乙烯基

Precipitation of indeformable or deformable reinforcing filler into thevinyl-terminatied polydimethysiloxaneprior to or after endlinkinginto silicon networks were observed by the hydrolysis of siloxane compoundas well as the comparison between their reinforcing effects.

本文通过硅氧烷水解的途径对乙烯基封端的聚二甲基硅氧烷在交联前后导入不变形或可变形的补强填充剂的新方法进行了研究，并此较了它们的补强性能。

By desigh,the flame spreading index of the high inflaming retarding ethylene products is below 10,which meets the requirements of engineering fire resistance for safety.

通过设计，高阻燃乙烯基制品的火焰传播指数达到10以下，可以满足工程防火要求，以保证安全。

In the polymerization procedure,S--α-phenyl ethylamine was used as target template molecules,methacrylic acid was selected as functional monomers, ethylene glycol dimethacrylate or divinylbenzene as crosslinker, azobisisobutyronitrile or benzophenone was used as irritator.

以S--α-苯乙胺为模板，甲基丙烯酸为功能单体，分别以二甲基丙烯酸乙二醇酯、二乙烯基苯为交联剂，偶氮二异丁睛或二苯甲酮为引发剂，采用了本体聚合法、悬浮聚合法合成了一系列的S--α-苯乙胺印迹聚合物。

Two cyclohexanes were first reported in Murraya.

主要成分3，4-二乙烯基-3-甲基环己烷在本属其它种未见报道。

The possible mechanism was discussed. These bowl-shaped aggregates are promising candidates for nano reactor or drug carrier.4 2,7-dimethylene-1,4,6-trioxaspiro[4, 4]nonane with two vinyls was prepared to be used as electron-donor and crosslinker. The ATRP of this crosslinker and excess methylacrylate (used as electron-accpetor) was proved to mainly form homopolymers. With the chain-transfer agent S-1-Dodecyl-S\'-(α,α\'-dimethyl-α-acetic acid)trithiocarbonate, the copolymerization of the spiro hydrocarbon, maleic anhydride and MA by RAFT method produced star PMA.

这些由聚电解质复合物自组装形成的聚集体，在微反应器和药物释放等领域具有潜在的应用前景。4合成了双乙烯基的2，7-二亚甲基-1，4，6-三氧杂螺环烷，作为给电子单体和交联剂，与吸电子单体马来酸酐或过量的丙烯酸甲酯形成电荷转移络合物共同聚合，尝试了用ATRP和RAFT方法一步法合成星形聚合物。

The Suzuki reaction, the coupling of organoborate compounds with organic electrophiles catalyzed by Palladium complexes, is a valuable Csp2-Csp bond forming reaction. The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of phenylboronic acid with benzyl halides catalyzed by Pd(PPh3)2Cl2 DMF/H2O(v/v=10 : 2) was first reported.

第四章：微波辐射下Pd配合物催化端烯与芳卤偶联反应研究本章中我们在微波辐射条件下，研究了PdclZ(P Ph3)：催化端烯与芳卤的偶联反应，合成出了七种乙烯基化合物；并分别考察了微波辐射功率、辐射时间、原料配比、和PTc等因素对反应的影响，优选出了较佳的反应条件，并根据文献及实验结果，讨论了可能的反应机理。

In this article, star-high vinyl content polybutadiene was prepared using a multi-functional organolithium anionic initiator by " one-step " process. On the basis of 250ml glassware experiment ,we improved the experiment in 2L metal kettle. The polymerization condition was got as follows: polymerization temperature : 50-60 ℃, monomer content : 8-llg/100ml, polymerization time : 3~4 hours.Chracterizations were carried out by 'H-NMR, IR and GPC.

本文首次采用多官能团有机锂引发剂一步法合成出了星型高乙烯基聚丁二烯，在250ml玻璃瓶的基础上，进行2L金属斧的扩大实验，确定了以下聚合工艺参数：聚合反应温度：50～60℃，单体浓度：8～11g／100ml，聚合反应时间：3～4小时。

About 70 years ago, towards the end of 1938 and at the start of 1939 to be exact, the chemist Walter Reppe, working in a BASF laboratory in Ludwigshafen, used acetylene and pyrrolidone to produce a new monomer called vinylpyrrolidone, which in turn can be transformed into the polymer polyvinylpyrrolidone.

大约70年前，对1938年底和1939年开始的，确切地说，是化学家沃尔特雷佩，在路德维希港的巴斯夫在实验室使用的乙炔和吡咯烷酮产生新的单体，工作称为乙烯基，这反过来又可以转化为聚合物聚乙烯吡咯烷酮。

The in vitro degradation of the crosslinked composites formed by unsaturated polyphosphoester N-vinyl pyrrolidone and β-tricalcium phosphate was investigated and the surface morphology of degradation sample was imaged by scanning electron microscopy.

研究了不饱和聚磷酸酯、N-乙烯基吡咯烷酮与β-磷酸钙交联复合体系的体外降解过程，并用扫描电镜观察了降解一定时间后试样表面的形貌结构。

The in vitro degradation of the crosslinked composites formed by unsaturated polyphosphoester、N-vinyl pyrrolidone and β-tricalcium phosphate was investigated and the surface morphology of dagradation sample was imaged by scanning electron microscopy.

研究了不饱和聚磷酸酯、N-乙烯基吡咯烷酮与β-磷酸钙交联复合体系的体外降解过程，并用扫描电镜观察了降解一定时间后试样表面的形貌结构。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。