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_6P_2W_(17)VO_(62) catalyst was prepared and characterized by FTIR,and synthesis of fraistone over as-synthesized catalyst from ethyl acetoacetate and 1,2-propylene glycol was investigated.

制备了Dawson型磷钨钒酸铵催化剂,用FT-IR分析方法对催化剂进行了结构表征,并以乙酰乙酸乙酯与1,2-丙二醇为原料催化合成了苹果酯-B。

Supported 12-Phosphotungstic Acid and Its Salts as Catalysts for the Synthesis of Fructone and Fructone-B;2. Their catalytic activities were measured by synthesis of fructone-B from ethyl acetoacetate and 1,2-propanediol.

制备了一系列以脱铝超稳Y沸石为载体的磷钨酸及其铯盐催化剂,考察了催化剂在以乙酰乙酸乙酯和1,2-丙二醇为原料催化合成草莓酯反应过程中的性能。

Conclu sion: The ethyl acetate elution of ethyl acetate fraction extract of Alisma orientalis can significantly inhibit urinary calcium oxalate stone formation in rats and be the most effective constituent of Alisma orientalis .

泽泻醋酸乙酯浸膏的醋酸乙酯洗脱液能抑制实验性高草酸尿症大白鼠体内肾草酸钙晶体的形成,是泽泻抑制尿草酸钙结石形成的有效部位。

Strains of high alcohol-producing or high ethyl acetate-producing yeasts were isolated from koji of Shanxi overmature vinegar at different temperatures. One high alcohol-producing yeast Nz19.3 and one high ethyl acetate-producing yeast Nz9.8 were identified as Saccharomyces cerevisiae and Hansenula anomala, respectively.

通过对山西老陈醋大曲的富集培养,筛选到9株高产乙醇或高产乙酸乙酯的酵母菌功能菌株,分别挑选高产乙醇和乙酸乙酯的酵母菌各1株(经分类鉴定,二者分别为酿酒酵母和异常汉逊酵母)进行共培养试验。

Replacement of one benzimidazole fragment with benzothiazole or benzoxazole and optimization of the structure to create the new frame of the compounds were also carried out with the exception to find more potent compounds. The purpose of design and synthesis of these compounds is to investigate the QSAR of this class of compounds with the inhibition of HCV NS3/NS4A protease and eventually to develop more potent inhibitors.

本文首次采用了丙二酰胺与邻芳二胺在微波辐射下制备对称性双芳并唑甲烷化合物、用芳并唑-2-乙酸乙酯与邻芳二胺在微波辐射下制备非对称性双芳并唑甲烷化合物、用4-取代噻唑-2-乙酸乙酯与邻芳二胺在微波辐射下制备非对称性(4-取代-噻唑-2-基)(1H-芳并咪唑-2-基)甲烷化合物等合成路线,共合成了48个目标化合物,其中41个为新化合物,用~1HNMR,ESI-MS,FT-IR,元素分析对这些化合物进行了全面表征,确定了这些化合物的结构,并对部分化合物进行了~(13)CNMR分析。

Components were identified which represented 85.1% of the total essential oil by the silica gel column separately.Conclusion 10 components were identified which included Bicyclo (6,3,0) undeca-dien-3-one, 5,5-dimethyl ect. of the essential oil from Angelica acutiloba Kitag were analyzed for the first time.

结果超临界CO2萃取物为黄棕色油状物,得率为0.9%,用GC-MS联用技术从中鉴定出亚油酸乙酯、5,5-二甲基-双环(6,3,0)-1,7-十一烯-3-酮等30种成分,占挥发油总含量65.66%;萃取物经硅胶柱色谱分离纯化,从中鉴定出十八酸乙酯等11种成分,占总含量的85.1%。

Components were identified which represented 65.66% of the total essential oil includding 9.12-octadecadienoic acid, ethyl ester and ect. 11 components were identified which represented 85.1% of the total essential oil by the silica gel column separately.conclusion 10 components were identified which included bicyclo (6,3,0) undeca-dien-3-one, 5,5-dimethyl ect.

结果超临界co2萃取物为黄棕色油状物,得率为0.9%,用gc-ms联用技术从中鉴定出亚油酸乙酯、5,5-二甲基-双环(6,3,0)-1,7-十一烯-3-酮等30种成分,占挥发油总含量65.66%;萃取物经硅胶柱色谱分离纯化,从中鉴定出十八酸乙酯等11种成分,占总含量的85.1%。

Carene, ethyl p?methoxycinnamate and ethyl cinnamate.

3?蒈烯、肉桂酸乙酯和对甲氧基肉桂酸乙酯等。

The active compound Celangulin-V, which is the main active compound against insect pest from Celastrus angulatus Max, was modified at its 6-OH and the core structure β-dihydroagarofuran polyol of Celangulins from the basic hydrolysis of the extract of the root bark of Celastrus angulatus Max was modified by combinatorial chemical method.

主要结果如下: 1、合成了苦皮藤素V6-乙酯、6-烯丙基醚和6-酮等衍生物,通过NMR方法鉴定了化合物的结构,经文献检索均为新化合物,生测结果表明酮衍生物丧失了杀虫活性,乙酯衍生物与苦皮藤素V活性相当,醚衍生物较苦皮藤素V活性提高11倍。

Ethyl phenoxyacetate has been synthesised by the reaction of phenol with ethyl chloroacetate under the condition of solid-liquid phase transfer catalysis using PEG-400 as the catalyst.

于固一液相转移催化条件下,以PEG-400为催化剂,通过苯酚与氯乙酸乙酯反应合成了苯氧基乙酸乙酯。与85%的水合肼作用得到相应的酰肼。

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