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The thermal inactivation of penicillin amidase entrapped in AOT/isooctane reversed micelles was studied in detail.

研究了青霉素酰化酶在二-(2-乙基己基)琥珀酸双酯磺酸钠/异辛烷反胶团中的稳定特性。

This article introduces manufacturing methods of taurine by means of sodium hydroxyethyl sulfonate ammonolysis acidification .

研究了羟乙基磺酸钠氨解酸化法生产牛磺酸的工艺,对其中的高压氨解反应过程采用二次回归正交设计实验方法进行了优化。

In this paper, the catalytical esterification of palmitic acid with 1 hexadecanol by lipase immobilized by microemulsion base organo gel that consisted of bis (2 ethylhexyl)sodium sulphsuccinate/heptane/water/gelatin in apolar organic solvent was studied.

研究了以AOT二(2 乙基已基琥珀酸酯磺酸钠/正庚烷/水/明胶组成的反相微乳凝胶固定化脂肪酶,在有机溶剂中催化棕榈酸和十六醇的酯化反应。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下:(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2,3-双(2,6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2,6-二[1-(2,4,6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上,研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响,研究表明:1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理,可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体;2、BET,XRD,IR,SEM,GPC和DSC研究表明,脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下:(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2,3-双(2,6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2,6-二[1-(2,4,6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上,研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响,研究表明: 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理,可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体; 2、BET,XRD,IR,SEM,GPC和DSC研究表明,脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

In this paper,firstly a series of acryloxyl derivatives were synthesized from the dehydrogenated abietic acid,a main composition of disproportionated rosin, through acyl chloridation and esterification.The derivatives included the (β-acryloxyl ethyl) esters of dehydrogenated abietie acid,(β-methacryloxyl ethyl) esters of dehydrogenated abietic acid and (β-methacryloxyl propyl)esters of dehydrogenated abietic acid.

论文首先以歧化松香中的主要成分脱氢枞酸为模型化合物,采用酰氯化、酯化手段合成了它的一系列丙烯酰氧基衍生物,包括脱氢枞酸酯、脱氢枞酸(β-甲基丙烯酰氧基乙基)酯和脱氢枞酸(β-甲基丙烯酰氧基丙基)酯。

Using 2-bromo-ethanesulfonic acid sodium salt ,α,ω- binary primary amine and dodecanoic acid as the main raw materials, drawing support from two-step synthesis of experiments—Alkylated reaction and Schotten-Baumann acylation, A series of LAS(12-s-12) gemini surfactants were synthesized.

并以2-溴乙基磺酸钠、α,ω-二元伯胺、月桂酸等为主要原料,借助胺基的烷基化和Schotten-Baumann酰基化反应制备了α,ω-烷撑-双钠盐LAS(12-s-12)表面活性剂,联结基团为亚甲基—(CH2)s—(S=2,4,6,8,12),取得以下进展

In the presence of alkalinity and tetraethyl ammonium bromide, 2,4-dihydroxy benzophenone reacts with allyl glycidyl ether to form an ethylenic derivative of benzophenone, 2-hydroxy-4-(β-hydroxy-γ-allyloxy) propyloxy benzophenone, which can further undergo hydrosilylation with polyhydromethylsiloxane.

在相转移催化剂四乙基溴化按作用下,利用2,4-二羟基二苯甲酮与烯丙基缩水甘油醚在碱性水溶液中的开环加成反应,合成了中间体4-丙氧基-2-羟基二苯甲酮,将其进一步与聚甲基氢硅氧烷进行硅氢化加成反应。

Paraacetaminophenyl-β-hydroxyethylsulfone can be used as raw material to produce the target product 2-sulfonic-4-(β-sulphatoethyl-sulphone) phenylamine through sulfonationating and hydrolytic reactions.

本文研究了以对乙酰氨基苯基-β-羟乙基砜为原料,经磺化和水解反应,制得产品2-磺酸-4-苯胺的合成工艺,以及2-磺酸-4-乙基砜基硫酸酯苯胺钠盐后处理的最佳操作工艺。

Poly/montmorillonite/2-Carboxyethyl phosphinic acid (PET/MMT/CEPP) nanocomposites were prepared through direct-esterification process by adding reactive flame retardant before esterification, and organic MMT was added before polycondensation.

采用直接酯化法,将共聚型阻燃剂羧乙基苯基次磷酸和对苯二甲酸以及乙二醇混合后酯化,在酯化产物中加入经过有机改性的蒙脱土,缩聚制备了阻燃聚酯/蒙脱土纳米复合材料(PET/MMT/CEPP)。

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