乙酯

Cycloalkylation of diethyl malonate and ethyl cyanoacetate with alkyl halide was investigated in the presence of toluene.

以甲苯为溶剂及带水剂，用粉末K2CO3代替常规使用的乙醇钠，在季铵盐和聚乙二醇混合相转移催化剂的存在下，含有活泼氢的丙二酸二乙酯和氰乙酸乙酯与二卤代物进行缩合反应，得到相应的环化物。

In order to investigate the mechanism for this reac-tion, methyl α-bromoacetate or ethyl α-bromoacetate as starting material was added to the solution of phenyl selenoamide in ethanol in 1∶1 or 2∶1 molar ratio under the neutral condition at room temperature. The results indicated that the same product bis or bis diselenide was formed. Byproduct ethyl benzoate was also separated.

为了研究该反应机理，选择α-溴代乙酸甲酯或α-溴代乙酸乙酯在无催化剂、中性条件下，乙醇溶液中与苯基硒代酰胺室温下反应，投料比为1∶1和2∶1，结果也都生成了同一类产物二甲氧羰基甲基二硒醚或二乙氧羰基甲基二硒醚，同时还分离得到了相应的副产物苯甲酸乙酯。

In order to investigate the mechanism for this reaction, methyl α-bromoacetate or ethyl α-bromoacetate as starting material was added to the solution of phenyl selenoamide in ethanol in 1:1 or 2:1 molar ratio under the neutral condition at room temperature. The results indicated that the same product bis or bis diselenide was formed. Byproduct ethyl benzoate was also separated.

为了研究该反应机理，选择α-溴代乙酸甲酯或α-溴代乙酸乙酯在无催化剂、中性条件下，乙醇溶液中与苯基硒代酰胺室温下反应，投料比为1：1和2：1，结果也都生成了同一类产物二甲氧羰基甲基二硒醚或二乙氧羰基甲基二硒醚，同时还分离得到了相应的副产物苯甲酸乙酯。

The antimicrobial test and researched was done on wide distillation of different solvents on Terpenoid, polarity separation of ethanol distillable substance, thin layer chromatography of different polarities and distillation of amylase. The results showed that the active substance distilled by 95% ethanol and V methanol: toluene=3:1 had stronger antimicrobial activity on Agaricus blazei Murrill. The antimicrobial activity of ethyl acetate was stronger than wide distilling substance with ethanol, but the water part has not antimicrobial effect. Two straps of ethyl acetate phase（Rf0.57、Rf0.63）(0.1g/ml)had stronger antimicrobial activity on Agaricus blazei Murrill, the antimicrobial zone on Pseudomonas was 19.3mm. The bacteriostatic activity of chromatography strap of water phase was rather weaker, the water solution (0.5g/g) of amylase had better effect on pathogenic fungus of Agaricus blazei Murrill, its antimicrobial zone on Aspergillus niger, Citrinin, Trichoderma viride were 10.8 mm, 7.9 mm, 5.3 mm.

通过对日本凹顶藻以不同溶剂的粗提、乙醇提取物的极性分离、不同极性的薄层层析和多糖的提取，进行抗菌试验的研究，发现95%乙醇和V甲醇：甲苯为3∶1的提取的活性物质具有较强的抗姬松茸的病原细菌活性，乙酸乙酯相对病原细菌的抑菌强于乙醇的粗提物，而水相基本无抑菌效果，乙酸乙酯相的两个带（Rf0.57、Rf0.63）浓度为0.1g/ml具有较强抗姬松茸病原细菌的活性，对假单孢杆菌抑菌圈达到19.3mm，水相层析带的抑菌活性较弱，多糖的粗提物配成0.25g/g的水溶液对姬松茸病原真菌有较好的抑菌效果对黑曲霉、桔青霉和绿色木霉的抑菌圈分别达到10.8 mm、7.9 mm、5.3 mm。

Our company is mainly engaged in chemical raw materials trading, the company mainly engaged in: toluene, xylene, mesitylene, durene, 6 # 120 # 200 # solvent, ethyl acetate, butyl acetate, acetone, butanone, cyclohexanone, isophorone, MIBK, isopropyl alcohol, isobutyl alcohol, butanol, mixed alcohols, methanol, ethanol, ethylene glycol, diethylene glycol, diacetone alcohol, Anti-White Water, CAC, n-hexane, dichloromethane, trichloro-B, DMF, 5 # 10 # 15 # white mineral oil, lubricating oil, sewing machine oil, as well as high-pressure polyethylene, linear polyethylene, low-pressure polyethylene, polypropylene, rubber and other chemical raw materials.

我公司主要从事化工原料贸易，公司主要经营：甲苯、二甲苯、三甲苯、四甲苯、6# 120# 200#溶剂、醋酸乙酯、醋酸丁酯、丙酮、丁酮、环已酮、异佛尔酮、MIBK、异丙醇、异丁醇、正丁醇、混丙醇、甲醇、乙醇、乙二醇、二甘醇、二丙酮醇、防白水、CAC、正已烷、二氯甲烷、三氯乙、DMF、5# 10# 15#白矿油、润滑油、针车油以及高压聚乙烯、线性聚乙烯、低压聚乙烯、聚丙烯、橡胶等各种化工原料。

The main products are as follows: Pharmaceutical Intermediate, Trimethyl Orthoformate , Triethyl Orthoformate, Sodium Methoxide, Power and solution Ethoxide,α-Chloropropionyl Chloride, Acetyl Chloride. Shandong Xinhua Junli Chemical Co.,Ltd.

公司主要产品为医药中间体，原甲酸三甲酯、原甲酸三乙酯、甲醇钠、乙醇钠、α-氯代丙酰氯、乙酰氯，其中原甲酸三甲酯、原甲酸三乙酯是国内唯一采用金属钠法工艺生产的企业。

This thesis consists of four chapters:Chapter 1: Michael addition of chalcones with active methylene compounds such as diethyl malonate, ethyl acetoacetate and nitromethane catalyzed by potassium hydroxide in anhydrous ethanol results Michael adducts in 72-98% yield under ultrasound irradiation in 25-150min.

第一章：研究了超声辐射下，氢氧化钾催化的查耳酮与活泼亚甲基化合物如丙二酸二乙酯、乙酰乙酸乙酯和硝基甲烷的迈克尔反应。

Using silicotungstic acid as catalyst with the catalyst supported on active carbon,2-methyl-2-ethyl-acetic-1,3-oxathiolane(targeted compound I,an aroma compound with apple flavor )was synthesized by the reaction of ethyl aceto-acetate and 2-mercapto-ethanol.

以活性炭固载硅钨酸作为催化剂，用乙酰乙酸乙酯与巯基乙醇缩和合成了具有浓郁苹果香气的香料化合物2-甲基-2-乙酸乙酯基-1，3-氧硫杂环戊烷。

Waste oil category: Waste oil, waste hydraulic oil, waste oil, waste oil injection, waste kerosene, waste of white mineral oil, white waste oil, waste oil sparks, the repeal of toluene, waste cutting oil, gear oil, lubricants, batteries oil, spindle oil, zorra, oil, turpentine oil, solvent oil, gear oil, oil rails; waste chemical categories: one, the repeal of toluene, xylene waste, spent 2 pure benzene, acetone waste, waste Ding ketone, cyclohexanone 3 waste, waste dichloromethane, dichloroethane waste, waste Dichloropropane 4, solvent categories: soluble oil 6 #, 120 # dissolving agents, dissolving agents 200 # 5, trichloro ethylene, dichloromethane, trichloroethane; tetrachlorethylene, trichloromethane 6, the repeal of methanol, ethanol, waste, waste alcohol, isopropyl alcohol waste 7, the repeal of ethylene glycol, diethylene glycol waste, spent three 8 glycol, waste butyl acetate, ethyl acetate wastewater, waste acetate 9, the repeal of ethyl ether, acetonitrile waste, waste petroleum ether 10, cleaning categories: cleaning agent, washing machine water, days that water; wash board water,×oil wastewater liquid 11, the supply of tires category: special supply of fuel oil, non-standard oil, burner oil, waste oil and other refined crude oil.

废油类：废机油，废液压油，废柴油，废注塑机油，废煤油，废白矿油，废白电油，废火花机油，废甲苯，废切削油，齿轮油，润滑油，废电池机油，锭子油，索拉油，松节油，溶剂油，齿轮油，导轨油等；废化工类：1、废甲苯、废二甲苯、废纯苯2、废丙酮、废丁酮、废环已酮3、废二氯甲烷、废二氯乙烷、废二氯丙烷4、溶剂类： 6#溶油剂， 120#溶油剂， 200#溶油剂5、三氯乙烯，二氯甲烷，三氯乙烷；四氯乙烯，三氯甲烷6、废甲醇、废乙醇、废丁醇、废异丙醇7、废乙二醇、废二甘醇、废三甘醇8、废醋酸丁酯、废醋酸乙酯、废醋酸甲酯9、废乙醚、废乙腈、废石油醚10、清洗类：清洗剂，洗机水，天那水；洗板水，去渍油等废液废水11、废轮胎类供应：特价供应燃料油，非标油，烧火油，废油提练的原油等。

Optically active ethyl-3-hydroxybutyrate,a useful chiral synthon,was prepared by stereoselective reduction of ethyl acetoacetate of the bread yeast in organic solvent.

利用面包酵母在非水相中不对称还原乙酰乙酸乙酯，制备了光学活性的手性化合物S-3-羟基丁酸乙酯。

Singer Leona Lewis and former Led Zeppelin guitarist Jimmy Page emerged as the bus transformed into a grass-covered carnival float, and the pair combined for a rendition of "Whole Lotta Love".

歌手leona刘易斯和前率领的飞艇的吉他手吉米页出现巴士转化为基层所涵盖的嘉年华花车，和一双合并为一移交&整个lotta爱&。

This is Kate, and that's Erin.

这是凯特，那个是爱朗。