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The improved process produces a polyester of improved color versus other titanyl oxalate catalysts and a novel polyester without the presence of antimony.

此改进的方法制备出一种与采用其它钛氧基乙二酸盐催化剂的方法相比具有改进的色泽的聚酯和一种不含锑的新型聚酯。

The present invention provides an improved method of producing polyester by the polycondensation of polyester forming reactants wherein the improvement comprises utilizing, as the polycondensation catalyst, lithium titanyl oxalate.

本发明提供了一种由制备聚酯用反应物的缩聚反应制备聚酯的改进方法,其中的改进包括使用钛氧基乙二酸锂作为缩聚反应催化剂。

The absorption and transport of umbelliferone, osthole, columbianadin, columbianetin acetate, angelolA and angelolB are passive diffusion as the dominating process in Caco2 cell monolayer model.

为了考察独活中香豆素类化学成分在整体口服实验中能否被吸收和吸收程度,本文首先采用Caco2细胞单层模型[8]研究独活中的主要化学成分伞形花内酯、甲氧基欧芹素、二氢欧山芹素、二氢欧山芹醇乙酯、当归醇A和当归醇B的吸收和转运。6种香豆素类成分的化学结构见图1。

Simultaneously we prepared benzimidazolines with two methods by the of reduction benzimidazolium salts with NaBH_4 and Grignard addition with benzimidazolium salts. Thus we provided a new biomimic synthetic method for 13 kind of tetrahydroisoquinoline starting from carboxylic aicd and halid, gave a new idea of the synthesis for new drugs.It can make many kind ofβ-carboline alkaloids which have bioactivity to antibacterium, antivirus and antitumor to start from 1,2,3,4-tetrahydro -β-carboline.

本文以1,3-二甲基苯并咪唑碘盐和2-取代的1,3-二甲基苯并咪唑碘盐为原料,采用了NaBH_4还原和Grignard试剂加成两种方法,制备了13种1,3-二甲基苯并咪唑烷和2-取代的1,3-二甲基苯并咪唑烷作为四氢叶酸辅酶一碳单元转移新模型,在酸性条件下,以2-(3,4-二甲氧基苯基)乙胺作为接收一碳转移的亲核试剂,完成了13种重要的四氢异喹啉类化合物的新合成方法研究。

From the investigation into the visible spectra and performances on textile of these azo dyes, as acid dye, it was found that these dyes had deep coloring effects on dyeing wool or silk, and five of which could dye wool into black one at 3% o. w. f., especially the diazo dye derived from 2, 8-diamino-10-methoxy-5, 10-dihydrophenophosphazine 10-oxide and acet-J-acid, it could not only dye wool into black one but each fastness of the obtained dyed sample was good.

对这些已知结构的染料进行浸染染色,结果发现,它们作为酸性染料,在羊毛及丝绸纤维上染色时,能够获得比一般偶氮染料不宜获得的深色效应,其中5支染料得到黑色染样,尤其由2,8-二氨基-10-甲氧基-5,10-二氢磷杂吖嗪与乙酰J-酸形成的双偶氮染料得到黑色染样,其各项牢度都比较理想。

Objective: To synthesize 2-benzyloxy-5-fluoro-4-oxo-pyrimidine-3-butyric acid ethyl ester, the key intermediate in the synthesis of fluorouracil derivatives.

目的:合成氟尿嘧啶类衍生物合成中的关键中间体2-苄氧基-5-氟-4-嘧啶酮-3-丁酸乙酯。

One compound is identified as the title compound 2-benzyloxy-5-fluoro-4-oxo-pyrimidine-3-butyric acid ethyl ester, and the other one is its formula isomer.

通过IR谱确证一个化合物是目标物2-苄氧基-5-氟-4-嘧啶酮-3-丁酸乙酯,另一化合物是它的同分异构体。

Properties of frontier orbital of xanthogen formates and ethoxycarbonyl thionocarbamates, including HOMO energy, shape of HOMO and atomic HOMO density, were calculated with quantum chemistry programs GW03 and FUJISTU CAChe. According to the results, the relationship between selectivity of such two kinds of collectors and their quantum chemical indices was investigated to discuss the feasibility of applying them in screening chalcopyrite collectors.

摘 要:利用量子化学软件GW03和FUJISTU CAChe计算黄原酸甲酸酯类、乙氧羰基硫氨酯类黄铜矿捕收剂的前线轨道的性质—HOMO能量、HOMO形状以及药剂组成原子的HOMO密度,并结合这两类药剂的浮选结果研究这些量化参数与药剂选择性之间的联系,探讨这些参数作为选择黄铜矿捕收剂判据的可行性。

A series of p hydroxybenzoic acid oligomers were synthesized of p acetoxybenzoic acid (4 ABA).

用对乙酰氧基苯甲酸合成了一系列对羟基苯甲酸的齐聚物,由于这些齐聚物不溶于大部分有机溶剂,因此尝试用傅立叶红外谱半定量地分析齐聚物的聚合度。

A series of p hydroxybenzoic acid oligomers were synthesized of p acetoxybenzoic acid (4 ABA). Since the oligomers are insoluble in most organic solvent, we tried to analyze the degree of polymerization of the oligomers half stoichiometricly by the FT IR method.

用对乙酰氧基苯甲酸合成了一系列对羟基苯甲酸的齐聚物,由于这些齐聚物不溶于大部分有机溶剂,因此尝试用傅立叶红外谱半定量地分析齐聚物的聚合度。

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