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乙胺

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This chelating starch was used to chelate copper and argentum ions,and thermal gravity analysis was .

以淀粉为原料,接枝丙烯酸甲酯,然后与乙二胺反应,合成了具有多个酰胺基和胺基的螯合淀粉。

0 Of polyamidoamine has been synthesized by a divergent method with ethylenediamine as core.

采用发散合成法,合成了以乙二胺为核的1.0代树枝状大分子聚酰胺-胺(PAMAM1.0),用静态法测定了树枝状大分子在高硅溶液中对胶体硅的阻垢性能。

According to the compared analysis of prevention sulfur deposition during the production of high sour gas well, the key of prevent sulfur deposition and to control sulfur blocking is choose right element sulfur, carry out some research on the selection of sulfur solution, remix the triethylenetetramine, diethylenetriamine and monoethanolamine in different ratios, finally formed LJ-1 compounding which is best fit the production of north Sichuan province.

对比分析了多种硫沉积防治方法,防治的关键在于溶硫剂的合理选择,通过溶硫剂优选室内评价实验研究筛选出三乙烯四胺、二乙烯三胺和乙醇胺等三种单剂,按照不同的比例与现场使用的防冻剂乙二醇进行复配,最终形成了适合川东地区高含硫气井的溶硫剂LJ-1合理配方,性能评价实验表明溶硫剂LJ-1溶硫速率快、溶解度高、腐蚀小。

The result of the experiment showed that the qualitative medium - speed filter paper can be used as the material of the nitrite - detecting paper: color developing reagent A containing 4 - aminobenzene sulfonamide and N - 1 naphthyl ethylenediamine hydrochloride, and mixtures of 1 : 1 naphthylamine solution and sulfanilic acid solution as color developing reagent.

实验结果表明:定性中速滤纸可以作为亚硝酸根试纸的材料;含有4-氨基苯磺酰胺和N-1-萘基乙二胺盐酸盐的显色剂A及含有1:1的α-萘胺溶液和对氨基苯磺酸溶液的显色剂B,按1:1混合后可以作为显色剂;通过应用实验表明,亚硝酸根试纸具有体积小、便于携带、检测方便、成本低廉等特点。

To understand the reaction of tetrakis hydroxymethyl phosphonium chloride with collagen protein,the interactions of THPC with polycaprolactam,poly vinyl alcohol or ethylenediamine which were used as the model substances of amido,hydroxy and amino groups of collagen protein were examed.

通过研究THPC与聚己内酰胺、聚乙烯醇、乙二胺的酰胺基、羟基、氨基的反应,间接证明THPC主要与胶原蛋白的氨基结合,可与氨基以n∶n=1.0∶2.2形成交联,THPC与羟基和酰胺基均有少量结合,并在pH=8.0时结合量最高。

Second, degradation of butachlor is mainly by microbial metabolism; photodegradation and volatilization is limited.

丁草胺是我国生产量最多的三种除草剂丁草胺、乙草胺和草甘膦之一,主要应用在水稻田。

In this thesis,the AM1,MNDO,MINDO/3(mainly AM1)and INDO/S-CI semiempirical MO methods were used toinvestigate the excited-state intramolecular protontransfer reactions of salicylic acid derivatives—salicylic acid,methyl salicylate,salicylaldehyde,o-hydroxyaceto-phenone,salicylamide and 3-hydroxy-picolinamide (6 conformers and 2-3 anion species);2-(2'-hydroxy-5' methylphenyl) benzotriazole(4 conformers),2-(2' hydroxyphenyl) benzimidazole (3 conformers and 3anion species),Bis-2,5-(2-benzoxazolyl)hydroquinone(3 conformers),2-(2'-hydroxyphenyl)benzothiazole(2conformers) and 7-azaindole dimer (2 conformers).Theinvestigations were described as follows.Geometry optimization,relative stability andhydrogen bonding energy First,for sylicylic acid derivative molecules,the AM1,MNDO and MINDO/3 methods were used toinvestigate ground-state geometry optimization,energies,relative stabilities and hydrogen-bondingenergies on the five kinds of the molecules(designing 6 conformers and 2-3 anion species).Comparing with experimental data,the optimizedgeometry,the order of stability,the hydrogen-bonding energies and the distances between O-O in O-H..O hydrogen bonds by AM1 method were in agreementwith the experimental data,however,the C-C bondlengths optimized by MNDO and MINDO/3 were longer,C-O and O-H bond lengths were shorter;for C-N bondlengths,the results opitimized by MNDO method werethe same as those by AM1 method,nevertheless the C-Nbond lengths given by MINDO/3 method were muchshorter.For some sylicylic acid derivatives(e.g.methyl salicylate,salicylamide),the order ofstabilities on the conformers given by MNDO andMINDO/3 methods were not in agreement with theexisting conformers deduced by experimental methods,and the hydrogen bonding energies calculated by MNDO.and MINDO/3 methods were smaller.Second,the studyon the other systems found that the optimizedgeometry of the proton-transfered product with INDOmethod could not be obtained,only could theoptimized geometry of reactant be obtained,and thecalculated hydrogen bonding energies were greater.Many results of calculation indicated that the studyon the excited-state intramolecular proton transferreaction system using AM1 method was suitable andreliable.

本论文用AM1、MNDO、MINDO/3(主要是AM1)和INDO/S-CI半经验分子轨道方法对水杨酸衍生物系列——水杨酸、水杨酸甲酯、水杨醛、O-羟基乙酰苯酮、水杨酰胺和3-羟基吡啶酰胺(6种异构体和2-3种阴离子);2-(2'-羟基-5'-甲基苯基)苯并三〓唑(4种异构体);2-(2'-羟基苯基)苯并咪唑(3种异构体和3种阴离子);2,5-二间氮杂氧茚氢醌(3种异构体);2-(2'-羟基苯基)间〓杂硫茚(2种异构体)和7-〓吲哚二体(2种异构体)的激发态分子内质子转移反应在以下几个方面进行了较系统的理论研究:几何构型优化和相对稳定性及氢键能首先以水杨酸衍生物系列分子为例,用AM1、MNDO和MINDO/3方法考察了5种分子(每种分子设计6种异构体和2-3种阴离子)的基态几何构型优化,能量、相对稳定性和氢键能计算,通过和实验数据进行比较,AM1方法给出的优化几何构型、稳定性次序、氢键能和O—H。。。O氢键的0—0距离与实验数据吻合最好,MNDO和MINDO/3方法优化的C-C键长偏长,C-O键和O-H键长偏短;对于C-N键长,MNDO和AM1优化结果差别不大,而MINDO/3给出了过短的C-N键长,MNDO和MINDO/3方法给出的有些水杨酸衍生物分子(如水杨酸甲酯和水杨酰胺)异构体的稳定性次序和实验上推测的可存在异构体结果不一致,MNDO和MINDO/3方法给出的氢键能偏低,对其他体系的研究发现INDO方法常常不能得到质子转移产物的优化几何构型,只能得到反应物的优化构型,并且估算的氢键能偏高,大量的计算结果表明AM1方法对本论文研究的激发态分子内质子转移反应体系是适宜和可靠的。

Ketimine, which is prepared by acetone and ethylene diamine or hexamethylene diamine was used as potential chain extender to improve the properties of aqueous polyurethane resin.

用丙酮分别和乙二胺、己二胺反应制备酮亚胺,并以其作为潜伏性扩链剂改善水性聚氨酯的性能。

MAIN OUTCOME MEASURES: The contents of monoamine neurotranmitters of norepinephrine, adrenalin, dopamine and 5-serotonin (5-HA) and its metabolites of DHPR, 5-hydroxyindoleacetic acid (5-HIAA) and homovanillic acid in the striatum and marginal area of brain in rats were observed.

主要观察指标:大鼠纹状体和脑边缘区单胺类递质去甲肾上腺素、肾上腺素、多巴胺和5-羟色胺及其代谢产物3,4-二羟苯乙二醇、5-羟吲哚乙酸、高香草酸的含量。

Serotonin (5-HT), its precursors tryptophan and 5-hydroxytryptophan (5-HTP), major metabolites 5-hydroxyindoleacetic acid (5-HIAA); and 3-methoxy-4- hydroxyphenylethylene glycol , homovanillic acid , the respective major metabolites of noradrenaline and dopamine were measured by a method of HPLC.

应用高效液相色谱法测定其中5—羟色胺(5-HT)系列代谢物:色氨酸、5-羟色胺酸(5-HTP)、5-HT、5-羟吲哚乙酸(5-HIAA);多巴胺的主要代谢产物3-甲氧基-4-羟基苯乙酸;去甲肾上腺素的主要代谢产物3-甲氧基-4-羟基苯乙二醇等。

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