乙烯基

Iodobenzene, bromobenzene and their derivatives reacted smoothly with n-butyl acrylate or styrene under phosphine-free reaction conditions in the presence of palladium acetate and fluoroquinolones.

碘苯、溴苯和其它芳基卤衍生物与丙烯酸丁酯、苯乙烯等取代乙烯类化合物在钯和氟喹诺酮的催化下发生Heck反应。

The polymerization reacts from the inverse emulsion . Selecting white oil as continuous medium , Span60 and TX-10 as the complex emulsifier , AM-01﹑(NH4)2S2O4 and NaHSO3 as new-type complex initiator , the copolymerization of dimethylamino ethyl acrylate methyl chloride/acrylamide was developed . The effects of the concentration of monomer﹑emulsifier and initiator﹑ temperature﹑reaction time and pH on the molecular weight﹑intrinsic viscostity﹑conversion ratio and cation degree of copolymer were studied .

以反相乳液为初始聚合体系，油酸失水山梨醇酯Span60和辛基酚聚氧乙烯醚TX-10构成复配乳化剂，白油为连续介质，AM-01、过硫酸铵和亚硫酸氢钠组成新型复合引发体系，进行丙烯酰胺/（2-甲基丙烯酰氧乙基）三甲基氯化铵的反相准微乳液共聚合，研究了单体浓度、乳化剂、反应温度、反应时间、pH等因素对聚合产品分子量、特性粘数、转化率及阳离子度的影响。

In this thesis, themethod of moments was used in modeling the graft polymerization of vinyl acetatefrom polyethylene glycol and the vinyl/divinyl atom transfer radical copolymerizationwith cross-linking.

本文运用矩方法分别对聚乙二醇接枝醋酸乙烯酯聚合体系和双烯／单烯的原子转移自由基交联聚合体系进行了深入的建模研究。

The product is in the pore structure on the graft copolymer of styrene divinyl benzene [-N amines (CH 3) 2 The ion exchange resin], the less alkaline, in the acidic, neutral and effective exchange of inorganic acid medium. and the larger size can be adsorbed molecules in aqueous solution and the use of anion.

本产品是在大孔结构的苯乙烯二乙烯苯共聚体上接枝叔胺基[-N（CH3）2]的离子交换树脂，其碱性较弱，能在酸性、近中性介质中有效地交换无机酸，并能吸附分子尺寸较大的阴离子以及在非水溶液中使用。

The protic- or Lewis acid catalyzed ring-closure of divinyl ketones (and their acid-labile precursors) pentadienylic cations is known as the via Nazarov cyclization.

质子酸或路易斯酸通过戊二烯基阳离子催化二乙烯酮的环闭合（以及它们的酸不稳定前体）这个反应被称为Nazarov环化。

Thirdly,in the view of some different results between the reaction of complexes(2)、(3)and[(Me_3Si)_2N]_3LnLi_3 with aromatic aldehydes, the reaction of 2 equiv of aromatic aldehydes with 1 equiv of lithium amide(1) catalyzed by the YCl_3 was subsequently studied,and better yields of the corresponding amides and alcohols can be isolated.These results indicated that the enolate ligand in complexes(2)、(3)may have impact on the Cannizzaro disproportionation reaction.

第三，鉴于上述配合物2、3和[(Me_3Si_2)2_N]_3LnLi_3与芳香醛反应结果上的一些差别，我们又以三氯化钇为催化剂，将两当量的芳香醛与一当量化合物1的锂盐直接进行反应，结果以较好的产率得到了相应的酰胺和醇，这说明配合物2、3中所含的乙烯醇基可能对此Cannizzaro-型歧化反应存在一定的影响。

The formation mechanism for the C-PPV aggregation we proposed is: complex between K+ and the crown ether derivatives in the C-PPV brings two polymer chains closer together, and the K+ ions create interpolymer bridges, forming aggregations in the solution.

本文合成了可溶的带冠醚取代基的聚苯撑乙烯，其中冠醚基团的氧原子直接连在PPV主链上苯环的2、3位，并研究了聚合物在K~+存在下的自组装形成聚集体的行为。

A random copolymer of poly(vinyl acetate-co-isopropenyl acetate) with number-average molecular weight of 9600 and relatively narrow molecular weight distribution （MWD, M w/ M n=2.03）was prepared by free radical copolymerization of vinyl acetate with isopropenyl acetate using AIBN as initiator.

通过自由基共聚合方法，以AIBN为引发剂引发醋酸乙烯酯和醋酸异丙烯酯共聚，得到两者的无规共聚物聚。

Octylene was synthesized via tetramerization of ethylene at the presence of a catalyst system consisted of chromium acaet as primary catalyst, methylaluminoxane as cocatalyst, bis amine as ligand under high pressure. The effects of different PNP ligands on catalyst activity and selectivity to 1-octene were investigated.

在乙酰丙酮铬、甲基铝氧烷、配体三元催化体系中，以乙烯为原料在高压下齐聚生成1-辛烯，主要考察N原子上取代基不同的PNP配体对催化剂活性及1-辛烯选择性的影响。

Used the PERCA method union tubular mobile technology basically to determine the free radical production of the ozone ethene reaction, the result has been consistent with the literature value.

采用PERCA方法结合管式流动技术测定了臭氧乙烯反应生成的自由基的产率，结果与文献值基本一致。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。