50~65℃下进行，也取得了很高的收率；对于脂肪酮、芳香酮以及二元醛与丙二腈的缩合在75~85℃下也能顺利地进行，获得中等以上的收率。

The synthetic methods of dialkyl carbonate , through ester exchange, oxidative carbonylation, decarbonylation , synthesis with carbon dioxide , have been reviewed in this article.

简述了近年来碳酸二酯合成方法的研究进展，介绍了酯交换法、氧化羰化法、脱羰基法和二氧化碳直接合成法等，并着重介绍了碳酸二甲酯、碳酸二乙酯、碳酸二苯酯合成工艺中催化剂的研究与开发情

Gas chromatograph/mass spectrometer system was used to analyze polycyclic aromatic hydrocarbon (PAHs, including naphthalin, anthracene and fluoranthene) and phthalic acid ester [PAEs, including dimethyl phthalate, diethyl phthalate, diisobutyl phthalate and di(2-ethylhexyl) phthalate] concentration in water samples taken from every treatment units of a large-scale waterworks in a western city whose water source is the upstream of Yangtze river.

以多环芳烃(包括萘、蒽、荧蒽三种物质)和邻苯二甲酸酯包括邻苯二甲酸二甲酯(DMP、邻苯二甲酸二乙酯、邻苯二甲酸二异丁酯、邻苯二甲酸二(2-乙基己基)酯4种物质作为研究对象，采用GC-MS方法测定了以长江为原水的某大型城市给水厂各工艺段水样中的上述物质。

L-Phenylalanine was then obtained by alkylation of N- glycine ethyl ester with benzyl bromide in the presence of an asymmetric phase-transfer catalyst-N-benzyl-cinchonine chloride, followed by hydrolysis of the resulting product.

以甘氨酸乙酯盐酸盐和二苯甲酮为起始原料合成了N-二苯亚甲氨基乙酸乙酯，后者在手性相转移催化剂-N-苄基氯化辛可宁诱导下与烷基化试剂溴化苄发生不对称相转移催化烷基化反应，水解得到L-苯丙氨酸。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。