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乙烯

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In this paper, the affect of pressure to the synthetic reaction of vinyl acetate was systematically summarized.

介绍了压力对合成醋酸乙烯反应的影响,提出了合成醋酸乙烯系统加压提高收率的实施方法,分析了加压后的经济效益。

Anilido-imino nickel complex 1 {(C6H3Me2-2,6)N=CH-5-NO2-C6H3N (C6H3Me2-2,6)}NiBr was first synthesized, and its catalytic behavior toward polymerizations of norbornene and ethylene in the presense of methylaluminoxane were investigated in detail. The complex activated with methylaluminoxane exhibited high activities for norbornene polymerization.

首次合成了苯胺基亚胺镍配合物1{(C6H3Me2-2,6)N=CH-5-NO2-C6H3N(C6H3Me2-2,6)}NiBr,研究了其在助催化剂甲基铝氧烷的作用下对降冰片烯、乙烯的均聚以及对降冰片烯和乙烯的共聚的催化性能。

Sucrose vinyl adipoyl ester was synthesized from sucrose and divinyl adipate in organic solvents using an immobilized alkaline proleather.

用固定化蛋白酶FG-F在有机溶剂中催化蔗糖和己二酸二乙烯酯合成了蔗糖己二酸单乙烯酯。

Aims We investigated aerenchyma formation in stems of riparian plants Arundinella anomala and Salix variegate as affected by addition of ethylene and a-naphthalene acetic acid under non-flooded conditions in order to ascertain whether phytohormone ethylene and auxin are direct stimuli for aerenchyma formation in flooded plants.

为了探究乙烯和α-萘乙酸是否是水淹环境条件下植物体内通气组织形成的直接原因,对三峡库区岸生植物野古草和秋华柳在无水淹环境条件下施加乙烯利和α-NAA后茎中通气组织的形成情况进行了研究。

The effects of above-mentionedconditions on alkylene reaction are studied to obtain the optimum reactive conditionsby orthogonal experiments having seven factors and three levels. GCLE is chosen as material to prepare 7-phenyl acetamideyl vinyl cephalkyl acidp-methoxy benyl eatsr in the experiment. The process is as follow: GCLE reacts withiodide in solvent, and produce 3-iodid, then reacts with PPh_3 to produce Witting agent,and reacts with HCHO to produce 7-phenyl acetamideyl vinyl cephalkyl acid p-methoxy benyl eatsr in alkaline conditions.

试验选用GCLE作为原料制备7-苯乙酰氨基-3-乙烯基头孢烷酸对甲氧苄酯,反应过程如下:GCLE与碘化物、PPh3在溶剂中反应生成3位膦盐,在碱性条件下生成Wittig试剂再与HCHO反应生成7-苯乙酰氨基-3-乙烯基头孢烷酸对甲氧苄酯。

PVC resin, PTFE resin, fumaric acid, anthraquinone, nitroanthraquinone, paraaminophenol, melamine, cyanuric acid, sulfanilic acid, chemical inhibitor 168, azoic coupling component As, stearate, aniline, nitroaniline, pentaerythritol, chlorcosane, sodium calcium, triethylene diamine, sodium benzene sulphinate, m-phthalic acid, thiourea, aniline black dyestuffs, acid dyestuff, etc.

聚氯乙烯树脂、聚四氟乙烯树脂、反丁烯二酸、蒽醌、硝基蒽醌、对氨基苯酚、三聚氰胺、氰尿酸、对氨基苯磺酸、抗氧剂168、色酚As、硬脂酸盐、苯胺、硝基苯胺、双季戊四醇、氯???腊、甲酸钙、三乙烯二胺、苯亚磺酸钠、间苯二甲酸、二甲酯五磺酸钠、硫脲、油溶性苯胺黑染料、酸性黑染料等有机化工原料和中间体。

Emphasis was placed on CB-polymer interaction adjustment in order to control dispersion of carbon black aggregates in polymer matrix and obtain technical data for designing and manufacturing PTC products of practical values.

本论文在中山大学材料科学研究所有关工作的基础上,着重从聚合物基PTC材料的组成和加工工艺的角度,以炭黑填充单一低密度聚乙烯为参照体系,通过调节炭黑-聚合物基体之间的界面相互作用、控制炭黑的分散程度与分布状态,进而研究炭黑填充低密度聚乙烯/乙烯-乙酸乙烯酯共混物基PTC型复合材料,力图改善上述不足,为更好地了解这类PTC材料的结构-加工-性能之间的关系,设计和制造具有实际应用价值的PTC制品提供科学依据。

At first, the rought C〓F〓 mixed gases are obtained by pyrolysis process of R22. A experimental pyrolysis device is designed and made by ourself. The optimum operating conditions are offered in the paper. Secondly, the much efforts is on the synthesis of R134. After through the discussion of basic thermodynamics and kinetics, selecting and preparating catalyst, it is possible that the synthesis of R134 by pyrolyzed gases hydrogenation. Base on the character of catalytic process, the kinetics equation about C〓F〓 catalytic hydrogenation is established. The rate constant of the reaction is obtained through experiment data regression. In order to achieve higher yield of R134, some optimum technological conditions is determined.

论文首先对R22裂解制成四氟乙烯混合原料气的裂解过程进行了讨论,自行设计和制作裂解反应装置,并确定裂解反应的最佳操作条件;然后,重点对R134的合成进行基础研究,分别从热力学和动力学的角度探讨以含四氟乙烯的R22裂解混合气为原料合成R134这一全新工艺的可能性,选择和制备加氢催化剂,根据催化过程特点建立四氟乙烯催化加氢反应的总包动力学方程,并在此基础上自行设计和制作中试合成装置,获得了以裂解混合气为原料合成R134的最佳工艺条件,为R134的工业化生产提供了必要的理论依据和实验基础。

DETERMINATION OF VINYL IN VINYL CHLORIDE ACETATE COPOLYMERS.

乙烯一乙酸乙烯共聚物中醋酸乙烯的测定

The corresponding relations between the strain of the static state and dynamic cycle load and the volume resistance of the short chopped carbon fibers, short chopped carbon mat, unidirectional carbon fibers reinforced vinyl resin composites is existed. The physical modes of these kinds of composites are also designed based on the experiment data. The resistance and strain of the short chopped fibers reinforced vinyl composites satisfy the equation of y =A + Bx + Cx~2 in the static strain test method and the short chopped mat reinforced vinyl composites is y = A + Bx.

短切碳纤维、短切碳纤维毡、单向碳纤维增强乙烯基酯树脂复合材料在静态和动态循环载荷下,应变与电阻之间有较好的对应性,同时根据实验数据,建立了不同条件下该复合材料应变和电阻变化规律的物理模型,短切碳纤维增强乙烯基酯树脂复合材料在静态拉伸时电阻与应变之间满足:y=A+Bχ+Cχ~2;碳纤维毡增强乙烯基酯树脂复合材料在静态拉伸破坏时电阻与应变之间满足:y=A+Bχ。

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