乙胺

In this paper, acetanilide used as start material was chlorosulfonated, then reacted with alkylamines with different length of carbon chain to prepare 4 p-acetylaminophenylsulfonylalkylamine.

本文以乙酰苯胺为起始原料，经氯磺化后分别和不同碳链的正烷基胺反应制得4种不同碳链长度的对乙酰氨基苯磺酰烷基胺，将其水解后制得了对氨基苯磺酰正丁胺、对氨基苯磺酰正辛胺、对氨基苯磺酰正十二胺和对氨基苯磺酰正十八胺。

Methods 4-Hydroxy- benzonitrile was treated with sodium hydrogen sulfide and anhydrous magnesium chloride in dimethyl formamide to give thioamide, which was then directly cyclized with ethyl 2-chloroacetoacetate without separation to give ethyl 2-(4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(2) in one-pot; then 2 was formylated with Duff reaction adopting hexamethylenetetramine in trifluoroacetic acid to give ethyl 2-(3-formyl-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(3); finally, the target compound was obtained by the treatment of 3 with hydroxylamine hydrochloride and sodium formate in formic acid.

采用"一勺烩"方法，以4-羟基苯甲腈为起始原料，首先与硫氢化钠和无水氯化镁在N，N-二甲基甲酰胺中反应，所得中间体不经分离，直接加入2-氯乙酰乙酸乙酯进行环合反应，得到2-(4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（2）；然后通过六亚甲基四胺/三氟乙酸进行Duff反应，得到2-(3-甲酰基-4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（3）；再经盐酸羟胺/甲酸/甲酸钠体系脱水得到目标化合物。

Through using Mythylene DinitrAmine as rude product, the knowledge of its reaction properties in different phases have been increased, Through using Mythylene BisAcetAmide as rude product, intermediates which include 1,3-Diacetyl -4,5-dihydroxy -1,3-diazacyclopentane and 1,3-Diacetyl- 4,5-diacetoxy-l,3-diaza cyclopentane have been obtained. 2,4,6,8-tetracetyl- 2,4,6,8-tetraaza bicyclo[3,3,0]octane which can be used to produce Bicyclo-HMX by nitrolysis was also produced. Through using Mythylene BisFormAmide as rude product, intermediates which include 1,3-Diformyl-4,5-dihydroxy- 1,3-diazacyclopentane and 1,3-Diformyl- 4,5-diacetoxy-l,3-diazacyclopentane have been abtained.

以亚甲基二硝胺为初始原料，加深了对亚甲基二硝胺在不同反应相反应特征的认识；以亚甲基二乙酰胺为初始原料，制备了中间体1，3-二乙酰基-4，5-二羟基-1，3-二氮杂环戊烷和1，3-二乙酰基-4，5-二乙酰氧基-1，3-二氮杂环戊烷，最终制备了可被直接硝解为双环HMX的2，4，6，8-四乙酰基-2，4，6，8-四氮杂双环[3，3，0]辛烷；以亚甲基二甲酰胺为初始原料，制备了中间体1，3-二甲酰基-4，5-二羟基-1，3-二氮杂环戊烷和1，3-二甲酰基-4，5-二乙酰氧基-1，3-二氮杂环戊烷。

The process is carried out by taking organic acid and sulfoxide chloride as raw materials, acyl chloride synthesizing, reacting ethylenediamine with sodium chloroacetate to synthesize intermediate sodium EDDA, and reacting it with acyl chloride to synthesize the final product.

所述双子烷基羧酸盐表面活性剂是由以下方法制得的，以有机酸和氯化亚砜为原料首先进行酰氯的合成，再用乙二胺与氯乙酸钠反应合成中间体乙二胺二乙酸钠，将中间体乙二胺二乙酸钠与酰氯反应合成终产物。

The surface hydroxyl group onto magnetic polyvinyl acetate nanoparticles can be obtained by saponification reaction on their surface.

结果表明，磁性聚苯乙烯颗粒与丁二酸酐发生Freidel-Crafts酰基化反应，可以在颗粒表面引入少量羧基；磁性聚甲基丙烯酸甲酯颗粒分别与乙二醇、二缩三乙二醇、聚乙二醇等发生醇-酯交换反应，可以在颗粒表面接枝不同分子链长度的末端羟基；磁性聚醋酸乙烯酯颗粒经过醇解或皂化反应可以获得表面羟基；磁性聚丙烯酸甲酯颗粒通过乙二胺或1，6己二胺的胺解反应可以得到表面氨基，继而与一氯乙酸反应可以引入亚胺二乙酸基团。

Two kinds of polyaspartic acid derivates, i.e. PEG-g-PAsp and PEG-g-PDEA, were prepared through the ring-opening reaction of polysuccinimide by CH3O-PEG-NH2, followed by alkaline hydrolysis and aminolysis, respectively.

通过胺端基聚乙二醇(CH3O-PEG-NH2)开环聚琥珀酰亚胺，进一步碱解和胺解制备了聚乙二醇接枝聚天冬氨酸和聚乙二醇接枝聚乙二胺基天冬酰胺两种聚天冬氨酸衍生物。

A novel liquid crystalline compound named p-phenylenediamine di 4-[2- benzamide] was synthesized from allyl 2-hydroxyethylether, ethyl 4-hydroxybenzoate and p-phenylenediamine.

以乙二醇单烯丙基醚、对羟基苯甲酸乙酯、对苯二胺为原料合成了末端为不饱和双键的芳香聚酰胺溶致型液晶化合物——二对烯丙氧基乙氧基苯甲酰对苯二胺，最佳合成的摩尔比为∶羧酸∶对苯二胺∶吡啶=2。

Determining the dilution enthalpies of DMF and DMA in aqueous glycerol solutions of various molalities, we discussed peptide bond and hydrophobic side chains interacting with glycerol in aqueous solutions. Molecular dynamics simulating ethylene glycol and glycerol solutions have been done to study the microscopic structure of polyhydroxy compounds solutions.

本文用滴定量热法研究了298.15K下酰胺(N—甲基甲酰胺、N，N—二甲基甲酰胺、N—甲基乙酰胺和N，N—二甲基乙酰胺)分别在于MAO水溶液和尿素水溶液中的焓相互作用，探讨了溶剂变化对酰胺侧链相互作用的影响，从肽键及疏水侧链角度研究了TMAO和尿素对蛋白质稳定性的影响。

The results showed that there was a more better effect of filmformation and absorbency to use poly 1788 as an adhesive and polyvinyl pyrrolidone(K:90) as a hydrophilic polymer. The silicon dioxide with particle size 0.3-1 μm as a inorganic pigment had a better absorbency. The polyethylene glycol modified with ethylenediamine had a more better characteristic of dye immobilization, absorbency and definition than the polyethylene glycol modified with diethylenetriamine, of which the polyethylene glycol of molecular weight of 400 modifiedwith ethylenediamine had more best performance.

研究结果表明：采用聚乙烯醇1788作黏合剂、聚乙烯吡咯烷酮(K值为90)作亲水性高分子可得到比较理想的成膜效果和吸墨效果；粒径分布范围在0.3-1 μm的二氧化硅作为无机颜料具有较好的吸墨性能；用乙二胺改性的聚乙二醇比用二乙三胺改性的聚乙二醇具有更好的固墨性、吸墨效果以及清晰度，其中乙二胺改性的分子量为400的聚乙二醇所得到的烷基多胺的效果为最好。

Methods 4-Hydroxy- benzonitrile was treated with sodium hydrogen sulfide and anhydrous magnesium chloride in dimethyl formamide to give thioamide, which was then directly cyclized with ethyl 2-chloroacetoacetate without separation to give ethyl 2-(4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(2) in one-pot; then 2 was formylated with Duff reaction adopting hexamethylenetetramine in trifluoroacetic acid to give ethyl 2-(3-formyl-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(3); finally, the target compound was obtained by the treatment of 3 with hydroxylamine hydrochloride and sodium formate in formic acid.

采用&一勺烩&方法，以4-羟基苯甲腈为起始原料，首先与硫氢化钠和无水氯化镁在N，N-二甲基甲酰胺中反应，所得中间体不经分离，直接加入2-氯乙酰乙酸乙酯进行环合反应，得到2-(4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（2）；然后通过六亚甲基四胺/三氟乙酸进行Duff反应，得到2-(3-甲酰基-4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（3）；再经盐酸羟胺/甲酸/甲酸钠体系脱水得到目标化合物。

They weren't aggressive, but I yelled and threw a rock in their direction to get them off the trail and away from me, just in case.

他们没有侵略性，但我大喊，并在他们的方向扔石头让他们过的线索，远离我，以防万一。

In slot 2 in your bag put wrapping paper, quantity does not matter in this case.

在你的书包里槽2把包装纸、数量无关紧要。