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乙炔

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The energy of excited state depended on the nature of different cations. 3. 4-(4-tolyl)-6-phenyl-2, 2'-bipyridine platinum acetylide complex containing a monoazazcrown moiety in the acetylide ligand could signal Mg〓 specifically and displayed large changes both in color and in luminescence intensity upon complexation with Mg〓. The most striking result was that it could signal Mg〓 specifically even in the presence of alkali and alkaline earth metal ions in high concentrations.

对位带有氮杂-15-冠-5冠醚的苯乙炔为辅助配体的4-(4-甲基苯基)-6-苯基-2,2'-联吡啶Pt络合物AC,不仅在碱金属和碱土金属的存在下吸收光谱明显改变,更有意义的是,它只有在Mg〓离子存在时能够发光,因此可以通过发射光谱选择性的识别Mg〓,尤其可以在高浓度的其它金属离子存在下选择性的检出Mg〓离子。

An electron-rich acetylide ligand would render the metal center more electron-rich and hence raise the dπ orbital energy, leading to decrease energy of the MLCT excited state.

证明通过改变乙炔基配体取代基的电子效应,能够调节最低激发态MLCT态的能量。

Alkylation of Acetylide Anions.

乙炔基离子的烷基化。

ABSTRACT Homopolymerization and copolymerization of substituted acetylenes with different polarity by the transition metal acetylide complex catalysts PPO, Pd (PPh〓〓〓; PPB, Pd〓 C≡CC (CH〓〓OH 〓etc.

首次以过渡金属钯-炔配合物为催化剂(PPO,Pd〓〓;PPB,Pd〓〓等),实现了具有不同极性取代乙炔单体的均聚和共聚。

A series of crosslinkable alternating polys containing pendant phenylethynyl groups were synthesized via aromatic nucleophilic substitution reaction. The resultant polymers show good solubility in ordinary organic solvents.

以耐高温高性能树脂-聚芳醚酮作为研究对象,从改善材料的加工工艺性及提高材料的使用温度出发,对含有苯乙炔基的交替共聚物进行了系统研究。

Calcium carbide production, dissolved acetylene, self-diol, has been acetylenic diol, a hybroxybutyric alcohol, methyl amyl alcohol, without the others methyl diol and other products.

主要生产碳化钙、溶解乙炔、己二醇、己炔二醇、甲基丁炔醇、甲基戊炔醇、不带甲基的己二醇等产品。

Of acetylene. And of three cyanobacteria, nitrogenase of Anabaena flos-aquae was most easily to be affected by the two herbicides.

在10%最佳乙炔浓度下,3种固氮蓝藻固氮酶对单嘧磺隆、单嘧磺酯表现出了不同的耐受性,其中水华鱼腥藻固氮酶活性最易受到除草剂的影响。

It should also be remembered that it is antipyretic due to its conent of polyacetyene.

值得注意的是,由于它的结构是聚乙炔,它有退热的效果。

All sorts of specialized valves, flame arrestor and other accessories used for acetylene especially

乙炔专用的各类阀门、阻火器等配件;——各种气体充装汇流排。

In the thesis, the nonlinear optical properties and the thermochromism of the azobenzene functional polydiacetylenes were investigated detailedly.

本论文通过改变间隔基长度和偶氮苯环取代基以及连接方式的方法,将光响应性偶氮生色团引入聚二乙炔

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This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

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