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乙二醛

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The experimental results showed that SO_4 2-/TiO_2-MoO_3 was an excellent catalyst for synthesizing isobutyraldehyde glycol acetal .

研究了以固体超强酸SO42-/TiO2-MoO3为催化剂,异丁醛和乙二醇为原料,合成异丁醛乙二醇缩醛的反应条件。

Average current efficiency is 85.06%, chemical yield is 94.01%, average bath voltage is≤4.5V, the concentration of glyoxalic acid is ≥40%, the concentration of oxalic acid is ≤2.5%, and no oxalic aldehyde in the product is present.

本论文通过优化工艺控制,确定了最佳工艺条件,使平均电流效率达85.06%,化学收率达94.01%,平均槽电压≤4.5V,产品中乙醛酸浓度≥40%,草酸≤2.5%,产品中无乙二醛,可以满足下游产品的质量要求。

In this process, the electrolylic bath with cationic exchange membrance and leas electrode is used. The cathode liquor is oxalic acid, the anode liquor is diluted sulfuric acid. The process above has following advantages with high yield, top quality, lower cost, no "three wastes" pollution, and no oxalic aldehyde in the product. It is a cleaner and environment-friend technology, and is a development trend for production of glyoxalic acid. Complete analytical process for raw materials, intermediate and final products were established.

本论文通过对乙醛酸合成路线的研究,确定了草酸电解法制乙醛酸的工艺路线,此法采用装有阳离子交换隔膜和铅电极的电解槽,阴极电解液为草酸溶液,阳极电解液为稀硫酸,该工艺具有产品收率高、质量好、成本低、无三废污染、产品中无乙二醛等特点,是一条清洁、绿色工艺,是生产乙醛酸的主要发展方向。

Carbamide reacting with H2SO4 forms aminosulfonic acid. Allantoin is prepared by oxidation of the aqueous solution of glyoxal into glyoxylic acid which is then used to synthesize allantoin.

氨基磺酸的合成是用尿素和发烟硫酸反应;尿囊素的合成是用硝酸氧化乙二醛溶液制得乙醛酸后,再加入氢氧化钙和氯化钙,使乙醛酸以钙盐形式析出,然后在盐酸介质中与尿素缩合而成。

The main gluconeogenic precursor in kidney is thought to be lactate; however, less is emphasized enantiomerically. L-lactate is a glycolysis end-product, but D-lactate is formed after detoxification of methylglyoxal, which is the main source of advanced glycation end-products.

乳酸为肾脏糖质新生的主要来源,其含有一不对称碳,故具有D-、L-乳酸两种镜相异构物,而D-、L-乳酸两者之生成相当不同,L-乳酸是糖解作用之终产物,D-乳酸为体内一醣化终产物(advanced glycation end-products)─甲基乙二醛进行去毒化反应所生成,目前缺乏对乳酸镜像异构物与肾脏糖质新生间相关的探讨。

The result showed that the water-resisting and conglutinated intensity of the adhesive have obviously improved by cross-linking with oxalaldehyde .

此外,还研究了交联剂、催化剂、温度、反应时间、PVA和pH对氧化淀粉粘合剂粘合强度的影响,结果表明:以乙二醛进行交联改性粘合剂的耐水性、粘合强度有了明显的提高。

Furthermore,using oxaldehyde,make the emulsion crosslinked and form a kind of net structure,thus a new kind of water-resistant adhesive is created.

通过醋酸乙烯酯共聚改性的方法,用醋酸乙烯与丙烯酸系单体共聚,采用无皂乳液聚合,然后用乙二醛交联,使乳液形成网络结构,制备了一种新型耐水性胶粘剂,研究了共聚单体对乳液性能的影响,并采用DSC、透射电镜等对乳液结构及性能进行了测试。

A new kind of non-formaldehyde water-resistant emulsion is prepared by modifying polyvinyl acetate with the surfactant-free copolymerization to polymerize vinyl acetate and the acrylic acid monomers,and then by using oxaldehyde to make the emulsion crosslinked to form a kind of net structure.

通过醋酸乙烯酯共聚的改性方法,用醋酸乙烯与丙烯酸系单体共聚,采用无皂乳液聚合,后用乙二醛交联,使乳液形成网络结构,制备了一种无甲醛的新型耐水性乳液。

Chitosan and film-forming properties of polyvinyl pyrrolidone dissolved outstanding performance, made of composite membrane, through the composite membrane-embedded and glyoxal cross-linking role of the glassy carbon electrode have a common fixed-horseradish dismutase enzymes and hemoglobin, Fe 63-/4- body as an electronic transmission.

利用壳聚糖成膜性能及聚乙烯吡咯烷酮优异的溶解性能,制成复合膜,通过复合膜包埋和乙二醛交联作用在玻碳电极上共同固定辣根过氧化物酶和血红蛋白,Fe63-/4-作为电子传递体。

The o-aminobenzaldehyde ethylene acetals can be synthesized from corresponding o-nitrobenzaldehyde by reducing the nitro-group after the protection of carbonyl by ethylene. 2-Aminophenyl ketone ethylene ketal can also be prepared from 2-nitrophenyl ketones by this method.

邻氨基苯甲醛乙二醇缩醛可以由含不同取代基的邻硝基苯甲醛经羰基以乙二醇缩醛保护后还原硝基得到,邻氨基芳香酮乙二醇缩酮可以同样的方法由邻硝基芳香酮得到。

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