乙烯基

PVC resin, PTFE resin, fumaric acid, anthraquinone, nitroanthraquinone, paraaminophenol, melamine, cyanuric acid, sulfanilic acid, chemical inhibitor 168, azoic coupling component As, stearate, aniline, nitroaniline, pentaerythritol, chlorcosane, sodium calcium, triethylene diamine, sodium benzene sulphinate, m-phthalic acid, thiourea, aniline black dyestuffs, acid dyestuff, etc.

聚氯乙烯树脂、聚四氟乙烯树脂、反丁烯二酸、蒽醌、硝基蒽醌、对氨基苯酚、三聚氰胺、氰尿酸、对氨基苯磺酸、抗氧剂168、色酚As、硬脂酸盐、苯胺、硝基苯胺、双季戊四醇、氯？？？腊、甲酸钙、三乙烯二胺、苯亚磺酸钠、间苯二甲酸、二甲酯五磺酸钠、硫脲、油溶性苯胺黑染料、酸性黑染料等有机化工原料和中间体。

Emphasis was placed on CB-polymer interaction adjustment in order to control dispersion of carbon black aggregates in polymer matrix and obtain technical data for designing and manufacturing PTC products of practical values.

本论文在中山大学材料科学研究所有关工作的基础上，着重从聚合物基PTC材料的组成和加工工艺的角度，以炭黑填充单一低密度聚乙烯为参照体系，通过调节炭黑-聚合物基体之间的界面相互作用、控制炭黑的分散程度与分布状态，进而研究炭黑填充低密度聚乙烯/乙烯-乙酸乙烯酯共混物基PTC型复合材料，力图改善上述不足，为更好地了解这类PTC材料的结构-加工-性能之间的关系，设计和制造具有实际应用价值的PTC制品提供科学依据。

In chapter 4 an abnormal reaction that the nitro group of 1-aryl-2-nitroethenescan be easily replaced by the organic moity of FG-RZnI using Ni〓 and tertiaryamine as catalyst was first given. The experimental results show that in the presenceof catalytic amount of Ni〓 and tertiary amines, the reaction of FG-RZnI andl-aryl-2-nitroethenes give the substitution products l-aryl-l-alkene, instead ofMichael addition products.

通过实验发现，在催化量的Ni〓及叔胺催化下， l-硝基-2-芳基乙烯与烷基碘化锌并不进行Michael加成反应，而是发生1-硝基-2-芳基乙烯中硝基被取代的反应，生成了高产率的1-芳基-l-烯烃，由于此反应的原料易得、反应条件温和、产物的产率高，因而是合成l-芳基-1-烯烃的有效方法。

Poly{[2-(4-biphenylamino)phenyl]phenylenevinylene} was prep-ared with 4-nitroanline which was coupled with p-xylene,throughreduction、idionization、Ullmann reaction、bromization、condensepolymerizationto get the final product.

本文提出了两条合成聚(2-芳基苯撑乙烯)的新路线，即聚{ 2-[4-苯基]苯撑乙烯}是以对硝基苯胺为原料，其与对二甲苯经改良的Gomberg-Bachmann反应偶联、再通过还原、碘化、Ullmann反应、溴化、缩聚反应得到。

To further extend the scope of this type Cannizzaro disproportionation reaction and the reactivity of enolate ligand in complex with aldehyde,we designed to synthesis new rare earth complexes containing arylamido and.enolate mixed ligands,studied their reactivity with aromatic aldehydes for the disproportionation reaction.

为了进一步探索这种歧化反应的应用范围及配合物中作为配体的乙烯醇基与醛的反应性，我们设计合成了含胺基、乙烯醇基混合配体的新型稀土配合物，并研究了其与芳香醛的反应。

From the experiment discovered for the first time the dimethyl ether may substitute CO to take the chain-carrying agent of the peroxy free radical chemistry amplifier system, and optimized the CH_3OCH_3-NO-HO_2 chemistry amplifying system determination condition, the CH_3OCH_3 best density is 1.876 ppmv, the NO best density is 1.3ppmv, and obtained this method chain length CL=124, 5 parallel determinations densities of HO_2 are the 44.0pptv, the relatively standard deviation is smaller than 4%; Although chemistry box model computed result indicated the dimethyl ether, the ethene, the propene and the ethanol all can take the chain-carrying agent of the peroxy free radical chemistry amplifier system, and their simulation chain length all grows up compared to the CO-NO-HO_2 chemistry amplifying systems, but experiments proved the ethene, the propene and the ethanol have not suit the chain-carrying agents.

首次从实验上发现二甲醚可以替代CO作为过氧自由基化学放大系统的链传递试剂，并优化了CH_3OCH_3-NO-HO_2化学放大系统的测定条件，CH_3OCH_3的最佳浓度是1876ppmv，NO的最佳浓度为1.3ppmv，并得到了这一方法的链反应长度(CL=124)，5次平行测定浓度为44.0pptv的HO_2自由基，相对标准偏差＜4％；虽然化学盒子模式计算结果表明二甲醚、乙烯、丙烯和乙醇都能作为过氧自由基化学放大系统的链传递试剂，并且它们的模拟链长都比CO-NO-HO_2化学放大体系的链长大，但是实验证明乙烯、丙烯和乙醇不适合作为过氧自由基化学放大系统的链传递试剂。

In this paper, the orthogonal experimental analysis method is used to study on the effects of molar ratio of the unsaturated vinyl monomers, with carboxylic groups or sulphonic groups or polyoxyethylene side chain groups,etc., and the effects of the mean degree of polymerization in PEO side chains.

根据聚羧酸系高效减水剂的结构特点，采用正交试验分析法，分别研究了带羧基、磺酸基、聚氧化乙烯链酯基等活性基团的不饱和单体的物质的量之比及聚氧化乙烯链的聚合度等因素对聚羧酸系减水剂性能的影响，从而得出合成聚羧酸系高性能减水剂的一种最佳配方，并对试制产品进行了性能试验。

By way of orthogonal testing analysis,study was carried out on effects of molar ratio of unsaturated monomers with carboxylic groups,sulphonic groups,polyoxyethylene side chain groups and mean degree of polymerization of polyoxyethylene side chain groups on performance of polycarboxylic series of water reducer.

采用正交试验分析法，研究了带活性基团羧基、磺酸基、聚氧化乙烯链基等不饱和单体的摩尔比及聚氧化乙烯链的聚合度等对聚羧酸系减水剂性能的影响，提出一种合成聚羧酸系高性能减水剂的最佳配方。

Both the PL and EL of PPV are bluish-green emitting, the molecular weight, luminescenceefficiency and brightness of which are obviously higher than the homo-polymers and thecopolymers consisted of 9, 10-anthracene vinylene reported.

初步研究结果表明，聚2，6-蒽基乙烯膜状态下的荧光发射光谱和电致发光光谱均呈蓝绿光发射，其分子量、发光效率和亮度显著高于已有报道的聚9，10-蒽基乙烯，也明显高于文献报道的9，10-蒽基乙烯与其它单体的共聚物。

The main products are SF-1 (as the base plate of the middle sintering Copper Balls powder, surface modified PTFE); SF-2 (plate as the base of the middle sintering Copper Balls powder, surface modified POM); JDB (For brass, bronze, iron-based body, inlaid solid lubricant); dual-metal (steel as the base for the various models of the surface of copper); production of various enterprises have also filled with PTFE, the curve of bearings, bearing powder metallurgy, by Chun-for the Pistons, Piston Ring, ethylene tetrafluoroethylene ring, ring.

主要产品有SF-1（钢板为基体中间烧结铜球粉，表面为改性聚四氟乙烯）；SF-2(钢板为基体中间烧结铜球粉，表面为改性聚甲醛)；JDB（为黄铜、锡青铜、铸铁为基体，镶嵌固体润滑剂）；双金属（钢板为基体表面为各种型号铜）；企业还生产各种填充四氟带、曲线轴承、粉末冶金轴承、减震器活塞、活塞环、四氟乙烯密封圈、环。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。