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乙酯

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Short for poly, a condensation polymer that is commonly used in soft-drink bottles、fibers、engineering plastics etc.

聚对苯二甲酸乙二醇酯:PET是由乙二醇和对苯二甲酸通过缩聚反应而成的,反应过程中释放出副产物水。

BIO-BEAUTE commits to selecting only 100%pure natural extracts: no silicone, no PEG, no petrochemical derivatives, no genetically modified organisms, no artificial coloring agents, no parabens, no EDTA, no formaldehyde, no products with ethoxyl derivatives, no phenoxyethanol.

BIO-BEAUTE 保证选择100%的纯净天然提取物:无硅胶、无聚乙二醇、无石油化学衍生物、无转基因有机体、无人工着色剂、无苯甲酸酯类、无乙二胺四乙酸、无甲醛、无羟乙基衍生产品,无无苯氧乙醇。

A second group includes those compositions, which include an organic polymeric binding material, eg, mixed cellulose esters of monobasic or dibasic acids such as cellulose acetate succinate; an addition-polymerizable ethylenically unsaturated compound, eg, vinylidene and vinyl monomers, preferably of the acrylic or alkacrylic ester type; eg, triethylene glycol diacrylate; and an addition-polymerization initiator which forms radicals under the influence of actinic radiation, eg, anthraquinone.

第二组包括那些作品,其中包括有机聚合物具有约束力的物质,例如,对一元或二元酸混合纤维素酯,如醋酸纤维素琥珀酸; 1此外,聚合ethylenically不饱和化合物,例如,偏和乙烯基单体,丙烯酸最好的或alkacrylic酯类型,如,三乙二醇二丙烯酸酯;和加成聚合引发剂的形式下光化辐射的影响自由基,例如,蒽醌。

The aim of this study was to develop a novel amphiphilic functional block poly(ε-caprolactone) bearing ketone groups MPEG-b-P(OPD-co-CL. 2-oxepane-1, 5-dione was copolymerized with ε-caprolatone in which methoxy poly (MPEG, Mn=5 000) and stannous octoate were used as initiator and catalyst, respectively. The syntheses were conducted by bulk and solution polymerization. 1H NMR results showed that peak position and splitting of the polymers synthesized through solution polymerization were consistent with theoretical data, demonstrating the products were designed block copolymers. While in the bulk polymerization, polymer peak position was changed due to their high reaction temperature, suggesting their structural variation.

将带有羰基官能团的4-羰基己内酯和ε-己内酯分别在甲氧基聚乙二醇(MPEG,Mn=5 000)为引发剂,异辛酸亚锡为催化剂溶液和本体体系中开环聚合,合成了两亲性侧基带有羰基官能团的聚己内酯嵌段共聚物MPEG-b-P(OPD-co-CL.1H NMR结果表明采用溶液聚合法合成的聚合物各峰的峰位置和分裂情况与理论一致,证明了产物是实验所设计的嵌段共聚物,而采用本体聚合法合成的聚合物由于温度的影响,聚合物各峰的峰位置发生了变化,说明其结构发生了变化;差示扫描量热法分析结果表明随着OPD单体含量的增加,聚合物的熔点,玻璃化转变温度和熔融焓增加;热失重测试结果表明OPD单体的引入增加了聚合物的热敏感性。

Poly/montmorillonite/2-Carboxyethyl phosphinic acid (PET/MMT/CEPP) nanocomposites were prepared through direct-esterification process by adding reactive flame retardant before esterification, and organic MMT was added before polycondensation.

采用直接酯化法,将共聚型阻燃剂羧乙基苯基次磷酸和对苯二甲酸以及乙二醇混合后酯化,在酯化产物中加入经过有机改性的蒙脱土,缩聚制备了阻燃聚酯/蒙脱土纳米复合材料(PET/MMT/CEPP)。

In chapter four, molecular imprinting polymers against amino acid derivatives utilizing 2-VP+AM as combined functional monomer and trimethylolpropane trimethacrylate as tribasic cross-linker were prepared and result was compared with those with the same amino acid derivative as the imprinted molecules utilizing ethyleneglycol dimethacrylate as dibasic cross-linker. It was found that cross-link intensity of the molecular imprinting polymer is higher when TRIM was utilized and baseline separation for the imprinted molecule could be achieved. When TRIM was utilized as cross-linker more molecule is imprinted during the polymerization.

第四章采用2-乙烯基吡啶+丙烯酰胺复合功能单体,考察了三元交联剂三甲氧基丙烷三甲基丙烯酸酯烙印氨基酸衍生物的情况,并与二元交联剂乙二醇二甲基丙烯酸酯烙印相同氨基酸衍生物的情况进行了对比,发现三甲氧基丙烷三甲基丙烯酸酯交联剂在较小的用量下就可使分子烙印聚合物达到足够的交联度,实现烙印分子的基线分离。

In the second chapater, first-principles electronic structure calculations were performed to examine the reaction pathway and corresponding activation free energies for alkaline hydrolysis of representative phosphodiesters, including dimethyl phosphate, trimethylene phosphate, ethylene phosphate, and a simplified model of adenosine 3\', 5\'-phosphate.

第二章中主要应用量子化学从头计算方法研究了四种磷酸二酯—二甲基磷酸酯,乙撑磷酸酯,TMP阴离子及cAMP的模型化合物的碱性水解反应途径,并估算了各个反应的能垒和自由能能垒。

Segmented polyester polyurethaneurea based n 4, 4'-disphenylmethane diisocyanate, ethylene diamine and polybutylene adipate elastomers and their deuterated polymers were studied by means of IR spectroscopy.

用红外光谱法对基於4,4'-二苯基甲烷二异氰酸酯、乙二胺和聚己二酸丁二醇酯的嵌段聚酯型聚脲氨酯弹性体及其氘化產物进行了研究。

The advantages of catalytic synthesis of oxalate ester in gaseous phase by carbon monoxide are summarized. The five important characterization of our patent technology invented for the use of industrial raw material and the potential good economic value of the process are presented. It indicates that study and development of catalytic synthesis of oxalate ester .oxalic acid as well as glycols by natural gas in gaseous phase have a great advantage for full utilization of natural gas....

概述了&CO气相催化合成草酸酯&技术的先进性,介绍用工业性原料为主要内容的专利技术:&气相催化合成草酸酯连续工艺&的五个主要特点及其潜在的经济效益,并指出,用天然气经合成气进行气相催化合成草酸酯和草酸、乙二醇的研究与开发,可使天然气得到充分的利用,具有很好的经济效益,是天然气化工综合利用的一条有效途经,也是当代C1化学的重要发展方向。

Reaction of citric acid with paraformaldehyde gave anhydromethylene citric acid with a yield of 63%;the reaction of compound with acetic anhydride gave the corresponding anhydride with a yield of 87%;the esterification of compound with lauryl alcohol gave anhydrocitric acid monoester with a yield of 76%.

将等浓度的柠檬酸和多聚甲醛加热,反应生成柠檬酸缩醛环酯,产率为63%;与乙酸酐反应得到相应的柠檬酸酐,产率为87%;与月桂醇酯化,生成产物,产率为76%;用二氧六环做溶剂,将与等浓度的碱进行开环反应,生成柠檬酸月桂醇单酯,产率为83%。

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