乙烯醇

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明：1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体；2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明： 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体； 2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

The surface hydroxyl group onto magnetic polyvinyl acetate nanoparticles can be obtained by saponification reaction on their surface.

结果表明，磁性聚苯乙烯颗粒与丁二酸酐发生Freidel-Crafts酰基化反应，可以在颗粒表面引入少量羧基；磁性聚甲基丙烯酸甲酯颗粒分别与乙二醇、二缩三乙二醇、聚乙二醇等发生醇-酯交换反应，可以在颗粒表面接枝不同分子链长度的末端羟基；磁性聚醋酸乙烯酯颗粒经过醇解或皂化反应可以获得表面羟基；磁性聚丙烯酸甲酯颗粒通过乙二胺或1，6己二胺的胺解反应可以得到表面氨基，继而与一氯乙酸反应可以引入亚胺二乙酸基团。

The effects of feeding way of phosphorus pentoxide, ratio of C8H174OH to P2O5, reaction temperature and time on the synthesized isooctanol polyethenoxy ether phosphate were investigated. Its optimum synthesis technology conditions were as follows: feeding at batches while stirring tempestuously at 45℃, the ratio of nC8H17(EO4OH:n(P2O5)=2:1, esterifying at 70℃ for 4h, and add given volume of water at 70℃ for hydrolysing 2h.

研究五氧化磷的投料方式、反应物的用量比、反应温度和反应时间等因素对合成的异辛醇聚氧乙烯醚C8H17(EO4OH磷酸酯性能的影响，得到优化的异辛醇聚氧乙烯醚磷酸酯的合成工艺条件：在强烈搅拌下，分批投入P2O5，加料时的温度不超过45℃，nC8：H17(EO4OH：n(P2O5)=2：1，酯化温度为70℃，酯化时间为4h，在温度70℃时加入定量的水再水解2h。

The following was studied in this paper:(1) The adhesive strength of polyvinyl alcohol with different degree of polymerization and different degree of alcoholysis (2) The adhesive strength of polyvinyl acetals with different acetalization degree (3) Effects of polyvinyl acetate on adhesive strength of white glue when PVA or polyvinyl acetals was used as its protective colloid.

本文主要研究以下内容：(1)不同聚合度、醇解度聚乙烯醇溶液粘接强度；(2)不同缩醛度的聚乙烯醇缩醛溶液的粘接强度；(3)聚乙烯醇或聚乙烯醇缩甲醛为保护胶体时，聚醋酸乙烯酯乳液的粘接强度，以及研究白乳胶改性物，制备高粘度和高粘接强度的白乳胶。

Their technology and process is basically similar to that used ethylene, the raw material for the oxygen in the silver catalyst, caused by methane or nitrogen stabilizer, the existence of inhibitors of chloride, ethylene oxide directly generate ethylene oxide and ethylene B N and further to certain substances in water than in the tubular reactor for generating hydration ethylene glycol, ethylene glycol solution through evaporation to mention thick, dehydration, fractionation be ethylene glycol and other by-products.

它们的工艺技术和工艺流程基本上相似，即采用乙烯、氧气为原料，在银催化剂、甲烷或氮气致稳剂、氯化物抑制剂存在下，乙烯直接氧化生成环氧乙烷，环氧乙烷进一步与水以一定物质的量比在管式反应器内进行水合反应生成乙二醇，乙二醇溶液经蒸发提浓、脱水、分馏得到乙二醇及其他副产品。

Methanol and ethylene glycol poisoning; Methanol and ethylene glycol are both metabolised by alcohol dehydrogenase, the same enzyme that metabolises ethanol, to formic acid and oxalic acid, respectively.

甲醇和乙烯乙二醇中毒；甲醇和乙烯乙二醇二者经过乙醇脱氢酶——代谢乙醇的同一代谢分别形成蚁酸和草酸。

Methanol and ethylene glycol poison ing; Methanol and ethylene glycol are both metabolised by alcohol dehydrogenase, the same enzyme that metabolises ethanol, to formic acid and oxalic acid, respectively.

甲醇和乙烯乙二醇中毒；甲醇和乙烯乙二醇二者经过乙醇脱氢酶——代谢乙醇的同一代谢分别形成蚁酸和草酸。

Surface-active hydrophobic mono- lauryl polyoxyethylene(6)ether acrylatewas pre- pared from lauryl alcohol polyoxyethylene(6)ether and acrylate.

由丙烯酸和月桂醇聚氧乙烯(6)醚聚合得到具有表面活性的疏水单体月桂醇聚氧乙烯(6)醚丙烯酸酯。

Objective］ The research aimed to improve the comprehensive surface performance of lauryl polyoxyethylene ether (AEO3) by means of modification.［Method］ AEO3 was synthesized from lauryl alcohol and epoxy ethane, which reacted with liquid chloroacetic acid to produce modified AEC.

［目的］对月桂醇聚氧乙烯醚（AEO3）进行改性来提高它的综合表面性能［方法］用月桂醇、环氧乙烷合成月桂醇聚氧乙烯醚（AEO3），再用AEO3与液体氯乙酸反应改性合成AEC。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。