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Ethyl alcohol and-2,4-Decadienal were the primary volaties. Some unique and high relative content volatives, playing an important role in the formation of specific aroma of different Chaenomeles sinensis cultivars, were detected from most cultivars.

乙醇和-2,4-癸二烯醛等化合物是光皮木瓜果实内最主要的挥发性物质,绝大多数品种内还含有自己独特的且相对含量较高的挥发性物质,这对构成不同品种光皮木瓜特异香气起到重要作用。

The basic functionalized ionic liquid, 1 -butyl-3-methylimidazolium hydroxide OH, was prepared and used to catalyze the Knoevenagel condensation of aromatic aldehydes with malononitrile or ethyl cyanoacetate.

合成了碱性功能化离子液体氢氧化1-丁基-3-甲基咪唑,研究了将其作为催化剂催化芳香醛和丙二氰、氰基乙酸乙酯的Knoevenagel缩合反应。

The basic functionalized ionic liquid, 1-butyl-3-methylimidazolium hydroxide, was prepared and used to catalyze the Knoevenagel condensation of aromatic aldehydes with malononitrile or ethyl cyanoacetate.

合成了碱性功能化离子液体氢氧化1-丁基-3-甲基咪唑,研究了将其作为催化剂催化芳香醛和丙二氰、氰基乙酸乙酯的Knoevenagel缩合反应。

Knoevenagel condensation reaction between aromatic aldehyde, malononitrile or ethyl cyanoacetate is promoted by organocatalyst N-methylimidazole.

以1-甲基咪唑为有机小分子催化剂催化芳香醛与丙二腈或氰乙酸乙酯的Knoevenagel缩合反应,反应速度快,操作方便,产率高,后处理简单。

By reacting isobutyraldehyde with diethyl oxalate using sodium methoxide as catalyst,3-methyl-2-oxobutanoic acid,sodium salt was prepared by one pot.

采用甲醇钠催化异丁醛与草酸二乙酯反应,一釜法合成了3-甲基-2-氧代丁酸钠。

By using gas chromatography technique nine kinds of fragrance components(acetic aldehyde,ethyl acetate,ethanol,propyl acetate,3-hydroxy-2-butanone,acetic acid,furfural,metacetonic acid,2,3-butylene glycol)were measured quantitatively in different kinds of Shanxi overmature vinegar and the other kinds of vinegar.

应用气相色谱方法对山西老陈醋和其他种类醋的9种香气成分(乙醛、乙酸乙酯、乙醇、乙酸丙酯、3-羟基-2-丁酮、乙酸、糖醛、丙酸、2,3-丁二醇)进行了定性、定量测定,并用聚类分析、模糊综合评判、方差分析、回归分析的方法对实验结果进行了数理分析。

D-Pantothenyl alcohol, also called ortho-vitamin 85, is an important nutrition suppled substance. It has been widely applied in the field such as medicine, cosmetic, foodstuff, feed additive, and so on. The preparation of D-pantothenyl alcohol and the optimization of key factor are discussed mainly in this paper. It mainly includes three section.In the first section, with formaldehyde, isobutyl aldehyde and diethyl oxalate as the starting materials, D-pantolactone is prepared via three steps including condensation, catalytic hydrogenation and physical resolution. The specific rotatory power of the product is consistent with imported product.

D-泛醇,俗称原维生素B_5,属维生素B旋类营养增补剂,广泛应用于医药、化妆品、食品、饲料等领域,本文着重探讨了其制备及关键因素的优化,主要内容可分三部分:第一是D-泛内酯的制备,先以甲醛、异丁醛和草酸二乙酯为起始原料合成酮基泛内酯,再经催化氢化得到DL-泛内酯,然后通过物理拆分获得D-泛内酯,得到产物的比旋光度与进口产品基本一致。

Reaction of citric acid with paraformaldehyde gave anhydromethylene citric acid with a yield of 63%;the reaction of compound with acetic anhydride gave the corresponding anhydride with a yield of 87%;the esterification of compound with lauryl alcohol gave anhydrocitric acid monoester with a yield of 76%.

将等浓度的柠檬酸和多聚甲醛加热,反应生成柠檬酸缩醛环酯,产率为63%;与乙酸酐反应得到相应的柠檬酸酐,产率为87%;与月桂醇酯化,生成产物,产率为76%;用二氧六环做溶剂,将与等浓度的碱进行开环反应,生成柠檬酸月桂醇单酯,产率为83%。

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