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A series homopolyme of ethylene synthesised by metallocene catalyst was analyzed by the high temperature gelatin permeation chromatography. The results showed that the molecular weight distribution changed not too much when the ratio of Al/Ti ranging between 1000 and 4000, while the molecular weight distributed increased from 2.48 to 2.81 when the ratio ranging between 4000 and 7000; catalyst D had the lowest activity to be used as asymmetric metallocene catalyst; the curve of molecular weight moved much to the left with the increases of temperature and two active centres appeared when the temperature is 70℃.

通过高温凝胶渗透色谱对茂金属催化合成的一系列乙烯均聚物进行了分析,可以看出Al/Ti比从1000变到4000时,分子量分布曲线图变化不大,而从4000变到7000时,变化相当大,分布宽度从2.48增至2.81;催化剂D的活性最小,可作为非对称性茂系金属催化剂;该聚合体系分子量的大小受聚合温度的影响很明显,随温度的升高,分子量分布曲线图向左发生很大位移,在聚合温度为70℃时存在两个活性相当的活性中心。

In this study we use the oligomers of amino ethylene series as matrix and introduce dithiocarbamate group to adsorb merely heavy metal ions. Because of its special structural characteristics , dithiocarbamate can combine with a great number of heavy metal ions to produce insoluble complex compound except for alkali metals and alkaline earth metals.

本研究系将氨基乙烯系列之寡聚物(oligomers of amino ethylene series)当做基质引入只对重金属离子具有特殊螯合能力之荒酸盐,除了与碱金属及碱土族外荒酸盐与其他重金属离子都能形成不溶性错合物。

We also measured the content of indogenous IAA in different nodes in monoecium and gynoecium, and the variation of indogenous IAA and gibberellic acid at the different developing stages in cucumber after being treated with exogenous GA〓: the variation of ethylene release and the activities of ACC oxidase at the different developing stages after being treated with exogenous IAA and GA〓.

进一步比较了外源GA〓处理后,不同发育阶段雌性系黄瓜品种中的内源生长素和赤霉素含量的变化情况,结果表明:GA〓处理后的雄性化作用与降低黄瓜植株中内源生长素含量以及提高内源赤霉素含量有关,而生长素含量的降低则可能抑制了内源乙烯的释放。

Low molecular copolymers of stearyl methacrylate and methacrylic acid were used as stablizer for reverse phase emulsion polymerization.

采用具有增稠和抗电解质作用的丙烯酸聚氧乙烯酯活性单体和具有聚合稳定作用的高分子表面活性剂,通过反相乳液聚合法合成了涂料印花用丙烯酸系增稠剂。

Iron catalyst could polymerize butadiene into high vinyl polybutadiene poly(Bd with 1,2-units more than 90%.

铁系催化剂是催化丁二烯聚合生成高乙烯基聚丁二烯的一种较好的催化剂,所生成聚合物1,2-结构的含量可在90%左右。

The measuring principle, design method and configuration of the system are introduced. Then, the measuring system is calibrated by testing Lead Zirconate Titanate ceramic and Lithium Tantalate crystal with the known pyroelectric coefficients as the references. In addition, the pyroelectric coefficients of several common ferroelectric thin films such as PZT, PVDF (poly-vinylidene fluoride) and BST are tested.

介绍了该系统的测量原理、设计方法及组成,用已知热释电系数值的锆钛酸铅陶瓷及钽酸锂单晶作为参考样品对系统进行了调试,并对PZT、聚二氟乙烯及钛酸锶钡等几种常见的铁电薄膜材料的热释电系数进行了测试。

By virtue of the coordination of Cr2L (L = CO; PPh3; C3H5 BF4-) with N-vinylcarbazole, acenaphthylene and their derivatives as organic ligands, a series of organometallic complexes have been synthesized. Their spectra characterization and X-ray diffraction analysis have been performed. It is found that this kind of complexes possesses an electronic structure with highly extensive π- delocalization.

以N-乙烯基咔唑、苊烯及其衍生物作为配体与金属基团Cr2L(L = CO; PPh3; C3H5 BF4-)配位,合成了一系金属有机配合物,并对其进行了光谱表征和单晶X射线衍射分析,发现该类配合物具有高度离域的电子结构。

The design and synthesis of a new unsymmetric 2, 6-bis pyridine iron catalyst and its use in ethylene polymerization.

新型不对称结构双亚胺吡啶铁系催化剂的设计、合成及其催化乙烯聚合反应研究。

Comb-shaped polycarboxylic -type superplasticizers were synthesized with acrylic acid,mathacrylic acid,sodium allylsulphonateand methoxypolymethacrylatethrough aqueous copolymerization initiated by ammonium persulfate.

将甲氧基聚氧乙烯醚单甲基丙烯酸酯、丙烯酸、甲基丙烯酸和烯丙基磺酸钠进行水溶液共聚,合成了具有梳型结构的聚羧酸系高效减水剂。

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