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In the wet-process phosphoric acid production from the Hubei phosphate ore, one of the bothersome problems is that potassium fluosilicate and sodium fluosilicate scales are liable to form on the filtration system owing to its high potassium and sodium content, which greatly restrains the application of Hubei phosphate ore.

本文首先采用人工冷却系统模拟湿法磷酸生产的真空过滤系统冷却过程,研究垢物的析出规律,实验结果得知:垢物的主要成分为氟硅酸钠和氟硅酸钾,氟硅酸钠首先析出,结构致密,其次是氟硅酸钾,最后是二水硫酸钙,氟硅酸钠对氟硅酸钾有很强的结晶诱导作用;然后在三种生产中常用的不同的材质钼二钛、聚氯乙烯和聚四氟乙烯表面进行结垢试验,发现聚四氟乙烯表面最不易结垢,而在钼二钛表面最易结垢。

In chapter 4 an abnormal reaction that the nitro group of 1-aryl-2-nitroethenescan be easily replaced by the organic moity of FG-RZnI using Ni〓 and tertiaryamine as catalyst was first given. The experimental results show that in the presenceof catalytic amount of Ni〓 and tertiary amines, the reaction of FG-RZnI andl-aryl-2-nitroethenes give the substitution products l-aryl-l-alkene, instead ofMichael addition products.

通过实验发现,在催化量的Ni〓及叔胺催化下, l-硝基-2-芳基乙烯与烷基碘化锌并不进行Michael加成反应,而是发生1-硝基-2-芳基乙烯中硝基被取代的反应,生成了高产率的1-芳基-l-烯烃,由于此反应的原料易得、反应条件温和、产物的产率高,因而是合成l-芳基-1-烯烃的有效方法。

PE-RT is referred to as the Polyethylene Raised Temperature, it is by the ethylene monomer and 1 - octene copolymer from monomers is specifically designed for the heating system of medium-density ethylene - octene copolymer, which has a narrow molecular weight distribution , octene uniformly distributed in the polymer main chain on the special molecular structure, it retained the original PE performance and processing properties of the health advantages, but also strengthen the durability of a new type of high-temperature resin pipe.

PE-RT是Polyethylene Raised Temperature的简称,它是由乙烯单体和1-辛烯单体共聚而成的,是专门为采暖系统而设计的中密度乙烯-辛烯共聚物,其具有分子量分布狭窄,辛烯均匀分布在聚合物主链上的特殊分子结构,它既保留PE原有的卫生性能及加工性能等优点,又强化了高温耐久性的一种新型管材专用料。

This article has described the technology of application of sierozem powder and preparation of ethylene-ethyl acetate copolymeremulsion,including selection of raw materials,formulation and preparation procedure .

介绍了使用灰钙粉和乙烯-乙酸乙烯酯共聚物乳液配制VAE乳胶漆的技术,包括原材料的选用、配方和配制程序等;探讨了VAE乳液用量对涂料耐洗刷性的影响,灰钙粉用量对涂料对比率的影响以及用加速升温贮存试验和常温贮存试验测试乳胶漆的贮存稳定性的结果;综合评价了乳胶漆的性能特征和应用优势,并分析了灰钙粉提高涂料性能的原

The effects of feeding way of phosphorus pentoxide, ratio of C8H174OH to P2O5, reaction temperature and time on the synthesized isooctanol polyethenoxy ether phosphate were investigated. Its optimum synthesis technology conditions were as follows: feeding at batches while stirring tempestuously at 45℃, the ratio of nC8H17(EO4OH:n(P2O5)=2:1, esterifying at 70℃ for 4h, and add given volume of water at 70℃ for hydrolysing 2h.

研究五氧化磷的投料方式、反应物的用量比、反应温度和反应时间等因素对合成的异辛醇聚氧乙烯醚C8H17(EO4OH磷酸酯性能的影响,得到优化的异辛醇聚氧乙烯醚磷酸酯的合成工艺条件:在强烈搅拌下,分批投入P2O5,加料时的温度不超过45℃,nC8:H17(EO4OH:n(P2O5)=2:1,酯化温度为70℃,酯化时间为4h,在温度70℃时加入定量的水再水解2h。

Similar to S-adenosylmethionine decarboxylase(B26),S-adenosylmethionine methyl-transferase(B70), allene oxide synthase(B38),ethylene receptor(B96),cytochrome P450(B58) and methionine synthase (B77) were found in ovaries of Pingyi Tiancha at 1d before the blossom day,which related to plant hormone and could participate in metabolic pathways of ethylene,polyamine,jasmonate acid and gibberellin,et al.,as well as had close relationship with maturity and senescence of plants.

在平邑甜茶开花前1d的子房中发现的S-腺苷甲硫氨酸脱羧酶(B26)、S-腺苷甲硫氨酸甲基转移酶(B70)、丙二烯氧化合酶(B38)、乙烯受体(B96)、细胞色素P450酶(B58)、甲硫氨酸合酶(B77)等相似基因片段与植物体内的生长素有关,将会参与乙烯、多胺、茉莉酸、赤霉素等的代谢途径,与植物的成熟和衰老具有密切的关系。

Three kinds of CpTiCl had been synthesized when was catechol , 2, 2′-biphenol , or 2, 2′-binaphthol , respectively. In the case of CpTiCl〓, was 8-hydroxylquinoline , 2-methyl-8-hydroxyl-quinoline , and 8hydroxyl-5-nitro-quinoline , respectively.

研究表明,这三类半茂钛配合物在助催化剂MAO作用下,于30℃、0.1MPa乙烯压力下均可催化乙烯聚合,并显示较高的活性,远高于未引入非茂配体的CpTiCl〓及不含茂环的相应非茂配合物的活性,这说明同时含一个茂配体和一个非茂配体的半茂配合物是烯烃聚合的优良催化剂。

GA treatment restrained the respiration rate and ethylene production. 100mg.L-1ABA and 1000 L.L-1 ethephon evidently increased TSS and total titratable acidity acid content of green-mature fruit. The effect of ABA was more significantly than 1000 L .L-1ethephon, this suggested'ABA was the main hormone of influencing scenescence of'brumal jujube'fruit.

白熟冬枣采后冷藏过程中,内源ABA含量逐渐上升,贮藏后期有峰值出现;IAA和GA含量呈逐渐下降趋势;乙烯利和ABA处理都促进了内源ABA的积累和IAA和GA含量的下降,而ABA的作用比乙烯利明显;说明ABA调控果实的衰老是通过影响内源激素的变化而起作用的。

Due to great amount of double bond on rubber chain,a lot of intramolecular reaction occurred in the system,which made the uncontrolled cross-linked system into a controlled cross-linked copolymerization,resulting in chain growth can't go illimitably in cross-linking process.

苯乙烯和二乙烯苯共聚体系是典型的不可控制的交联聚合体系,加入天然橡胶后,通过阳离子聚合方法,生成三元共聚物线团,由于橡胶分子链上含有大量的双键,聚合体系中能进行分子内反应,使不可控的交联聚合体系成为可控的交联聚合体系,其链增长不能无限制进行,从而可以合成可溶解的交联的聚苯乙烯-二乙烯苯-天然橡胶聚合物。

Hydrophobic-hydrophilic macroporous polydivinylbenzene/polyacrylethylenediamine interpenetrating polymer networks (PDVB/PAEM IPN) were prepared by the sequential suspension polymerization method. These were composed of two networks, of which one was hydrophobic and the other was hydrophilic. The objective of this work was to study the adsorption thermodynamics and adsorption kinetics of this hydrophobic- hydrophilic IPN. The focus was on adsorption isotherms of vanillin at different temperatures, and these fit well into the Freundlich adsorption isotherm. The isosteric adsorption enthalpy, adsorption Gibbs free energies and the adsorption entropy could be calculated according to thermodynamic functions.

采用分步悬浮聚合法制备了具有疏水性能的聚二乙烯基苯(polydivinylbenzene, PDVB)为第一网,具有亲水性能的聚丙烯酰乙二胺(polyacrylethylenediamine, PAEM)为第二网的疏水/亲水大孔聚二乙烯基苯/聚丙烯酰乙二胺互穿聚合物网络(interpenetrating polymer networks, IPN),研究这类疏水/亲水IPN组成的树脂对吸附质的吸附热力学和吸附动力学;测定了该树脂对香兰素在不同温度下的吸附等温线,吸附等温线符合Freundlich等温吸附方程,利用热力学函数关系计算出了吸附焓、自由能和熵变。

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