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乙基氰

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The title compound (C21H15N5O) was obtained by the reaction of 3-methyl-1-phenyl-1H-pyrazol-5(4H)-one and 4-(2,2-dicyanovinyl)benzonitrile in water in the presence of TEBA and by recrystallization from EtOH(95%) and DMF.

水溶剂中,在三乙基苄基氯化铵存在下,由3-甲基-1-苯基-1H-吡唑-5(4H)-酮和4-(2,2-二氰基)苯基氰合成并经N,N-二甲基甲酰胺与95%乙醇的混合溶剂重结晶得到化合物C21H15N5O的晶体。

Ophenyl phenol,ophenyl phenol sodium salt tetrahydrate,7ADCA,2ethyl phenyl hydrazine hydrochloride,2,3dihydrofuran,7ethyl3(2hydroxy ethyl)indole,methyl ester of etodolac; 1,8diethyl1,3,4,9tetrahydropyrano[3.4b] indole1acetic acid methyl ester,5chloro2methoxy benzoic acid,4(2aminoethyl)benzene sulfonamide,5cyano phthalide,phthalhydrazide,9thioxanthenone,n[(1,4benzodioxane2yl)carboxyl]piperazine HCL,2chloro4amino6,7dimethoxyquinazoline,2chloro benzimidazole,1(4fluorobenzyl)2chlorobenzimidazole,2methylthio4pyrimidone,5amino4imidazole carboxamide HCL,6chloro2hexanone,11oxo6.11hydrodibenzothiepin,6,11dihydrodibenzooxepin11one,10,11dihydrodibenzocyclohepten5one;dibenzosuberone,dibenzo cyclohepten5one;dibenzosuberenone,3,5dihydroxy benzoic acid,3,5dihydroxy benzyl alcohol,2mercapto benzimidazole,3,4dihydroxy benzaldehyde,3,4dihydroxy benzonitrile,2amino5chloro benzonitrile,2(4chlorophenoxy)ethyl chloride,2(4chloro phenoxy)tert,butane,ditrimethylol propane;DTMP,2,2bis(4hydroxyphenyl)butane; bisphenol B,1,1'bis(4hydroxyphenyl)cyclohexane;bisphenol Z,tetrabromobisphenolS,3,5ditertbutyl salicylic acid,3,4,5trihydroxy benzoic acid stearyl ester,1,2,4trimethoxybenzene.

华业公司产品:邻苯基苯酚,邻苯基苯酚钠盐,7氨基3去乙酰氧基头孢烷酸,邻乙基苯肼盐酸盐,2,3二氢呋喃,7乙基色氨醇,依托度酸甲酯,5氯2甲氧基苯甲酸,4(2氨乙基)苯磺酰胺,5氰基苯酞,双酮酞嗪,9噻吨酮,N〔(1,4苯并二恶烷2基)羰基〕哌嗪盐酸盐,2氯4氨基6,7一二甲氧基喹唑啉,2氯苯并咪唑,1(4氟苄基)2氯苯并咪唑,2甲硫基4嘧啶酮,5氨基咪唑4 甲酰胺盐酸盐,6氯2已酮,11氧6.11二氢苯并〔b.c〕虑平,11氧代6,11二氢二苯并氧杂卓,10,11二氢二苯并环庚烯5酮,二苯并环庚烯5酮,3,5二羟基苯甲酸,3,5二羟基苯甲醇,2巯基苯并咪唑,3,4二羟基苯甲醛,3,4二羟基苯腈,2氨基5氯苯腈,2(4氯苯氧基)1氯乙烷,2(4氯苯氧基)叔丁烷,双丙烷,2,2二(4羟基苯基)丁烷;双酚B,1,1'双(4羟基苯基)环己烷;双酚Z,2[3,5二溴4(2,3二溴丙氧基)]苯砜,3,5二叔丁基水杨酸,3,4,5三羟基苯甲酸十八烷基脂,1,2,4三甲基氧基苯。

The 6- cyano-1, 1 (1, 3- dioxypropylidene)-7-(carbomethoxyl group- methyl - 5- oxo-Delt6 (8)- tetrahydrochysene indolizine and haloethane reacts with each other for ethylization with existence of alkali and organic solution with or without phase transversion catalyst, and produces mentioned product.

本发明在相转移催化剂或无相转移催化剂存在下,6-氰基-1,1-(1,3-亚丙二氧基)-7-(甲氧羰基-甲基-5-氧代-Δ6(8)-四氢中氮茚类化合物与卤代乙烷在碱和有机溶剂的存在下进行乙基化反应即得6-氰基-1,1-(1,3-亚丙二氧基)-7-1′-(烷氧羰基-丙基-5-氧代-Δ6(8)-四氢中氮茚类化合物。

METHODS 5-amino-1-hydroxyethyl pyrazole-4-carboylic acid was synthesized through condensation of ethyl cyanoacetate and triethyl orthoformate followed by one-pot methodology of cyclization,hydolysis.

方法原甲酸三乙酯与氰乙酸乙酯缩合,然后和羟乙基肼经环合、水解等一锅法合成5-氨基吡唑-4-甲酸,然后在亚硫酸钠存在条件下加热脱羧得到5-氨基-1-羟乙基吡唑。

The cholesteric liquid crystalline solution of ethyl-cyanoethyl cellulose/dichloroacetic acid C/DCA showed multi-texture behavior with variation of concentration.

乙基氰乙基纤维素/二氯乙酸溶液形成的胆甾相的聚集态结构随着浓度的变化会呈现出多种织构形态。

The paint includes liquid A, which consists of acrylic resin, mixed solvent of xylene, acetone and isophorone, organic silicone solution, superfine silica powder, titanium dioxide powder, methyl-(N-beta-amino ethyl gamma-amino propyl)-dimethoxy siloxane solution, gamma-methyl acrylyloxy propyl tromethoxy siloxane solution and fluorocarbon modified siloxane; and liquid B, which consists of hexamethylene diisocyanate, polydiisocyanate, xylene, and methoxy propyl acetate. When the paint is used, two components are mixed together.

由丙烯酸树脂、二甲苯和丙酮及异佛尔酮混合溶剂、有机硅酮溶液、超细二氧化硅粉、钛白粉、甲基(N-β-氨乙基γ-氨丙基)二甲氧基硅烷溶液、γ-甲基丙烯酰氧基丙基三甲氧基硅烷溶液、氟碳改性硅氧烷溶液组成A液,由六亚甲基二异氰酸酯聚异氰酸酯、二甲苯和甲氧基乙酸丙酯混合溶液组成B液,使用时将两组分混合。

Tri (2-hydroxyethyl) isocyanurate was used as the curing agent to synthesize the polyurethane elastomer modified by isocyanurate.

以三(2-羟乙基)异氰脲酸酯为固化剂,用异氰脲酸酯环合成改性聚氨酯弹性体。

Benzyl isothiocyanate and phenethyl isothiocyanate, are derived isothiocyanates from cruciferous vegetable, including watercress, broccoli and cabbage.

苯甲基异硫氰酸酯和苯乙基异硫氰酸酯是来自於十字花科蔬菜的衍生物,常见的十字花科蔬菜包含了花椰菜、甘蓝菜、芥菜…等。

In this study, we investigate the effect of benzyl isothiocyanate and phenethyl isothiocyanate on human prostate cancer DU-145 cells, the results demonstrate that benzyl isothiocyanate and phenethyl isothiocyanate induced cause G2 / M phase arrest and apoptosis. These effects are in a dose- and time-dependent manners.

但是苯甲基异硫氰酸酯和苯乙基异硫氰酸酯造成人类前列腺癌细胞株DU-145的凋亡机转则尚未有较详细的报导,所以本研究即是探讨苯甲基异硫氰酸酯和苯乙基异硫氰酸酯造成人类前列腺癌细胞株DU-145的相关凋亡机转。

Firstly, headspace solid-phase microextraction was established to determine AITC by orthogonal design. Extraction temperature, stir speed, extraction time, and desorption time were set at 40℃, 900r/min, 30min, and 5min, respectively. Under these optimal conditions, volatile flavor compounds in mustard oil, wasabi, and 'Chongcai'leaf mustard product were identified by SPME/GC/MS. In these three samples, 6,12,17 constituents were identified respectively; Allyl isothiocyanate was the main flavor compound, which accounted for 73.45%, 64.25%, 32.74% of total volatile compounds, respectively. Carbon disulfide, a hydrolysis product of AITC, accounted for 14.37% 25.40%, 51.67% of total volatile compounds respectively. There were some other isothiocycannates, such as butane, 1-isothiocyanato-, isobutyl isothiocyanate, 1-benzene, 4-isothiocyanato-, benzene (2-isothiocyanatoethyl)-, etc.

首先采用正交实验设计优化固相微萃取技术的前处理条件,结果表明,以萃取温度40℃、搅拌速度900r/min、萃取时间30min、解吸时间5min为最佳条件;在此最优条件基础上,利用SPME/GC/MS联用技术分析芥末油、青芥辣、冲菜的挥发性风味成分,分别检出6、12、17种化合物,主要风味物质均为AITC,相对丰度分别为73.45%、64.25%、32.74%;AITC的水解产物二硫化碳的相对丰度分别为14.37%、25.40%、51.67%;还检测到了其它几种异硫氰酸酯,如异硫氰酸丁酯、异硫氰酸异丁酯、异硫氰酸丁烯酯、2-苯乙基异硫氰酸酯等。

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