乙烷基

The amphiphilic copolymer poly (MAA-SMA-PEGMA) was synthesized by the conventional free-radical copolymerization of methacrylic acid, stearyl acryate and poly methacrylate monomers.

利用功能性单体甲基丙烯酸、甲基丙烯酸十八烷基酯和聚乙二醇甲基丙烯酸酯通过常规自由基无规共聚反应，合成了两亲性共聚物Poly(MAA-SMA-PEGMA)。

The silica MSU-X type mesoporous molecular sieves were synthesized by using the polyoxyethylene stearyl ether (C18EO10) as template, the tetraethyl orthosilicate and sodium silicates as silica source, respectively.

以十八烷基聚氧乙烯醚(C18EO10)为模板剂，以正硅酸乙酯和硅酸钠分别为硅源，研究了不同pH值、反应温度、反应时间、原料比等条件下，合成的全硅MSU-X型介孔分子筛产物的结构变化规律，并通过焙烧和水热处理，考察了MSU-X介孔材料的结构稳定性。

Described in chapter 3 is the immediate application of the Clemmensen reductive rearrangement reaction to the polycyclic system as illustrated in a elaboration of the 5-6-7 tricyclie core skeleton of Stemona alkaloids in 5 steps: N-alkylation, [3, 2] -sigmatropic rearrangement, Dieckmann condensation, oxidative cyclization, reductive rearrangement, starting from ethyl pipecolinate hydrochloride.

我们以哌啶酸乙酯为起始原料，经氮烷基化，[3，2]-σ重排，Dieckmann缩合，自由基环化，6-6-6元环系到5-6-7元环系的还原重排五步反应，高收率地构筑了百部生物碱的5-6-7氮杂三环骨架，并用X射线晶体衍射法确定了其结构。

The ligand of the chiral Schiff base and acetylacetone vanadium are subjected to complexation in situ, hydrogen peroxide is taken as an oxidant, aryl alkyl thioether asymmetric oxidation reaction is catalyzed in a toluene or dichloromethane solution under low temperature or room temperature, enantioselectivity of chiral sulphoxide is 72 percent to 95 percent ee, and yield is 42 percent to 83 percent.

将上述手性西佛碱配体与乙酰丙酮氧钒原位络合，采用双氧水为氧化剂，在甲苯或二氯甲烷溶液中低温至室温下催化芳基烷基硫醚不对称氧化反应，手性亚砜的对映选择性为72％-95％ee，产率为42％-83％。

In order to obtain versatile ulitity of host molecules, three new chiral calix [4] crown ethers containing aza, thio atoms bearing two chiral sites provided by -cysteine ester were synthesized by the condensation of calix [4] arene diacid dichloride with oligoethylene glycol bridged bis-amino acid methyl ester. All new compounds were characterized by NMR, MS and elemental analysis.

以-半胱氨酸为手性源，利用多甘醇二氯醚在碱性条件下对半胱氨酸巯基进行烷基化反应，成功地合成了多甘醇醚链桥联的半胱氨酸衍生物，醚化反应后，在高度稀释条件下与对叔丁基杯[4]芳烃二乙酰氯进行双功能基缩合反应成功地合成了新型的手性杯[4]含氮、硫杂冠醚，并利用〓H NMR、MS等谱图手段对其结构进行了表征。

Finally, we discuss the preparation, characterization and application of alkylsilane and mercaptoacetoxy monolayers on ordered mesoporous titanosilicate molecular sieve.

最后，我们讨论了介孔钛硅分子筛表面烷基硅烷单层和巯基乙酰氧基单层的制备、表征及应用。

Producing glyphosate by alkyl esterification method needs a large amount of triethyl amine s which are used as catalysts.

烷基酯法生产草甘膦需要消耗大量的三乙胺作催化剂。

Respectively, glutamic acid derivatized β-CD has been synthesized with epoxy chloropropane as the intermediate, a water-insoluble yellow liquid was got after the acetylating of the by using acetic anhydride, which was used as a novel gas chromatographic CSP; A water-soluble β-CD polymer cross-linked with epoxy chloropropane has been synthesized, and the derivatives of β-CD polymer were synthesized by its alkylating and acetylating. The different β-CD derivatives were coated on silica capillary columns by dynamic method, the chromatographic properties and retention behaviors of the fused silica capillary columns were studied, the results showed that the β-CD derivatives had good stereoselectivity and separation results to some compounds, especially to various positional isomers and enantiomers.

本文还分别以环氧氯丙烷为中间体，合成了七{2，6-二-O-[3-(1，3-二羟基丙氨酸)]}-β-环糊精，再用醋酸酐将其乙酰化，得到了一种淡黄色粘稠液体，合成了一种新型的环糊精衍生物；以环氧氯丙烷作交联剂合成了一种水溶性的β-环糊精聚合物，再将其烷基化和酰基化，合成了β-环糊精聚合物的不同衍生物，用动态法将不同类型的β-环糊精衍生物涂渍在石英毛细管柱上，通过对所制备柱柱性能的测试和对一系列化合物的分离和保留行为的研究，结果表明所合成的β-环糊精衍生物对各类化合物，特别是对位置异构体和对映异构体具有较好的分离效果，显示了很强的立体选择性。

N-dodecylethylenediaminetriacetic acid is a new type of chelating surfactants, which were in need of developing non-phorus detergents.

N-十二烷基乙二胺三乙酸是一种新型螯合性表面活性剂，是应无磷洗涤剂的研发要求而问世的。

The coking and deactivation process of benzene and ethylene alkylation reaction over AB-97 zeolite has been studied systematically. The results of acceleration deactivation reaction indicate that deactivation process go through three phases, high level activity stability period, activity decline period and low level activity stability period. The mechanism of this phenomenon was analyzed by the way of the experiment research of pore structure and acid quality of coked zeolite. It is concluded that reducing the strong acid active centers and crystal outer-surface active centers are benefit to improve the activity stability of zeolite.

在AB-97型分子筛催化剂上对苯/乙烯烷基化制乙苯反应体系的结焦失活历程系统实验研究，催速失活实验结果表明失活历程经历高水平活性稳定期，活性衰退期和低水平活性稳定期三个阶段，并通过对失活催化剂的孔结构及酸性质的实验研究，对这一现象进行了机理分析，认为催化剂改性研究中采用降低强酸活性位和晶粒表面活性位这两种手段都有利于改善催化剂的活性稳定性。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。