乙炔基

An electron-rich acetylide ligand would render the metal center more electron-rich and hence raise the dπ orbital energy, leading to decrease energy of the MLCT excited state.

证明通过改变乙炔基配体取代基的电子效应，能够调节最低激发态MLCT态的能量。

Alkylation of Acetylide Anions.

乙炔基离子的烷基化。

A series of crosslinkable alternating polys containing pendant phenylethynyl groups were synthesized via aromatic nucleophilic substitution reaction. The resultant polymers show good solubility in ordinary organic solvents.

以耐高温高性能树脂-聚芳醚酮作为研究对象，从改善材料的加工工艺性及提高材料的使用温度出发，对含有苯乙炔基的交替共聚物进行了系统研究。

A nonlinear regression is adopted to analyze the changes of plasma vitellogenin concentration in crucian carp via the environmental pollutant exposure concentration, and the concentration-response relationship is determined for the single chemical of estradiol (E2), ethynylestradiol (EE2), bisphenol A, 4-tert-octylphenol, and that of the mixed compounds at equipotent concentrations, the mixture being tested using a fixed-ratio design.

通过对鲫鱼血浆卵黄蛋白原含量的相对变化和暴露浓度的非线性回归分析得出17α-乙炔基雌二醇(EE2)、17β-雌二醇(E2)、双酚A、辛基苯酚及其等毒性固定浓度比例混合物产生雌激素效应的剂量－反应关系；应用相加作用数学模型根据单个化合物的数据预测混合物效应。

A gas chromatographic-mass spectrometric method for the simultaneous determination of environmental estrogens (including 4-nonylphenol, bisphenol A,diethylstilbestrol and 17α-ethinylestradiol) and endogenous estrogens (including 17α-estradiol, 17β-estradiol, estriol and estrone) in urine and bed mud is reported.

报道了尿及河底泥中环境雌激素(壬基酚、双酚A、己烯雌酚、17α-乙炔基雌二醇)和内源性雌激素(17α-雌二醇、17β-雌二醇、雌三醇、雌酮)的气相色谱-质谱测定法。

To investigate the pollution levels, occurrence and distribution of estrogens, six estrogens in the surface sediments of Wenyuhe River were analyzed quantitatively by GC/MS following ultrasonicated extraction including diethylstilbestrol, estrone(E1),β-estradiol(E2), 17α-ethynylestradiol(EE2), estriol(E3), and β-estradiol 17-valerate. Six estrogen concentrations ranged from 0.39-36.6ng/g and the mean concentration was 10.2ng/g.

为了调查温榆河沉积物中雌激素物质的污染状况，采用超声萃取、GC/MS法研究了6种常用雌激素（包括己烯雌酚DES、雌酮E1、雌二醇E2、乙炔基雌二醇EE2、雌三醇E3和戊酸雌二醇EV）在北京温榆河上游及干流表层沉积物中的含量水平，并对其分布及来源情况进行了分析。

A self-assembled monolayer film of tolane was fabricated in aqueous solution by using silane coupling agent.

用硅烷偶联剂3-氨丙基－三乙氧基硅烷，通过自组装反应在石英基板表面制备了含有二苯乙炔基的自组装单层膜。

In this paper,- and (5)-2,2'-diethynyl-1,1'-binaphthyl with highly stable chiral configurations were employed as structural templates, and a new type of helical cyclophane compounds-3 and-3 were synthesized in enantiopure form by the introduction of benzyl sulfone through Sonogashira coupling reaction, followed by the treatment of disulfone with lithium diisopropylamide.

基於2，2'-二取代的联萘衍生物在手性构型上高度稳定的特点，分别从光学活性的-和-2，2'-二乙炔基-1，1'-联萘结构模板出发，通过Sonogashira偶连反应导入苄基碸，然后用二异丙基氨基锂处理制得的联萘二碸成功地合成了一种新的螺旋环芳分子－对映异构体-3和-3。

Seven 1-phenyl-(4-pyridinyl)acetylene derivatives were conveniently synthesized in this paper using corresponding styrylpyridines as starting materials by bromination, rearrangement and debromination.

本文采用简单易行的方法从苯乙烯基吡啶类衍生物通过溴化、重排和脱溴化反应合成了7种苯乙炔基吡啶类单体，研究了它们在1mol/L盐酸水溶液中的光环加成反应。

Thestercoselectivity of the reaction of propargylide was different completely from that of the reactionof telluronium 3-trimethylsilylalltide with α,β-unsaturaled ketones and trans-trimethysilylacetylenyl-l-benzoyleyelopropane derivatives were obtained.

发现这一反应的立体化学与同样条件下含硅烯丙基碲叶立德和α，β-不饱和酮反应的立体化学完全不同，得到的是又式-2-三甲基硅基乙炔基-1-酮基环丙烷衍生物。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。