乙烯醇

- 1 - [2 -（bispheny - iodine - stannyl）vinyl] - 1 - cyclohexanol crystal structure antifumor activity

-1-[2-乙烯基]-1-环己醇；晶体结构；抗癌活性

In chapter four, molecular imprinting polymers against amino acid derivatives utilizing 2-VP+AM as combined functional monomer and trimethylolpropane trimethacrylate as tribasic cross-linker were prepared and result was compared with those with the same amino acid derivative as the imprinted molecules utilizing ethyleneglycol dimethacrylate as dibasic cross-linker. It was found that cross-link intensity of the molecular imprinting polymer is higher when TRIM was utilized and baseline separation for the imprinted molecule could be achieved. When TRIM was utilized as cross-linker more molecule is imprinted during the polymerization.

第四章采用2-乙烯基吡啶+丙烯酰胺复合功能单体，考察了三元交联剂三甲氧基丙烷三甲基丙烯酸酯烙印氨基酸衍生物的情况，并与二元交联剂乙二醇二甲基丙烯酸酯烙印相同氨基酸衍生物的情况进行了对比，发现三甲氧基丙烷三甲基丙烯酸酯交联剂在较小的用量下就可使分子烙印聚合物达到足够的交联度，实现烙印分子的基线分离。

The invention relates to a pipeline polyurea outer anticorrosive coating and the making method thereof, making heated prepolymerization reaction on dibenzo-methane diisocyanate, carbodiimide diisocyanate, polyether binary alcohol and polyether trihydric alcohol to prepare prepolymer solution A, and making end amino polyethylene oxide ether, dimethyl sulfur-based toluene diamine, diethyl diamine, iso-propyl titanate solution, polyacrylate, carbon black, titanium dioxide and lightweight calcium carbonate into solution B, and as using, respectively heating the solutions A and B to 65 deg.C and then mixing them, then quickly spraying and curing to form a coat.

本发明涉及一种管道用聚脲外防腐涂料及制造方法，由二苯基甲烷二异氰酸酯、碳化二亚胺化二异氰酸酯、聚醚二元醇和聚醚三元醇通过加热预聚反应制成预聚物的A液、由端氨基聚氧化乙烯醚、二甲硫基甲苯二胺、二乙基甲苯二胺、钛酸异丙酯溶液、聚丙烯酸酯溶液、碳黑、钛白粉和轻质碳酸钙配制而成的B液组成，使用时将A液和B液分别加热至65℃后混合，然后快速喷涂固化形成涂层。

The results showed that the addition leading to -2-phenyl-2-(2-vinylpiperidin-1-yl) ethanol 7 could proceed with good diastereoselectivity and excellent yield (95%).(3) The selective N-deprotection of -2-phenyl-2-(2-vinylpiperidin-1-yl) ethanol 2 without affecting the vinyl group in the substrate were untaken.(4) The Zip reaction for the transformation of -1-(3-aminopropyl)-3-methylazecan-2-one 8 to -7-Methyl-1, Sdiaza-cyclotetradecan-6-one 9 were undertaken. The results showed that, under controlled conditions, acceptable yields (43%) could be achieved and racemization can be minimized during the ring expansion reaction.

该合成路线与文献方法相比，反应条件较温和，也缩短了反应时间；(2)哌啶衍生物2与乙烯基格氏试剂进行加成反应的条件和立体选择性，取得了较好的结果（差向异构体比为80：20，产率95％左右）；(3)不饱和哌啶衍生物7在不影响碳碳双键的情况下去除苯基甘氨醇手性辅助基的条件；(4)具有羰基α位手性的氨基酰胺8在不同条件下经Zip重排反应转变为9的反应，控制反应条件，可使反应中消旋化减小到最小的程度。

Impact of global economic crisis on Chinese petrochemical and chemical industry and its countermove were commented: production and export of chemical industry product;ethylene item which is under construction shall postpone being put into production;recessing glycol,PTA,and polyester industrial link development;endengering neoprene rubber profession;reducing the output of tyre production;stopping or limiting the production part of units were presented.

评述了世界经济危机对中国石化和化工行业以下领域的影响：化工产品生产和出口减少；在建乙烯项目将推迟投产；乙二醇、PTA和聚酯产业链发展减速；危及氯丁橡胶行业；轮胎行业掀起减产限产潮；部分装置停产或限产。并提出了相应的对策。

Comb-shaped copolymer of polycarboxylate containing carboxyl,sulfonic groups(-SO3M),polyethylene glycol(-OC2H4-) was synthesized by monomers of sodium 2-acrylamido-2-methylpropane sulphonate,acrylic acid,polyethylene glycol monoester acrylate under certain conditions.

本文通过2-丙烯酰胺-2甲基丙基磺酸钠与丙烯酸、聚乙二醇单丙烯酸酯在一定条件下发生聚合反应合成含有羧基、磺酸基(—SO3M)、聚氧乙烯链(—OC2H4—)等侧链的高性能减水剂PC。

Used as an all purpose foot valve for multiple applications, including cold water, ethylene and glycol.

用于多种应用的底阀，包括冷水，乙烯和乙二醇。

objective: to prepare the molecularly imprinted composite membranes with propofol as template.methods: with the ultraviolet light and initiator, template molecular propofol, functional monomer methacrylate and crosslinking agent ethylenegly-coldimethacrylate formed molecularly imprinted composite membrane through polymerization on the surface of polyvinyli-dene fluoride microporous membrane.inspection of the combination of template molecule and functional monomer, characterization of the membrane surface morphology with scanning electron microscopy.results: the morphology of composite membranes was well.propofol bonded to methylacrylic acid with hydrogen bond.conclusion: the method of ultraviolet light-struck is feasible for preparation of molecularly imprinted composite membranes with propofol as template.

目的：制备异丙酚分子印迹复合膜。方法：在紫外光照和引发剂的作用下，模板分子异丙酚、功能单体甲基丙烯酸和交联剂乙二醇二甲基丙烯酸酯在聚偏氟乙烯微孔滤膜表面聚合形成分子印迹复合膜，考察模板分子和功能单体的结合特性，用扫描电镜表征膜的表面形态。结果：复合膜形态良好，异丙酚和甲基丙烯酸以氢键的方式缔合。结论：用紫外光照射法可以制得异丙酚分子印迹复合膜。

Industrial coatings are colored ACID, amino, nitro, alkyd, a vinyl chloride, such as epoxy primer, Ciqi, hammer paint, paint orange-shaped, metal flashlight paint, paint road lines such as midrange products; Lacquer coating for the vehicle, ship paint, paint bridges, electrical insulation paint, and so on; special coating that HCPE high-chlorinated polyethylene special rust paint and rust-proof, anti-corrosion series of high temperature silicone paint; decorative paint a high-polyester, dumb Light-finish, Seqi, crystal floor paint, primers, and other ancillary products transparent and within the external walls of the High ACID latex paint products.

工业涂料有各色丙稀酸、氨基、硝基、醇酸、过氯乙烯、环氧等底漆、磁漆、锤纹漆、桔形漆、金属闪光漆、道路划线漆等高中档产品；专用涂料有汽车漆、船舶漆、桥梁漆、电工绝缘漆等；特种涂料有HCPE高氯化聚乙烯特种带锈防锈防腐系列漆和有机硅耐高温漆；装饰涂料有聚酯高光、哑光清面漆、色漆、水晶地板漆、透明底漆等配套产品和丙稀酸高级内外墙乳胶漆系列产品。

It is made generally with mixed salt of triethanolamine and ammonium hydroxide, twelve-acid isopropyl alcohol amides, for malde-hyde, polyvinyl chloride, wool oil, spice, pigment and water as raw materials.

一般采用硫酸脂肪醇的乙三醇胺与氢氧化胺的混合盐、十二酸异丙醇酰胺、甲醛、聚氧乙烯、羊毛脂、香料、色料和水作为原料。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。