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N-(1-Naphthyl)ethylenediamine dihydrochloride solution was injected into the mixed flow of the water sample and sulfanilamide solution. Red dye formed by the reactions was spectrophotometrically detected at lλmax 540 nm.

将N-(1-萘基)乙二胺二盐酸盐溶液注入到水样和对氨基苯磺酰胺溶液的混合流,在lλmax 540nm处对反应形成的红色染料进行分光光度检测。

N-1-Naphthylethylenediamine dihydrochloride solution was injected into the mixed flow of the water sample and sulfanilamide solution. Red dye formed by the reactions was spectrophotometrically detected at lλmax 540 nm.

将N-1-萘基乙二胺二盐酸盐溶液注入到水样和对氨基苯磺酰胺溶液的混合流,在lλmax 540nm处对反应形成的红色染料进行分光光度检测。

Fluorescence experiment indicated that the characteristic emission intensity of terbium ion was greatly increased and possibly sensitized by gadolinium ion.

铕聚 N 乙烯基乙酰胺是一种无毒、生理相容性好的聚酰胺类高分子,可溶于水和有机溶剂,无低临界溶解温度[3]。

The crystalline amide of acetic acid, CH3CONH2, used as a solvent and wetting agent and in lacquers and explosives.

乙酰胺乙酸的晶体胺,CH3CONH2,用作溶剂和湿润剂,并用于油漆和炸药

The analogs of piracetum with the core of demethylclausenamide(III-4 and III-5) were prepared by condensation of demethylclausenamide with ethyl bromoacetate and hydrolysis or aminolysis there after.

3在兰培工作的基础上,选用O-乙酰-R--扁桃酸为拆分剂,成功的拆分了表黄皮酰胺前体5--4-苯基-1-甲基吡咯烷酮(Ⅱ-1),和Ⅱ-1分别引入3位羟基得到和表黄皮酰胺。

In order to develop an useful synthestic process, we have synthesized amides with various substitutents. The isoquinoline skeleton was constructed through Bischler-Napieralski reaction, followed by asymmetric reduction of the imine intermediates with a Ru complex to form the only chiral center. Finally, we connected the two phenyl groups by Heck reaction and effectively obtained optically active aporphine alkaloids.

为了发展一套实用的合成方法,我们首先制备於苯环上具有不同种取代基的苯乙醯胺,接著透过Bischler-Napieralski反应进行分子内合环,并利用钌金属对亚胺中间体进行不对称的还原反应,建立出产物中唯一的光学活性中心,最后再利用Heck反应连结两个苯环,就可以顺利得到具有光学选择性的阿朴吩类天然物。

Computationalresults indicate that the no-planar trans-benzanilide is the most stable structure. The spectra indicate that the Franck Condon region photodissociation dynamics have multidimensional character withnine activemodes. The intensity of υ24 mode in methanol is much stronger than that in acetonitrile. Compared with fatty amides and benzamide, phenyl substitution for H atom on-NH2 group makes C=O solvent effects disappear.

结果表明,苯甲酰苯胺的非平面反式结构为最稳定结构;在Frank-Condon区域内,苯甲酰苯胺主要由9个活性振动模组成;其中ν24(苯环上C=C不对称伸缩振动和CCH的面内弯曲振动,NH面内弯曲振动)振动模在甲醇溶剂中的强度远远大于其在乙腈的强度;与脂肪酰胺类化合物和苯甲酰胺的研究结果比较发现,苯基取代-NH2上的H原子使得C=O不再具有明显的溶剂效应。

Based on broad information collection, author compared and studied on the old synthesis process, and proposed the better process that started from benzyl chloride, then according to the sequence of " synthesis of benzylamine, synthesis of N-benzyl-N--acetamine, synthesis of 2-chloro-5-methylpridine ,2-chloro-5-trichloromethylpyridine,2-chloro-5-trifluropyridine " five steps to get the final product, CTFP.

本文在查阅大量文献资料和对2-氯-5-三氟甲基吡啶合成路线进行分析比较的基础上,提出了较佳合成路线,即以氯化苄为原料,合成的反应步骤为&苄胺&合成、&N-苄基-N--乙酰胺&合成、&2-氯-5-甲基吡啶&合成、&2-氯-5-三氯甲基吡啶&合成、&2-氯-5-三氟甲基吡啶&合成五步。

The factors which affect the average molecular weight of the polymer of AM and DMDAAC were investigated. The optimal reaction conditions are as follows: the concentration of monomer AM was 30%, while DMDAAC was 5%; the reaction temperature was 30℃, the amount of initiators at the low temperature stage was 0.05‰(compared to the weight of the monomers joining the polymerization), while V-50 was 0.025‰, the weight ratio of potassium persulphate to sodium bisulphite is 1:1, the amount of carbamide was 40‰, and complexing agent was 0.05‰, besides, aerate nitrogen gas for 8min, then the high molecular weight polymer (M=1.217×10^7) could be got after 16h reaction.

研究了影响AM与DMDAAC共聚物的平均分子量的因素,得到了优化条件为:单体浓度为30%,DMDAAC与AM摩尔比为5:95,聚合温度为30℃,低温段引发剂用量为0.05‰,K2S2O8与NaHSO3质量比为1:1,偶氮二异丁基脒盐酸盐(V-50)用量为0.025‰,尿素用量为40‰,乙二胺四乙酸二钠(EDTA-2Na)用量为0.05‰,在此优化条件下聚合反应16h后得到分子量为1.217×10^7的阳离子型聚丙烯酰胺。

Novel ZnSe nanosheets with tunable size and phase have been facilely synthesized via hydrothermal routes in the presence of neutral butylamine as structure-directing agent and ethylene diamine tetraacetic acid as stabilizer.

以乙二胺四乙酸为稳定剂、丁胺为结构导向模板,采用水热合成方法制备了尺寸和晶型可控的ZnSe纳米片晶;利用XRD,TEM,SEM以及紫外-可见漫反射等手段对所得的产物进了表征,结果表明,通过改变水热温度和BA用量,可以实现ZnSe纳米片晶的大小和物相的调控,并初步分析了其形成过程

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