乙烯的

Part 2. Annulation reaction of 3, 4-dichlorocoumarin (1) and 3, 4-dichloromaleimide (8) by a new general annulation strategy developed in this group with 2-phenylbenzofuran (15), 3-phenylbenzofuran (16), 2, 5-diphenyloxazole (17), 2, 5-diphenylthiazole (18), 2-methyl-4-phenylthiazole (19) and 2, 3-dimethoxy-1, 3-butadiene (40) were investigated.

二。在本课题组前一阶段提出的从二氯代环烯酮与1，1-二芳基乙烯的光化反应以及光化反应中得到的环丁烷产物的连续电环化反应对3，4-二氯马来酰亚胺以及3，4-二氯香豆素进行增环反应的工作基础上，研究了3，4-二氯香豆素（1）和3，4-二氯马来酰亚胺（8）与5个α-苯基取代的环烯烃2-苯基苯并呋喃（15），3-苯基苯并呋喃（16），2，5-二苯基噁唑（17），2，5-二苯基噻唑（18），2-甲基-4-苯基噻唑（19），以及一个丁二烯——2，3-二甲氧基丁二烯（40）进行的芳香族增环反应。

When EGTA (Ca〓 chelator), Verapmil and LaCl〓(Ca〓 channel blockers) were used to treat tomato fruit at green mature and strawberry fruit at white stage with ethylene, they could reverse ethylene-induced increase in ethylene production in tomato and strawberry, PG activity, lycopene content, soluble protein content in cell wall in tomato and degradation in soluble protein in strawberry, which indicated blocking Ca〓 channel in plasma membrane or chelating Ca〓 can decrease intracellular Ca〓, further inhibite ethylene-induced maturation, ripening and senescence of fruit.

用质膜钙通道阻断剂异博定、钙通道Ca〓竞争性抑制剂以及Ca〓专一性螯合剂与乙烯一起处理绿熟期番茄果实和乳白期草莓果实，均可抑制乙烯诱导番茄和草莓的乙烯生成、番茄PG活性的提高、番茄红素含量的增加和细胞壁可溶性蛋白含量的增加以及草莓可溶性蛋白的分解，表明阻断质膜Ca〓通道或螯合胞外Ca〓以减少胞内Ca〓能抑制乙烯对果实的催熟作用，间接证明乙烯对果实成熟衰老的诱导与胞外Ca〓内流引起的胞质Ca〓浓度的增加密切相关，表明乙烯信号转导可能与钙信使有关，调节胞质Ca〓浓度可调节乙烯对果实的催熟作用。

Monochloroethylene carbonate is prepared by chlorination of ethylene carbonate with sulfuryl chioride ,a solution of monochloroethylene carbonate in ethylene carbonate is reacted with triethylamine to give vinylene carbonate.A parameter design method was applied to select the optimum synthesis conditions.63.3％ and 78％ yields superior to the conventional for monochloroethylene carbonate and vinylene carbonate were obtained respectively,and the process was also simplified .

以碳酸乙烯酯为原料，用磺酰氯作为氯化剂生成一氯代碳酸乙烯酯，三乙胺为脱卤化剂在碳酸乙烯酯溶剂中合成碳酸亚乙烯酯，对一氯代碳酸乙烯酯和碳酸亚乙烯酯制备的工艺参数进行优化，收率分别达到63.3％和78％，均超过了传统方法，且简化了工艺，缩短了反应时间，易于工业化生产。

Afterintroduction of basic electroluminescent theory of polymers and discussion of the studysituation of electroluminescent polymers and polyphenylene vinylene particularly, therelationship among structure, solubility and electroluminescent properties was studiedIn this paper, polyether-type PPV, polythioether-type PPV, and PPV containingoxadizole, biphenylene, or saturated aliphatic unit were synthesized, the monomers andpolymers were characterized as well.

在讨论了电致发光聚合物的基本发光原理并深入地分析了国内外有机电致发光聚合物尤其是聚苯撑乙烯的研究现状与发展趋势的基础上，论文着重研究了PPV衍生物的结构与它的可溶性以及电致发光特性的关系。

The main results were as follows:'Brumal jujube' with higher respiration rate, which decreased slightly after harvest, and lower ethylene production, which had not the appearance of respiration and ethylene production peak, ethephon with different concentrations all increased respiration rate and the respiration rate increased with the raise of concentration ,which suggested 'brumal jujube ' was respiratory non-climactic fruits.

结果如下：冬枣采后果实呼吸强度高并呈平缓下降趋势，而乙烯释放量较低无明显高峰出现；不同浓度的乙烯利处理增加了果实呼吸强度，处理浓度越大，果实呼吸速率越高，说明冬枣为非跃变型果实；1000μL.L~(-1)乙烯利和100mg.L~(-1)ABA处理可显著提高绿熟冬枣采后的呼吸强度，两者无明显差异，但乙烯利处理显著增加了乙烯释放量、ACC含量和ACO活性，其作用比ABA明显；GA处理抑制了果实呼吸强度和乙烯释放量的增加。

The experiment that aPplication of Put shows that Put can inhibit chlorophyll discomposing and lower POD activity; Lower concentration (about 5mmol/L) can decrease respiration rate; ethylene's synthesis result in prolonging the storage time; Higher concentration (about l0,20mmol/L) Put can activate the respiration in some degree and disadvantage to storage.

外源腐胺处理香蕉果实的实验表明，腐胺可以减缓叶绿素的降解，另外，低浓度的（5mmol/L左右）腐胺可以较好的抑制乙烯的生成和呼吸作用，延缓果实衰老，而高浓度（10、20mmol/L）则在一定程度上刺激了呼吸作用，对贮藏不利。

In this paper, a series ofmodel compounds of PPV--M-PPVs were synthesized. All of the M-PPVscontained two bridge double bonds that connect the phenyl rings. The research ontheir photooxidative degradation of the M-PPVs including mechanism and kineticswas systemetically conducted.

本文设计合成了一系列含有两个桥双键的聚对苯撑乙烯的模型化合物，并对它们的光氧化降解反应与氧化机理进行了深入系统的研究，并探讨了M-PPV在不同微环境下的发光性质，主要结果如下：一。

The preparation of avermyctin emulsions in water was achieved by mixing the surfactants polyoxyethylene (10) octylphenyl ether (OP10), polyoxyethylene styrenated phenol ether (602), and polyoxyethylene (40) castor oil ether (EL-40) with polyoxyethylene (20) castor oil ether (EL-20), separatively. Emulsion stability was investigated by analyzing the hydrophile-lipophile balance, critical micelle concentration, and surface tension. Then, the surfactants of polyoxyethylene polyoxypropylene styrenated phenol ether (1601), block copolymer (L64), and octyl phenyl polyoxyethylene phosphonate were added to the emulsion made by blending EL-40 and EL-20, separatively. The stability of the emulsions was investigated further and discussed in terms of droplet size, surface tension, and zeta potential.

首先将辛基酚聚氧乙烯醚(OP10)、苯乙烯基酚聚氧乙烯醚(602)和蓖麻油聚氧乙烯(40)醚(EL-40)分别与蓖麻油聚氧乙烯(20)醚(EL-20)复配制备阿维菌素水乳剂，从亲水亲油平衡值、临界胶束浓度、表面张力等方面分析了二元表面活性剂复配对乳液稳定性的影响；其次，在EL-40与EL-20复配基础上，将苯乙烯基酚聚氧乙烯聚氧丙烯醚(1601)，嵌段共聚物(L64)和辛基酚聚氧乙烯醚磷酸酯分别添加到乳液中，从粒径、表面张力和zeta电势等方面考察三元表面活性剂复配对乳液稳定性的影响。

It was discussed in the paper the basic electroluminescent theory of polymers as well as the current study and the development trend of electroluminescent polymers and, especially that of polyphenylene vinylene. On this basis, the relationship among structure, solubility and electroluminescent properties was studied.

本文在讨论了电致发光聚合物的基本发光原理并深入分析了国内外有机电致发光聚合物尤其是聚苯撑乙烯的研究现状与发展趋势的基础上，着重研究了PPV衍生物的结构与它的可溶性以及电致发光特性的关系。

On this basis, chosing 15w germicidal lamp with radiation centred at 253. 7nm or 15w blacklight fluorescent lamp with radiation centred at 365nm as the light source respectively, the destruction effects of trace impurities in water by photocatalytic oxidation method using TiO〓 as an immobile phase have been investigated, and the effects are contrasted with photolysis. The investigation is mounted into Phenol aqueous solution, Hydroquinone and Humic Acid aqueous solutions、three representative halohydrocarbons coexisting in main water、the comprehensive index removal of varied trace organic pollutants in main water、the removal of residual chlorine and the disinfecting action, etc..

在此基础上，选择主波长253.7nm的紫外线杀茵灯或主波长365nm的蓝黑管紫外线荧光灯作为光源，研究了TiO〓膜固定相光催化氧化法去除水中微污染物的效果，包括苯酚水溶液、对苯二酚水溶液和腐植酸水溶液的光催化氧化以及自来水中共存的三种典型的氯代烃水溶液三氯甲烷、四氯化碳和四氯乙烯的混合光催化氧化、自来水中有机物总体去除效果以及光催化去除自来水中余氯的作用和光催化的消毒作用等，并进行了光解对比实验。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。