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The optimum reaction conditions are as follows: diphenylmethanethiol : methyl chloroacetate is 1:1.5, and the reaction carried out at 100℃ for 4 h, 2- acetamide can be carried out in the room temperature for 20 h, the yield of 2- acetamide was 76%, hydrogen dioxide: 2- acetamide is 1:1, and the reaction carried out at 60℃ for 3 h, the yield of modafinil was 79%, the total yield of reaction can be reached 48%.

研究表明,采用氯乙酸甲酯作为醚化试剂,反应时间4h,反应温度100℃,二苯甲硫醇:氯乙酸甲酯=1:1.5,室温下氨解反应20h,二苯甲硫乙酰胺收率76%;采用过氧化氢作为氧化试剂,反应时间3h,反应温度60℃,过氧化氢:二苯甲硫乙酰胺=1:l,莫达非尼收率79%,反应总收率可达48%。

In this paper, through a series of experiments, two series of quaternary-ammounium Gemini surfactants were synthesized, namely the pair alkylene double quaternary ammonium salt surfactant m-s-m·2Br and the pair the alkylene double quaternary ammonium salt surfactant -s-·2Br. We has carried on the attribute with the infrared spectrum to its structure, and to affected the factor which the synthesis pair the alkylene double quaternary ammonium salt surfactant responded to carry on the discussion. We has discovered the synthesis pair the ethylene double quaternary ammonium salt surfactant m-2-m·2Br optimum condition: The bromo alkane and a tetramethyl ethylene diamine mole of ratio is 3.0: 1.0, makes the solvent by the ethyl alcohol, 80℃ under responds for 48 hours in the backflow temperature; Synthesis pair alkylene double quaternary ammonium salt surfactant 12-S-12 ·2Br optimum condition: 12 tertiary amine and 1, 3- propylene dibromide (1, 4- two bromines butane) a mole of ratio is 2.2: 1.0, makes the solvent by the ethyl alcohol, responds for 48 hours in the constant temperature 80 ℃ under backflow.

本文通过一系列的实验,合成了两个系列的Gemini型表面活性剂,即双烷撑双季铵盐表面活性剂m-s-m·2Br和双烷撑双季铵盐表面活性剂-s-·2Br,用红外光谱对其结构进行了表征,并且对影响合成双烷撑双季铵盐表面活性剂反应的因素进行了讨论,找出了合成双乙撑双季铵盐表面活性剂m-2-m·2Br的最佳条件:溴代烷与四甲基乙二胺的摩尔比为3.0:1.0,以乙醇作溶剂,在回流温度80℃下反应48小时;合成双烷撑双季铵盐表面活性剂12-s-12·2Br的最佳条件:十二叔胺与1,3-二溴丙烷(1,4-二溴丁烷)摩尔比为2.2:1.0,以乙醇作溶剂,在恒温80℃下回流反应48小时。

Simultaneous removal of NO and SO〓 can be achieved by dissolving calcium oxide into cobalt ethylenediamine basic solution.

在碱性溶液中加入乙二胺合钴也可以实现NO的氧化和吸收同时进行,乙二胺合钴离子是氧化催化剂,氧化剂是废气中的氧气,该方法的实施能使NO的脱除工艺简化;在该溶液中再加入生石灰可以同时脱除SO〓。

Ethylenediamine was used as a flexible chain as well as a connecter to get water-soluble methyl red-modified hydroxypropyl β-cyclodextrin.

再利用乙二胺分子作为柔性链和连接剂键连制得水溶性的甲基乙二胺基羟丙基-β-环糊精。

The influences of the amount of 1,2-diaminoethane, temperature, molar ratio of epichlorohydrin and dimethylamine, and time on the viscosity and cationic degree of polyamine flocculants were investigated.

以环氧氯丙烷和二甲胺为原料,乙二胺为交联剂,制备有机阳离子聚合物,研究乙二胺加入量、反应温度、环氧氯丙烷和二甲胺的摩尔比、聚合时间等对聚合物粘度和阳离子度的影响。

Preparation of ethylene bis stearamide using stearyl chloride and ethylenediamine as raw materials has been studied.

研究了以乙二胺和硬脂酰氯为原料制备乙撑双硬脂酰胺的反应,讨论了原料配比、反应时间、反应温度的影响。

Thirty patients (M 23, F 7; age 50 a±s 15 a) with chronic eczema were treated with etofesalamide ointment (given th inly on the surface 3 times daily) for 4 wk; Another 30 patients (M 24, F 6; age 44 a±14 a) were treated with ointment base (given thinly on the surface 3 tim es daily) for 4 wk.

60例慢性湿疹病人,30例(男性23例,女性7例;年龄50 a±s 15 a)用乙氧苯柳胺软膏均匀涂布患处,tid, 4 wk为一个疗程;另30例(男性24例,女性6例,年龄44 a±14 a)采用乙氧苯柳胺软膏基质均匀涂敷患处,tid, 4 wk为一个疗程。

Results show that the yield of HEDTMP is more than 77% when the mole ratio of catalyst HC1 to HEDA [N-(2- hydroxyethyl) ethlenediamine] is more than 3 and methanal to HEDA is more than 6 after the process of reaction at 80?

结果表明,在催化剂HCI与羟乙基乙二胺摩尔比大于3,甲醛与羟乙基乙二胺摩尔比大于6时,80℃反应2h可获得收率大于77%的HEDTMP;经IR、~1H—NMR和元素分析确认合成是成功的。

In this study the incidence of acute mountain sickness was 24% for people taking 125 mg twice daily, 21% for people taking 325 mg twice daily, and 51% for people taking placebo.9

在这项研究中,急性高空病的发病率在应用乙酰唑胺125mg2次/天组为24%,在应用乙酰唑胺325mg2次/天组为21%,在应用安慰剂组为51%[9]。

Optimal process conditions for preparing N,N'-ethylenediamine diacetic acid: Potassium cyanide was combined with formaldehyde and ethylenediamine at a mole ratio of 2.4 to 2.4 to1, at temperature 18℃,and then was hydrolyzed for 8 hours.

通过单因素分析,合成N,N′—乙二胺二乙酸的最佳反应条件为:反应温度为18℃,水解时间为8 小时,甲醛∶氰化钾∶乙二胺的摩尔比为2.4∶2.4∶1。

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