乙二醛

In the precence of the base catalyst KF/Al2O3, the one - pot reaction of 2 -hydroxybenzaldehyde or 2 - hydroxynaphthaldehyde with ethyl α- bromoacetate,α-bromoacetophenone , 1,4 - dichloromethylbenzene , 4,4'- dichloromethylbiphenyl and 1,5 -dichloromethylnaphthalene gave the benzofuran compounds in 38-89% yield.

本文报道用 KF/Al_2O_3作为碱催化剂，由水杨醛或2-羟基-1-萘醛分别和α-溴代乙酸酯、α-溴代苯乙酮、苄基氯、4，4'-二氯甲基联苯和1，5-二氯甲基萘等进行一锅化缩合反应，以38～89％的产率合成了14种芳并呋喃化合物。

The condensation reaction,in which the yield of intermediate product after refining process was more than 90%,used iso-butylaldehyde and formaldehyde as materials,Et 3N as catalyst.The hydrogenation,in which the conversion of hydroxypivaldehyde and selectivity of NPG were respectively 99% and 95%,used Cu-ZnO as catalyst,and ethanol as solute,meanwhile in the hydrogenation,the impurity in material could also ...

缩合反应采用异丁醛和甲醛为原料，三乙胺为催化剂，在 60℃左右反应，缩合产物经减压蒸馏和结晶、干燥，得到收率为 90 %以上的中间体羟基戊醛；加氢反应采用自制的Cu -ZnO催化剂，乙醇为溶剂，在 15 0℃将HPA加氢生成新戊二醇，HPA转化率为 99%，新戊二醇收率在 95 %以上，而且HPA缩合反应的副产物在加氢反应中也转化为新戊二醇。

The preparation of 2,2-dimethyl-3-hydroxy propanal from the condensation of formaldehyde and i-butyraldehyde by using triethylamine as catalyst was studied.

以异丁醛和甲醛为原料，三乙胺为催化剂，羟醛缩合法合成了2，2-二甲基－3-羟基丙醛。

Amino-6-methoxy Benzothiazole 99%、2-Amino Benzothiazole 99%、Veratraldehyde 99%、Veratric Acid 99%、1,2- Dimethoxy Benzene 99%、6-Nitroveratric Acid 97%、2,5-Dichlorobenzoic Acid 99%、4-Chloro-3-Nitrobenzoic Acid 99%、 3-Nitrobenzole Acid 98%、p-Methoxybenzoie Acid 99%、Anisole 99.5%、p-Methoxyacetophenonc 99%、(2'-Chloroethyl) Benzene 99%、(2'-Bromoethyl) Benzene 99%、N,N-Diethyi-m-Toiuamide 99%、Aminoacetonitrile Hydrochloride 98%、 Alkyl Diphenyl Phosphate Estrel 98%、5-Chloro-2-benzothiazolone 99%、6-bromo-2-naphthol 98%、6-Nitro-Veretric Acid Estrel 97%、4-chloro phenoxyaeetic 99

2-氨基-6-甲氧基苯骈噻唑、2-氨基苯骈噻唑、藜芦醛、藜芦酸、藜芦醚、6-硝基藜芦酸、2，5-二氯苯甲酸、3-硝基-4-氯苯甲酸、3-硝基苯甲酸、对甲氧基苯甲酸、苯甲醚、对甲氧基苯乙酮、β-氯代苯乙烷、β-溴代苯乙烷、N，N-二乙基间甲苯甲酰胺、氨基乙腈盐酸盐、磷酸二苯月桂酯、5-氯-2-苯骈噻唑酮、6-溴-2-萘酚、6-硝基藜芦酸甲酯、4-氯苯氧乙酸

In this catalyst system, the Knoevenagel condensations of a series of aromatic aldehydes with malononitrile or ethyl cyanoacetate were programmed and a mechanism was postulated as well. When aromatic aldehydes reacted with ethyl cyanoacetate, the corresponding alkenes proved to be E-isomers by 1H NMR.

在该反应体系中考察了一系列芳香醛和丙二氰、氰基乙酸乙酯的缩合反应，并推测了Knoevenagel缩合反应的机理，芳香醛与氰基乙酸乙酯缩合产物经1H NMR检测为E式烯烃。

The chemical constituents of extracts of Tamarindus indica L were determined by GC-MS. The relative contents of constitutes were determined by area normalizing method. 48 compounds were identified, amounting to total mass fraction 98.5%. The main compounds were 5-methyl-2(3H)-furanone, diethyl succinate, furfural, hexadecanoic acid, linolenic acid, 5-methylfurfural, oleic acid, linoleic acid, etc.

并利用气相色谱仪-质谱仪对罗望子萃取物的化学组成进行了分析鉴定，并用面积归一化法测定了各种成分的质量分数，共鉴定了48种成分，占总质量分数为98.35%，其中主要成分为：5-甲基-2(3H)-呋喃酮、丁二酸二乙酯、糠醛、十六酸、亚麻酸、5-甲基糠醛、油酸、亚油酸等。

The first synthetic route uses 1,2,4-trimethoxybenzene and chloroacetonitrile in forming 2,4,5-trimethoxy-a-chlor-acetophenone under the anhydrous condition, then the intermediate condensates with papaverine forming the core pyrro[2,l-a]isoquinoline, followed by formation and lactonization to form the lactone ring. The second synthetic route uses prepared aldehyde with prepared ethyl nitroacetate by Knoevenagel condensation to obtain 2-Nitro-3-(2,4,5-tris-methoxy-phenyl)-acrylic acid ethyl ester and 2-Nitro-3-(2,4,5-tris-benzyloxy -phenyl)-acrylic acid ethyl ester etal intermediates. The lamellarin skeleton could arise from condensation of the papaverine and these intermediates by Michael reaction, the ester group is provided for subsequent lactonization. The third synthetic route uses coumarin or indan-l,3-dione derivatives and papaverine to form lamellarin under basic conditions.

第一条路线首先从1，2，4-三甲氧基苯出发与卤乙腈作用合成卤代芳酮中间体，然后与罂粟碱反应合成开链片螺素，最后经乙酰化、去保护、成内酯环得到片螺素；第二条路线由制备的芳醛和制备的硝基乙酸乙酯经缩合得到2-硝基-3-芳基丙烯酸乙酯，然后由该中间体与罂粟碱反应，在完成关环的同时也引入酯基，最后去保护、成内酯环得到片螺素；第三条路线是由香豆素或茚二酮出发，经溴代后的中间体与罂粟碱反应，得到片螺素的基本框架。

Water, C12-20 acid PEG-8 ester, hydrogenated polysobutene, petrolatum, dicaprylyl maleate, hydrogenated vegetable oil, propylene glycol, acetylated lancolin, glycoprrotiens,panax ginseng root extract,equisetum arvense extract, carbomer, butyrospermum parkill fruit, potassium cetyl phosphate, triethanolamine, hypericum perforatum extract, malva sylvestris extract, methylparaben, glycerin, urea, saccharide hydrolysate, magnesium aspartate, glycine, alanine, creatine, propylparaben, ethlparaben, imidazolidinyl urea, polyperfluoromethylisopropyl ether, fragrance

水，C12-20 酸 PEG-8酯，氢化聚异丁烯，凡士林，马来酸二辛酯，氢化植物油，丙二醇，乙醯化羊毛脂，糖蛋白，人参根萃取，问荆萃取，卡波姆，乳木果，鲸蜡醇磷酸酯钾，三乙醇胺，金丝桃萃取，锦葵萃取，羟苯甲酯，甘油，尿素，水解糖，天门冬酸镁，甘氨酸，丙氨酸，肌酸，羟苯丙酯，羟苯乙酯，尿素醛，聚全氟甲基异丙基醚，香料

Ethyl alcohol, 3-methyl-4-oxo- pentanoic acid, acetic acid butyl ester, 2-methyl-butanoic acid ethyl ester, diethyl phthalate,-2,4-Decadienal were the same volatiles d from the 10 cultivars.

其中共有组6种，为乙醇、3-甲基-4-羰基戊酸、乙酸丁酯、2-甲基丁酸乙酯、邻苯二甲酸二乙酯、-2，4-癸二烯醛。

RESULTS: 12 compounds were isolated and identified as aurantiamide acetate (1), aurantiamide benzoate (2), physcion (3), scopoletin (4), vanillin (5), coniferyl aldehyde (6), syringaldehyde (7), syringic acid (8), luteolin (9), apigenin (10), azelaic acid (11), dotriacontanic acid (12), respectively.

结果：从羊耳菊全草的氯仿和乙酸乙酯部分共分离得到12个化合物，分别鉴定为橙黄胡椒酰胺乙酸酯(1)，橙黄胡椒酰胺苯甲酸酯(2)，大黄素甲醚(3)，东莨菪亭(4)，香草醛(5)，松柏醛(6)，丁香醛(7)，丁香酸(8)，木犀草素(9)，芹菜素(10)，壬二酸(11)，三十二烷酸(12)。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。