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In chapter three, molecular imprinting chiral stationary phases against amino acid derivatives utilizing 2-vinylpyridine+acrylamide (2-VP+AM) as combined functional monomers were prepared. Comparing combined functional monomer 2-VP+AM with AM and methacrylic acid+2-VP, the former, 2-VP+AM showed higher imprinting ability. Explanation was given according to the compatibleness between the functional monomer and the imprinted molecule.

第三章系统考察了复合功能单体2-乙烯基吡啶+丙烯酰胺制备氨基酸衍生物分子烙印手性固定相的情况,发现复合功能单体2-乙烯基吡啶+丙烯酰胺烙印体系与丙烯酰胺及复合功能单体2-乙烯基吡啶+甲基丙烯酸烙印体系相比,对氨基酸衍生物表现出更好的烙印能力,验证了功能单体与烙印分子之间存在着匹配性的观点。

The results showed that the tensile strength and elongation at break of the objective silicone rubber increased with the increase of vinyl content in PDM-MVS. The tensile strength was 3.9 MPa and elongation at break was 416%, and the reinforcement effect of PS on silicone rubber was significant when the mass fraction of vinyl was 1.50%. The objective silicone rubber had microphase-separated structure consisting of PS domains uniformly dispersed within a continuous PDM-MVS matrix. The compatibility between the two phases increased with the increase of vinyl content in PDM-MVS.

结果表明,目标硅橡胶的拉伸强度和扯断伸长率均随PDM-MVS中乙烯基质量分数的增加而增大,当乙烯基质量分数为1.50%时,其拉伸强度达3.9 MPa,扯断伸长率达416%,PS的增强效果明显;目标硅橡胶具有微相分离结构,PS作为分散相均匀分布于PDM-MVS连续相中,两相的相容性随着PDM-MVS中乙烯基质量分数的增加而增强。

The second layer (10) comprises: 100 parts by weight of an acrylonitrile-butadiene rubber, said acrylonitrile rubber comprising from 20 to 65 percent by weight of bound acrylonitrile; from 3 to 20 parts by weight, per 100 parts by weight of the NBR, of at least one acid acceptor; from 1 to 10 parts by weight, per 100 parts by weight of the NBR, of at least one organophosphonium salt; and from 0.25 to 10 parts by weight, per 100 parts by weight of the NBR, of at least one amidine.

公开的是一种包含直接相互接触的第一层与第二层的软管;第一层包含从四氟乙烯、六氟丙烯、偏二氟乙烯、和全氟乙烯醚衍生的一种热塑性四元共聚物;第二层包含100重量份丙烯腈丁二烯橡胶,所述丙烯腈橡胶包含约20~约65wt%结合丙烯腈;每100重量份NBR约3~约20重量份至少一种酸受体;每100重量份NBR约1~约10重量份至少一种有机盐;和每100重量份NBR约0.25~约10重量份至少一种脒。

The amphoteric fatliquor of N-amidel- polyethylene polyamine -β-aminopropionic acid types has been synthesized by nature oil and fat reaction with polyethylene polyamine and acrylic acid .

用天然油脂、多乙烯多胺和丙烯酸合成制得N -酰胺基多乙烯多胺-β-氨基丙酸型两性加脂剂,最佳合成条件分两步的反应温度分别控制在 10 0℃及 12 0℃、两步反应时间分别为 2h和 4h ,天然油脂与多乙烯多胺及丙烯酸的物质量的比为 1:0 。

The conducting polymer Poly 3,4-Ethylene Dioxy Thiophene thin films was prepared by chemical polymerization. Fourier transform infrared and Scanning Electron Microscope were used to characterize its optical property and morphology. A gas sensor using PEDT thin film was fabricated with the assistance of interdigitated electrodes. The sensitivities of the prepared sensor to toxic NO2 and NH3 and its temperature property were studied.

采用化学聚合法制备了导电聚合物3,4-乙烯二氧噻吩膜,利用扫描电子显微镜和傅里叶变换红外光谱法对薄膜的光学成分及形貌进行了分析,采用叉指电极结构研制出了3,4-乙烯二氧噻吩薄膜气体传感器,研究了3,4-乙烯二氧噻吩薄膜气体传感器对有毒气体NO2和NH3的敏感特性以及其自身的温度特性。

Use D4 or DMC, Divinyl tetramethyl disiloxane, Tetravinyl tetramethyl cyelo tetrasiloxane were used as raw materials and Tetramethyl ammonium hydroxide as catalyst to synthesize a high molecular weight of vinyl silicone oil. Concentrate hydrosilicone oil, tetramethyl dihydro disiloxane, hexamethyldisiloxane and D4 were used to synthesize the cross linker of low-hydro silicone oil required in experiments.

以D4或DMC,乙烯基双封头,乙烯基环体等为原料,四甲基氢氧化铵为催化剂合成了不同摩尔质量的乙烯基硅油;以高含氢硅油,含氢双封头,六甲基二硅氧烷,D4合成实验所需的交联剂低含氢硅油。

The absorbency changes of both thiol and vinyl functional group were monitored independently by FTIR spectrometer during vinyl silazane photopolymerizing with ethanedithiol, Based on the results,the kenitics of reaction was studied and the convertion of both thiol and vinyl functional groups were investigated.

采用傅立叶变换红外光谱法跟踪巯基和乙烯基吸光度的变化,跟踪测定了光聚合反应过程中巯基和乙烯基的转化率,研究了乙二硫醇/乙烯基硅氮烷体系的光聚合反应动力学。

Both the PL and EL of PPV are bluish-green emitting, the molecular weight, luminescenceefficiency and brightness of which are obviously higher than the homo-polymers and thecopolymers consisted of 9, 10-anthracene vinylene reported.

初步研究结果表明,聚2,6-蒽基乙烯膜状态下的荧光发射光谱和电致发光光谱均呈蓝绿光发射,其分子量、发光效率和亮度显著高于已有报道的聚9,10-蒽基乙烯,也明显高于文献报道的9,10-蒽基乙烯与其它单体的共聚物。

The squares and young bolls of cotton were rather sen-sitive to ethylene, the percentage of squares and bolls abscised being higher withhigher concentration and longer duration of fumigation while cotton bolls of ageslonger than 16 days were resist...

棉花的蕾及幼铃对乙烯比较敏感,脱落率随乙烯浓度的增大及熏气时间的延长而增长,日令16天以上的棉铃对乙烯抗性强。

The corresponding relations between the strain of the static state and dynamic cycle load and the volume resistance of the short chopped carbon fibers, short chopped carbon mat, unidirectional carbon fibers reinforced vinyl resin composites is existed. The physical modes of these kinds of composites are also designed based on the experiment data. The resistance and strain of the short chopped fibers reinforced vinyl composites satisfy the equation of y =A + Bx + Cx~2 in the static strain test method and the short chopped mat reinforced vinyl composites is y = A + Bx.

短切碳纤维、短切碳纤维毡、单向碳纤维增强乙烯基酯树脂复合材料在静态和动态循环载荷下,应变与电阻之间有较好的对应性,同时根据实验数据,建立了不同条件下该复合材料应变和电阻变化规律的物理模型,短切碳纤维增强乙烯基酯树脂复合材料在静态拉伸时电阻与应变之间满足:y=A+Bχ+Cχ~2;碳纤维毡增强乙烯基酯树脂复合材料在静态拉伸破坏时电阻与应变之间满足:y=A+Bχ。

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