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乙炔基

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In the thesis, the nonlinear optical properties and the thermochromism of the azobenzene functional polydiacetylenes were investigated detailedly.

本论文通过改变间隔基长度和偶氮苯环取代基以及连接方式的方法,将光响应性偶氮生色团引入聚二乙炔。

We gained the ethynylferrocene in high yield by the the reaction of triphenylphosphine with chloroform or bromoform in the presence of KOBu~t to give witting reagent, which reacted with formylferrocene and then followed by n-butyllithium dehydrohalogenation.

在本论文的第二部分,我们用三苯基磷与溴仿或氯仿在叔丁醇钾作用下,制得三苯基磷甲叉烯,然后与二茂铁甲醛反应,得到二氯取代烯烃,在正丁基锂作用下得到二茂铁乙炔。

Benzene and acetylene formation in n-heptane/air partially premixed counterflow flame was simulated using a detailed mechanism including 108 species and 572 elementary reactions.

采用详细反应机理对正庚烷部分预混对冲层流火焰中苯环与乙炔的生成进行了模拟,反应机理包括108种组分的572个基元反应。

Our company has different types of cobalt-base alloy powder, which can meet the requirements of laser cladding for plasma surfacing and oxyacetylene flame welding.

我公司生产的钴基合金粉,既有适合等离子堆焊的、激光熔敷的,也有适合氧乙炔焰喷焊的,下面介绍的钴基喷焊合金粉,采用塑料桶和铁桶封装,但由于粉末颗粒较细,极易吸潮,建议用户在使用前经120℃保温两小时烘干后使用为佳。

Syntheses of PPVs derivatives with alkoxyl as side-chain by the method of dehalogenating condensation reaction Those PPV derivatives, named poly (2-methoxy-5-alkoxyl) phenylene vinylene,containing alkoxyl on benzene ring, were placed on emphasis in this paper.

一。通过强碱诱导的去卤缩合法合成支链含不同烷氧基的PPV衍生物本文首先重点研究了支链中含不同链长烷氧取代基的PPV衍生物:聚(2-甲氧基-5-烷氧基)对苯乙炔。

Unsaturated alkynyl alcohols, such as dehydronerolidol, dehydrogeranyllinalool, and dehydroisophytol, were prepared by ethynylation of turpentine derivatives, namely terpenylacetones, e. g. geranylacetone, farnesylacetone, and phyton under normal pressure in presence of alkali metal hydroxide and organic solvents.

松节油衍生物格萜烯基丙酮,如香叶基丙酮、金合欢基丙酮和植物酮在常压条件,碱金属氢氧化物和有机溶剂存在下可发生乙炔化反应,形成对应的α,β-不饱和炔醇化合物脱氢橙花叔醇、脱氢香叶基芳樟醇和脱氢异植物醇。

By dehydrochlorination reaction the poly[(2-methoxyl-5-octyloxy)phenylene vinylene] is synthesized and the material"s structure is characterized by nuclear magnetic resonance spectroscopy, infrared absorption spectrum, ultraviolet and visible spectrophotometry. At the meantime, the fluorescence spectrum is measured and the mechanism of fluorescence occurring is analyzed. Thermal Gravimetric Analyzer"s results show that the MO-PPV"s thermal stability is fine. Also the experiment of resolvable property indicates that the MO-PPV can well dissolve in chloroform. Through analyzing the film"s surface by Metaloscope and Atomic Force Microscope, the good filming is found.

通过脱氯缩合法合成了聚(2-甲氧基-5-辛氧基)对苯乙炔,并分别用核磁共振波谱法、红外吸收光谱法、紫外-可见分光光度法等对其进行了结构表征;测量了样品的荧光光谱,分析了荧光产生的机理;热失重仪分析了材料的热稳定性,研究表明MO-PPV材料具有良好的热稳定性;溶解性实验发现材料在氯仿中溶解性较好;金相显微镜和原子力显微镜研究了薄膜的表面形貌,发现该材料的成膜性良好;材料的导电性研究表明,固体材料在掺杂下才可以表现出导电特性,而配成溶液的材料导电性因溶剂的不同而不同,并随溶解时间的长短发生变化。

Therefore, the pre-fabricated functional surface containing azide groups can be covalently anchored through click-chemistry by newly designed acetylene-appended HBCs. These HBC derivatives not only possess the potential in the formation of SAM, but their alignment modes of edge-on or face-on could be controlled by tailor-made molecular design.

因此,我们设计出末端带有乙炔官能基之HBC分子,希望在预先处理并带有叠氮(-N3)官能基的基板表面上进行click-chemistry (速配组合式化学、点击化学),利用共价键之形式将HBC分子镶嵌於基板表面,除了藉此制作出分子自组装单层薄膜之外,利用分子设计进一步控制其排列方式为edge-on或是face-on。

This paper determined Li+ content of LiFePO4/C composite by air-acetylene flame atomic Absorption spectrum method,recovery rate of standard series sample with Fe2+ and PO3-4 and without Fe2+ and PO3-4 were determinated.

采用空气-乙炔火焰原子吸收法测定了LiFePO4/C复合物中的锂含量,考察了不加基体和加入基体的两种标准系列的回收率;因为目前还没有LiFePO4的标准样品和标准分析方法,所以实验采用模拟标准样品考察了不同酸介质和不同酸用量的影响,并进行了Fe2+、PO34-、Cr3+、Mg2+、Mn2+、Co2+、Ni2+离子对测定锂的干扰实验。

The target molecules were synthesized through a Sonogashira coupling reaction of 1-trans-4-(trans-4-n-pentylcyclohexyl)cyclohexylacetylene and 4-iodo-2,3-difluoro- phenyl ether with total yields of 27%~28%.

目标化合物采用1-trans-4-(trans-4-正戊基环己基)环己基乙炔与4-碘-2,3-二氟苯基醚进行Sonogashira偶联反应制备,反应总产率27%~28%。

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