乙基化

The progress in the catalytic amination of bifunctional alcohols to diamines or cyclic amines is reviewed in this paper.

以乙醇和哌嗪催化胺化合成N-乙基哌嗪的反应为模型，对分子间醇的催化胺化反应进行了研究。

In this paper, the catalytical esterification of palmitic acid with 1 hexadecanol by lipase immobilized by microemulsion base organo gel that consisted of bis (2 ethylhexyl)sodium sulphsuccinate/heptane/water/gelatin in apolar organic solvent was studied.

研究了以AOT二(2 乙基已基琥珀酸酯磺酸钠/正庚烷/水/明胶组成的反相微乳凝胶固定化脂肪酶，在有机溶剂中催化棕榈酸和十六醇的酯化反应。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明：1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体；2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明： 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体； 2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

The intermolecular catalytic amination of alcohols is examined by using the catalytic amination of ethanol with piperazine to N-ethylpiperazine as a model.

以乙醇和哌嗪催化胺化合成N-乙基哌嗪的反应为模型，对分子间醇的催化胺化反应进行了研究。

Three novel hemicyanine derivatives,-N-(4-sulfopropyl)-4-[2-(4- N, N-diethylaminophenyl)-ethenyl]pyridinium,-N-(4-suMbbutyl)- 4-[2-(4-N, N-diethylaminophenyl)ethenyl]pyridinium (EPS4), and-N-(4- su)fobutyl-4-[2-(4-N, N-diethylaminophenyl)ethenyl]quinolinium (EQS4) with different length of alkyl chains between the adsorbing group (RSO3-) and the chromophore group, were synthesized and their photophysical and photoelectrochemical properties were studied.

设计合成了具有不同空间位阻的吡啶盐类和喹啉盐类半菁染料-N-(4—磺酸根丙基)-4-[2-4（4-N，N-二乙基氨基苯基）乙烯基]吡啶鎓盐，-N-4-磺酸根丁基）-4-[2-(4-N，N-二乙氨基苯基）乙烯基]吡啶鎓盐（EPS4）和-N-（4-磺酸根丁基）-4-2-（4-N，N-二乙基氨基苯基）喹啉鎓盐（EQS4），研究了它们的光物理性质，并将它们用作TiO2纳米晶电极的光敏化剂引入光电化学电池中。

The glass transition temperature from DMTA analysis revealed the glass transition temperature of the extragallery cured epoxy resin and was in relation to the curing temperatures. Addition of organophilic montmorillonite led to the disappearance of the α' peak of loss tangent of the nanocomposites.

DMTA测试表明，所测的玻璃化转变温度是层外固化环氧树脂的玻璃化转变温度，并发现二亚乙基三胺固化环氧树脂纳米复合材料的玻璃化转变温度与固化温度紧密相关，且加入蒙脱土后纳米复合材料的低温α'松弛峰消失。

Paraacetaminophenyl-β-hydroxyethylsulfone can be used as raw material to produce the target product 2-sulfonic-4-(β-sulphatoethyl-sulphone) phenylamine through sulfonationating and hydrolytic reactions.

本文研究了以对乙酰氨基苯基-β-羟乙基砜为原料，经磺化和水解反应，制得产品2-磺酸-4-苯胺的合成工艺，以及2-磺酸-4-乙基砜基硫酸酯苯胺钠盐后处理的最佳操作工艺。

Poly/montmorillonite/2-Carboxyethyl phosphinic acid (PET/MMT/CEPP) nanocomposites were prepared through direct-esterification process by adding reactive flame retardant before esterification, and organic MMT was added before polycondensation.

采用直接酯化法，将共聚型阻燃剂羧乙基苯基次磷酸和对苯二甲酸以及乙二醇混合后酯化，在酯化产物中加入经过有机改性的蒙脱土，缩聚制备了阻燃聚酯／蒙脱土纳米复合材料(PET/MMT/CEPP)。

0 H; reaction temperature: 140～ 150°C ; molar ratio of p toluene sulphonic acid to salicylic acid, 1∶11, with no water carrying reagent; yield: about 98%.

应用对甲苯磺酸作为水杨酸和 2 -乙基己醇的酯化催化剂，成功合成了水杨酸- 2 -乙基己酯。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新