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In this paper, acetanilide used as start material was chlorosulfonated, then reacted with alkylamines with different length of carbon chain to prepare 4 p-acetylaminophenylsulfonylalkylamine.

本文以乙酰苯胺为起始原料,经氯磺化后分别和不同碳链的正烷基胺反应制得4种不同碳链长度的对乙酰氨基苯磺酰烷基胺,将其水解后制得了对氨基苯磺酰正丁胺、对氨基苯磺酰正辛胺、对氨基苯磺酰正十二胺和对氨基苯磺酰正十八胺。

Over the AlPO〓, the deamination and dealkylation of diethylmine and triethylmine produced ethylene selectivily. Over AlPONs of acid-base bifunctional catalysts the ethylnitrol formed selectivily.

二乙胺、三乙胺在酸性的磷酸铝上选择性的脱烷基/脱氨生成乙烯,在酸碱两性的氮化磷酸铝上选择性脱烷基/脱氢生成乙腈。

Our country ethylene diamine mainly uses in producing the agricultural chemicals (woods manganese zinc, dithane Z-78, generation of woods amine and pesticide, weed killer, disinfectant), the surface active agent (lives geminate stearic acid amide, alkyl imidazole lin, double amide, with oxirane, epoxypropane synthesizes non-ionic surface active agent), the epoxy resin firming agent (polyamide resins, epoxy firming agent, hydroxyethyl ethylene diamine and so on), the wash assistant (ethylene diamine four ethanoic acid and sodium salt series chelating agents), medicine raw material (aminophylline, washes must be peaceful, nose eye only, deinsectization spirit and so on), water treatment medicinal preparation (ethylene diamine four methylene phosphonates, second grade trunk base ethylidene two phosphine acids), corrosion inhibitor dye fixing agent, photography materialFixing bath and oil dope and so on.

我国乙二胺主要用于生产农药(森锰锌、代森锌、代森胺及杀虫剂、除草剂、杀菌剂),表面活性剂(生成双硬脂酸酰胺,烷基咪唑啉、双酰胺,与环氧乙烷,环氧丙烷合成非离子表面活性剂),环氧树脂固化剂(聚酰胺树脂,环氧固化剂,羟乙基乙二胺等),洗涤助剂(乙二胺四乙酸及其钠盐系列螯合剂),医药原料(氨茶碱,洗必泰,鼻眼净,灭虫灵等),水处理剂(乙二胺四甲叉膦酸盐,乙脒基乙叉二膦酸),缓蚀剂染料固色剂,照相材料定影液及润滑油添加剂等。

By using the a device being similar to water segregator and by controlling the temperature, cyclization of the intermediate product in chloroform reduced carbonization and gave 2-dodecaneanthraquinane in 68.1% yielding.

以十二烷基苯和苯酐为起始原料,经酰基化、关环和磺化三步反应合成了3-十二烷基蒽醌磺酸;并进一步改进和优化了合成工艺条件:即在催化剂三氯化铝过量50%并有三乙胺存在的条件下,中间体2-(4-十二烷基苯甲酰基)苯甲酸收率为72.45%;关环反应采用氯仿作溶剂,利用类似分水器的装置有效控制反应温度以减少碳化,2-十二烷基蒽醌的收率为68.1%。

Reduction of 2-bromodifluoromethyl substituted propargyl vinyl ether afforded the difluorovinyl propargyl ether, which rearranged to the corresponding allene bearing a gem-difluoromethene in the mid-aliphatic chain.

第三部分,在碱性条件下,α-氟烷基乙酸乙酯与炔丙醇反应制备了一系列的氟烷基取代的炔丙基烯基醚,并研究了它的Claisen重排反应,得到了2,4-不饱和的氟烷基酮。

Water,c12-20 acid peg-8 ester,octyldodecanol,cetearyl isononanoate,butylene glycol,biosaccaride gum-1,peg-40 hydrogenated caster oil,ethylhexyl menthoxycinnamate,phenoxyethanol,potassium cetyl phosphate,macadamia ternifolia seed oil,dimethicone,carbomer,propylene glycol,glyceryl stearate,cocoglycerides,butyrospermum parkii,c12-13 alkyl lactate,methylparaben,benzophenone-3,pentadecalactone,sorbic acid,citrus aurantium dulcis oil,sodium hydroxyde,tocopheryl acetate,disodium edta,iris germanica root extract,retinyl palmitate,equisetum arvense extract,butylparaben,peg-8,propylparaben,ethylparaben,sodium hyaluronate,chlorhexidine digluconate,citrus aurantium amaraoil,tocopherol,ascorbyl palmitate,citric acid,ascorbic acid,limonene,linalool

水,c12-20 acid peg-8 ester,辛基十二烷醇,鲸蜡硬脂醇异壬酸酯,丁烯二醇,多醣物质,PEG-40氢化蓖麻油,4-甲氧基肉桂酸-2-乙基己基酯,苯氧乙醇,十六烷基磷酸钾,澳洲胡桃子油,地美司康,卡波姆,丙烯乙二醇,甘油硬脂酸,椰油脂酸甘油酯类,牛油果,c12-13烷醇乳酸酯,对羟基苯甲酸甲酯,二苯甲酮-3 ,环十五内酯,山梨酸,甜橙油,氢氧化钠,维生素E醋酸酯,乙二胺四乙酸二钠,鸢尾花萃取,维他命A酯,问荆萃取,对羟基苯甲酸丁酯,聚乙二醇- 8,羟苯丙酯,羟苯乙酯,透明质酸钠,洗必泰葡萄糖酸盐,苦橙油,维生素E ,维生素C棕榈酸酯,柠檬酸,抗坏血酸,柠檬精油,沉香醇水:几乎所有护肤品成分第一位都是水。辛基十二烷醇:界面活性剂、乳化剂、稠化剂,有一定刺激性

Silver nanoparticles with average particle size ranging from 2 to 131nm were manipulatively synthesized starting from silver nitrate using 10 kinds of different functional group-containing organic modifiers, such as polyvinylpyrrolidone, tween-80, sodium dodecyl sulfate, sodium polyacrylate, polyethylene glycol, D-sorbitol, sodium dodecyl sulfonate, sodium dodecylbenzene sulfonate, polyvinyl alcohol, cetyltrimethylammonium bromide, at room temperature.

摘 要:选择10种含有不同官能团的有机物为表面修饰剂,如聚乙烯吡咯烷酮、吐温-80、十二烷基硫酸钠、聚丙烯酸钠、聚乙二醇、山梨醇、十二烷基磺酸钠、聚乙烯醇、十二烷基苯磺酸钠和十六烷基三甲基溴化铵等,在室温下进行了平均粒径在2~131nm范围内纳米银颗粒的控制合成研究。

The results showed that there was a more better effect of filmformation and absorbency to use poly 1788 as an adhesive and polyvinyl pyrrolidone(K:90) as a hydrophilic polymer. The silicon dioxide with particle size 0.3-1 μm as a inorganic pigment had a better absorbency. The polyethylene glycol modified with ethylenediamine had a more better characteristic of dye immobilization, absorbency and definition than the polyethylene glycol modified with diethylenetriamine, of which the polyethylene glycol of molecular weight of 400 modifiedwith ethylenediamine had more best performance.

研究结果表明:采用聚乙烯醇1788作黏合剂、聚乙烯吡咯烷酮(K值为90)作亲水性高分子可得到比较理想的成膜效果和吸墨效果;粒径分布范围在0.3-1 μm的二氧化硅作为无机颜料具有较好的吸墨性能;用乙二胺改性的聚乙二醇比用二乙三胺改性的聚乙二醇具有更好的固墨性、吸墨效果以及清晰度,其中乙二胺改性的分子量为400的聚乙二醇所得到的烷基多胺的效果为最好。

Fine chemicals to add auxiliary Series: lubricating oil pour point depressant, calcium zinc magnesium methacrylate, methyl acrylic acid lauryl ester, tetradecane methacrylate ester, methacrylic acid octadecyl ester, a acid ethylene glycol, diethylene glycol methacrylic acid ester, glycidyl methacrylate, the second reduction of three ethylene glycol dimethyl acrylate, acrylic acid lauryl ester, tetradecyl acrylate, octadecyl acrylate, acrylic acid ethylene glycol, diethylene glycol acrylate esters, glycidyl, two shrink three acrylate such as ethylene glycol.

精细化工添加助剂系列:润滑油降凝剂,甲基丙烯酸钙锌镁,甲基丙烯酸月桂酯,甲基丙烯酸十四烷酯,甲基丙烯酸十八烷基酯,甲基丙烯酸乙二醇,甲基丙烯酸二乙二醇酯,甲基丙烯酸缩水甘油酯,二缩三乙二醇二甲基丙烯酸酯,丙烯酸月桂酯,丙烯酸十四酯,丙烯酸十八酯,丙烯酸乙二醇,丙烯酸二乙二醇酯,丙烯酸缩水甘油酯,二缩三乙二醇丙烯酸酯等。

L-Phenylalanine was then obtained by alkylation of N- glycine ethyl ester with benzyl bromide in the presence of an asymmetric phase-transfer catalyst-N-benzyl-cinchonine chloride, followed by hydrolysis of the resulting product.

以甘氨酸乙酯盐酸盐和二苯甲酮为起始原料合成了N-二苯亚甲氨基乙酸乙酯,后者在手性相转移催化剂-N-苄基氯化辛可宁诱导下与烷基化试剂溴化苄发生不对称相转移催化烷基化反应,水解得到L-苯丙氨酸。

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