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The results showed that when 0.3 g of divinyl benzene was used as crosslinking agent, the crosslinking degree increased significantly from 28.26% to 90.95% with the increase of MAA amount from 4.0 mol% to 10.0 mol%, and this increase became slowly as MAA amount was more than 10.0 mol%; the particle volume expansion was increased gradually as MAA amount increased, and reached a maximum of 42.1% when 12.0 mol% of MAA was used, and perfect porous morphology inside particles was observed even when the crosslinking degree reached 95.4% at 14.0 mol% of MAA.

结果表明:在交联剂二乙烯基苯用量一定(0.3 g)的条件下,随着MAA用量从4.0 mol%增加到 10.0 mol%,聚合物交联程度从28.26%迅速增大至90.95%,当其用量超过10.0 mol%后 P x增大趋势变缓;随着MAA用量的增加,处理后胶粒体积膨胀百分率逐渐增大,在MAA用量为12.0 mol%时Δ V 达到42.1%的最大值,当MAA用量增大到14.0 mol%时,尽管 P x高达95.44%,胶粒仍具有完好的孔状结构。

The formation mechanism for the C-PPV aggregation we proposed is: complex between K+ and the crown ether derivatives in the C-PPV brings two polymer chains closer together, and the K+ ions create interpolymer bridges, forming aggregations in the solution.

本文合成了可溶的带冠醚取代基的聚苯撑乙烯,其中冠醚基团的氧原子直接连在PPV主链上苯环的2、3位,并研究了聚合物在K~+存在下的自组装形成聚集体的行为。

A second group includes those compositions, which include an organic polymeric binding material, eg, mixed cellulose esters of monobasic or dibasic acids such as cellulose acetate succinate; an addition-polymerizable ethylenically unsaturated compound, eg, vinylidene and vinyl monomers, preferably of the acrylic or alkacrylic ester type; eg, triethylene glycol diacrylate; and an addition-polymerization initiator which forms radicals under the influence of actinic radiation, eg, anthraquinone.

第二组包括那些作品,其中包括有机聚合物具有约束力的物质,例如,对一元或二元酸混合纤维素酯,如醋酸纤维素琥珀酸; 1此外,聚合ethylenically不饱和化合物,例如,偏和乙烯基单体,丙烯酸最好的或alkacrylic酯类型,如,三乙二醇二丙烯酸酯;和加成聚合引发剂的形式下光化辐射的影响自由基,例如,蒽醌。

Most of the substances in the deposit were the nonsticky calcium carbonate and fines that could adhere to the sticky contaminants and deposit together, resulting in a great deal of the deposit.

对福建南平纸厂网前压力筛处的胶粘物进行分离和分析发现,以聚醋酸乙烯酯和聚丙烯酸酯为代表的人工合成聚合物以及机械浆中的木材树脂是产生胶粘物的根本来源,但它们在胶粘物沉积中的含量只有5%左右。

Considering the low morphological stability of dye-doped polymer thin film and based on the above multi-chromophoric organic small molecules, six novel copolymers have been synthesized by the co-polymerization, in which there are three functions: 1, 8-naphthalimide as emitting moiety, oxadiazole as electron transporting moiety, and N-vinyl carbazole as hole transporting moiety.

考虑到有机小分子掺杂到聚合物膜中低的形态稳定性,我们在上面多发色团有机小分子研究的基础上,通过自由基引发共聚合成了六个新型的共聚物。在该类共聚物的侧链上含有三个功能团:1,8-萘酰亚胺单元、噁二唑单元和N-乙烯基咔唑单元。

About 70 years ago, towards the end of 1938 and at the start of 1939 to be exact, the chemist Walter Reppe, working in a BASF laboratory in Ludwigshafen, used acetylene and pyrrolidone to produce a new monomer called vinylpyrrolidone, which in turn can be transformed into the polymer polyvinylpyrrolidone.

大约70年前,对1938年底和1939年开始的,确切地说,是化学家沃尔特雷佩,在路德维希港的巴斯夫在实验室使用的乙炔和吡咯烷酮产生新的单体,工作称为乙烯基,这反过来又可以转化为聚合物聚乙烯吡咯烷酮。

In chapter four, molecular imprinting polymers against amino acid derivatives utilizing 2-VP+AM as combined functional monomer and trimethylolpropane trimethacrylate as tribasic cross-linker were prepared and result was compared with those with the same amino acid derivative as the imprinted molecules utilizing ethyleneglycol dimethacrylate as dibasic cross-linker. It was found that cross-link intensity of the molecular imprinting polymer is higher when TRIM was utilized and baseline separation for the imprinted molecule could be achieved. When TRIM was utilized as cross-linker more molecule is imprinted during the polymerization.

第四章采用2-乙烯基吡啶+丙烯酰胺复合功能单体,考察了三元交联剂三甲氧基丙烷三甲基丙烯酸酯烙印氨基酸衍生物的情况,并与二元交联剂乙二醇二甲基丙烯酸酯烙印相同氨基酸衍生物的情况进行了对比,发现三甲氧基丙烷三甲基丙烯酸酯交联剂在较小的用量下就可使分子烙印聚合物达到足够的交联度,实现烙印分子的基线分离。

After the graft reaction of ungelatinized starch, the morphology of the copolymers kept the aggregate structure of starch, and vinyl copolymer is grafted on its surface; while the gelatinized starch forms homogeneous polymer which is totally different with ungelatinized products.

结果表明,合成的淀粉接枝共聚物符合预期结构,未糊化的淀粉接枝后,聚合物保持团粒结构,表面接枝上了乙烯基均聚物;糊化的淀粉接枝后,形成了均匀的淀粉接枝共聚物。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力