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乙烯基

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The results showed that the thermo-sensitivity of hairy PNIPA changed obviously in the presence of hairy PAA as polyelectrolyte.4-cyanopentanoic acid dithiobenzoate as soluble reversible addition-fragmentation chain transfer agent was directly added into the above PS particles with photo-initiator on the surface and NVP or NIPA as monomer.

其次,将水溶性RAFT试剂直接引入上述光引发聚合体系,探讨连续相中RAFT试剂的存在对微球表面N-乙烯基吡咯烷酮或N-异丙基丙烯酰胺聚合的影响,考察了RAFT试剂对聚合过程中微球壳层高分子毛发厚度和单体转化率变化趋势。

Most importantly, the LUMO energies of PFCN are around 1 eV lower than those of PF, which results in the decrement of EA about 0.9 eV, indicating that the 1,2-bis( p -phenylene)-1-cyanovinylene unit has significantly improved the electron-accepting properties of the copolymer PFCN.

更重要的是,PFCN和PPhCN的最低空轨道比聚芴低近1 eV,直接导致电子亲和势降低0.9 eV。这意味着含氰基亚乙烯基共聚物的电子注入能力大大提高。

Designating any of a group of polymerized thermoplastic vinyls,such as polyvinyl chloride.

乙烯基的表示一组聚合的热塑性乙烯基中任一种的,如聚氯乙烯

The bulk and solution photopolymerization of vinyl butyl ether were studied using diph-enyl-4-thiophenoxyphenyl sulfonium salt as photoinitiator.

以二苯基-4-苯硫基代苯基硫鎓盐为光引发剂,研究了乙烯基正丁醚的本体和溶液光聚合。

The reaction takes place as soon as 3a is dissolved in solution. With the presence of a tethering terminal vinyl group bound to the vinylidene ligand, the [2+2] cycloaddition of two C=C double bonds readily occurred.

当有一乙烯基键结在丙二烯基上,分子内的两个碳碳双键会马上发生[2+2]的环化加成反应。

The chiral polymer P-1 shows strong blue fluorescence due to the extended π-electronic structure between the chiral repeating unit-6,6'-di(4-trifluoromethyl-phenyl)-2,2'-bisoctoxy-1,1'-binaphthyl and the conjugated linker 2,2'-bipyridyl group via vinylene bridge.

手性高分子P-1能发射强的蓝色荧光,这是由于手性重复单元-6,6′-二(4-三氟甲基苯基)-2,2′-二正辛氧基-1,1′-联萘和单元2,2′-联吡啶通过亚乙烯基桥连形成共轭高分子结构造成的。

The interaction between the polycation and polyanion was studied by spectrophotometry and conductometric titration.

目前研究得较多的体系是聚苯乙烯衍生物,如Ioplex 1 0 1即由聚苯乙烯磺酸钠和聚氯化乙烯基苄基三甲基铵反应而得[2 ,3] 。。。。。

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能,共由以下六部分组成:1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应;2、亚甲基环丙烷类化合物开环产物的偶联反应;3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应;4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应;5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应;6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1,3-偶极环加成反应。

The analysis shows that, the larger the mol value of ethylic sequence in high molecule chains, the higher the low-temperature viscosity, the worse the low-temperature starting performance and pumpability.

通过分析得出:随着高分子链中丙基序列所占摩尔分数的增大,低温粘度变大,低温启动和泵送性能变差;而随着乙烯基含量的增加,低温粘度下降,低温性能变好。

Dihydrojasmone was synthesized from2-hexyl-5-methyl-1,2-oxaborolane,prepared frommethyl vinyl ketone and hexene,via the homologationwith 〓 followed by PCC oxidation and intra-molecular condensation.In stead of the oxidation ofthe C-B bond of 1,2-oxaborolane,fluoride inducedhalogenation of 2-alkoxy-1,2-oxaborolane was found togive 3-halopropanol.

硼氢化甲基乙烯基酮和已烯得到的2-已基-5-甲基-1,2-氧硼杂环戊烷与〓反应,再经PCC氧化,分子内缩合得到二氢茉莉酮。1,2-氧硼杂环戊烷的C-B键除氧化断裂之外,也能够在〓或KF作用下卤化断裂成碳卤键。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。