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It have been observed that oxonium ion reacted with water more easily than with THF. So water could be used as ceasing reagent to control the molecular weight of the polymer.

本文还对四氢呋喃、环氧丁烷和环氧乙烷阳离子开环聚合反应中,分子内尾咬、扩环这一典型的副反应进行了理论研究。

When using partly or in general return-material that remains after the pre-screening operation (see step 4 of the production) the amount of added Ethanol, Iso-Hexane and paraffinic oil has to be adapted accordingly.

当部分或者普遍使用前期筛分后回收来的材料时,乙醇、异乙烷和石蜡油的数量要相应地调整。

The properties of single chain and pauci chain polystyrene microspheres and recent results on the electron microscopy and selected area electron diffraction of single chain monocrystals of polyethylene oxide, isotactic polystyrene, cis1,4 polybutadiene and gutta percha are presented and discussed.

介绍和讨论了单链和寡链聚苯乙烯玻璃体微球的性质以及聚环氧乙烷、同立构聚苯乙烯、-,4-丁二稀、-,4-异戊二烯单链单晶电子显微镜和选区电子衍射观察的最新结果。

The selectivity of phenylacetaldehyde is increased when Br〓nsted acidity is getting stronger. The selectivity of benzaldehyde can be increased by increasing the amount of extraframework titanium species.

分子筛的B酸中心强度对产物分布有着显著的影响,B酸越强,苯乙醛的选择性越高,B酸位是催化环氧苯乙烷定向重排生成苯乙醛的催化活性中心;非骨架钛物种的增加有利于苯甲醛的生成。

Deoxybenzoin(3) was prepareded by using the resorcinol and substituted phenylacetic as starting meterials in microwave-mediated.Then the compound(3) was reacted with acetic anhydride to produce(4).The compound(4) was hydrolyzed to convert compound(5) in the acid-mediated. The compound(5) was reacted with the 1,2-dibromo-ethane and 1,3-dibromo-propane in refluxed condition with acetone as solvent to give(6) or(7),respectively.Lastly,the title compounds were synthesized by refluxing(6) or(7) with 2-methyl-benzimidazole and potassium carbonate in acetone solution.

以取代苯乙酸和间苯二酚为起始原料,用微波辐射法合成脱氧安息香(3),(3)与乙酸酐缩合生成2-甲基-7-乙酰氧基异黄酮(4),(4)在酸性条件下水解生成相应的异黄酮(5),化合物(5)分别与1,2-二溴乙烷和1,3-二溴丙烷反应生成(6)和(7),化合物(6)和(7)再分别与2-甲基苯并咪唑偶合生成目标化合物。

The comparative investigation of synthesizing the polyhydric alcohols, such as pentaerythritol, pentaglycerine, trimethylolpropane, neopentyl glycol and so on are conducted, these compounds are all based on the reaction of cross-aldol condensation.

对季戊四醇、三羟甲基乙烷、三羟甲基丙烷、新戊二醇等基于交叉羟醛缩合反应的多元醇类化合物的合成进行对比研究。

Propargyl alcohol was protected by dihydrophran with the catalysis of PPTS ,and then reacted with Ethyl Mag bromide to prepare its corresponding Grignard reagent.

炔丙醇在 PPTS 催化下由二氢吡喃保护,与溴乙烷格氏试剂反应生成相应的格氏试剂,然后与氯甲酸甲酯反应得到羟基丁炔酸甲酯四氢吡喃醚,在 PPTS 催化下脱保护后进行甲磺酰化,由溴化钠进行溴取代后合成了4-溴-2-丁炔酸甲酯,总收率达53%。

Initially, we studied the ring opening of various epoxides such as styrene oxide, propylene oxide, epichlorohydrin and cyclohexene oxide with pyrazole and excellent results were obtained.

最初,我们研究了开环的各种氧化物,如环氧苯乙烷,环氧丙烷,环氧氯丙烷和环氧环己烷与吡唑和优异的成绩获得。

Especially , the rearrangement reaction of converting styrene oxide to phenylacetyldehyde were investigated. In this paper, we also studied the method of preparing SO42-/TiO2 by vitriolic titanium boiling regurgitant hydrolyzation and applications of SO42-/TiO2 in the preparation of iso-amyl acetate.

对环氧苯乙烷经分子重排反应制备苯乙醛进行了深入研究;本论文还用硫酸钛沸腾回流水解法制备了纳米SO_4~(2-)/TiO_2固体超强酸粉末,并应用于冰乙酸与异戊醇酯化合成乙酸异戊酯的反应。

The reliability of technical performance is tested through experiments and application, on which the requirements of steam sterilization, EO sterilization and residual EO removement are dependant.

通过试验和试用考核了技术性能的可靠性,确定了高压蒸汽灭菌条件及环氧乙烷灭菌和残留气清除条件。

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