乙二醇

A kinetic study on the photopolymerization of MMA with benzophenone/triethylamine/mer-captan system as initiator has been carried out in the presence of oxygen.

采用二笨甲酮/三乙胺/硫醇体系作为引发剂，在含氧条件下进行了MMA光聚合反应的动力学研究。

Due to their applications in magnetic, optical, electronic and catalyst, polynuclear lanthanide clusters are of importance. In this part, a series of nanowheel-shaped nonanuclear lanthanide clusters,〓〓(Ln=Sm~Tm; BA=benzoylacetone), were prepared and characterized. Each complex can exist in three phases, i. e., cubic, tetragonal and triclinic.

本论文第二部分在醇溶液中以三乙胺调变溶液pH，利用β-二酮配位方式的灵活性成功地构筑了一系列结构稳定、纳米尺度轮状的九核稀土配合物〓〓（Ln=Sm~Tm；BA=苯甲酰丙酮），并在不同溶剂中重结晶分别得到了三斜、四方以及立方三种晶型的晶体。

A process for the carbonylation of allylic butenyl ether (for example, methyl crotyl ether, 3-methoxybutene-1 and mixtures thereof) or mixture of butadiene and alcohol and production of beta-gamma unsaturated carboxylic acid esters (for example, methyl-3-pentenoate) utilizing a rhodium-containing catalyst for example, dicarbonylacetylacetonate rhodium(I or the like promoted with an iodide-containing compound (for example, HI, AlI3, SnI4, TiI4, CrI3, and CoI2 or the like).

一种将烯丙型丁烯基醚(如甲基巴豆基醚、3－甲氧基丁烯－1及其混合物)或者丁二烯与醇的混合物羰基化的方法，以及由含碘化物化合物(如HI、AlI3、SnI4、TiI4、CrI3和CoI2或等效物)促进，用含铑催化剂如二羰基乙酰丙酮酸铑(I或其等效物制备β－γ不饱和羧酸酯(如甲基－3－戊烯酸酯)的方法。

Their chemical structures were characterizd on the basis of spectral and chemical evidences to be: Sarracenin (1), 2-methyl-5-hydroxy-7-O-ethyl caffeate chromome (2), Naringenin(3), 2-methyl-5, 7-dihydroxychromome (4), 2-methyl-6-hydroxyl-cinnamic acid methyl ester (5), eriodictyol (6), quercetin (7), Naringenin-7-O-β-D-glucoside( 8 ), eriodictyol-7-O-α-D-glucoside (9), quercetin-3-O-β-D-glucoside(10). In addition, one compound was abtained from the n-butanol frationk, which was finally identified as Morrosiside(11) by spectral and chemical evidences.

以波谱数据及其理化性质鉴定为：Sarracenin(1)，2-甲基-5-羟基-7-O-咖啡酸乙酯色原酮(2)，柚皮素(3)，2-甲基-5，7-二羟基色原酮(4)，2-甲基-6-羟基苯丙烯酸甲酯(5)，圣草酚(6)，槲皮素(7)，柚皮素-7-O-β-D-葡萄糖苷(Naringenin-7-O-β-D-glucoside)(8)，圣草酚-7-O-α-D-葡萄糖苷(eriodictyol-7-O-α-D-glucoside)(9)，槲皮素-3-O-β-D-葡萄糖苷(quercetin--3-O-β-D-glucoside)(10)；另外从正丁醇萃取部位分离得到1个化合物，以波谱数据和文献对照鉴定为：Morroniside(11)。

Dipropyl ether will be recovered in the distillate using 1-pentanol.

使用1-戊醇。N.N-二甲基甲酰胺和2-乙氧基乙醇作为共溶剂时二丙醚将在馏分中回收。

A Product main business categories: chemical solvents white oil, toluene, xylene, durene, valitin water, acetate, D resin, acetone, butanone, cyclohexanone , anti-white water, dichloromethane, trichloroethane, trichlorethylene, loose water-saving washing network water, open water, wash water, and days that water, rust agent, to water-logging, washing machine water, decontamination water, n-butyl alcohol, isopropyl alcohol, ethanol, industrial alcohol, car-washing water, washing machine water, clean lines of water, cleaning machine water, fire water, paint remover, fungicides, antifreeze water, chloroform, grinding fluid , diluent, release agent, dehydration agent substantial industrial solvents.

主要经营产品 A类：化工溶剂白电油、甲苯、二甲苯、四甲苯、凡立水、乙脂、丁脂、丙酮、丁酮、环己酮、防白水、二氯甲烷、三氯乙烷、三氯乙烯、松节水、洗网水、开油水、洗面水、天那水、除锈剂、去渍水、洗枪水、去污水、正丁醇、异丙醇、乙醇、工业酒精、洗车水、洗机水、抹线水、抹机水、火水、脱漆剂、杀菌剂、防冻水、哥罗仿、研磨液、稀释剂、脱模剂、脱水剂等大量工业溶剂。

Then two star-shaped oligomers with designed molecular weights 5000 g mol-1 and 10000 g mol-1, respectively, were synthesized from D, L-lactide and glycolide as raw materials and pentaerythritol as initiator under catalysis of dibutyltin oxide.

以合成的丙交酯和乙交酯为原料，季戊四醇为引发剂，氧化二丁基锡为催化剂合成出设计分子量为5000和10000两种预聚物。

Results Six compounds were isolated and identified as:5α,8α-epidioxy-(22E,24R)-ergosta-6,22-dien-3β-ol,scopoletin,isofraxidin,p-hydroxy benzaldehyde,3,4,5-trimethoxy benzoic acid,protocatechuic acid ethyl ester...

结果得到6个化合物，分别鉴定为：5α，8α表二氧(22E，24R)麦角甾6，22二烯3β醇、东莨菪素、异秦皮啶、对羟基苯甲醛、3，4，5三甲氧基苯甲酸、原儿茶酸乙酯。结论化合物Ⅰ～Ⅵ均为首次从该属植物中分离得到。

In order to obtain versatile ulitity of host molecules, three new chiral calix [4] crown ethers containing aza, thio atoms bearing two chiral sites provided by -cysteine ester were synthesized by the condensation of calix [4] arene diacid dichloride with oligoethylene glycol bridged bis-amino acid methyl ester. All new compounds were characterized by NMR, MS and elemental analysis.

以-半胱氨酸为手性源，利用多甘醇二氯醚在碱性条件下对半胱氨酸巯基进行烷基化反应，成功地合成了多甘醇醚链桥联的半胱氨酸衍生物，醚化反应后，在高度稀释条件下与对叔丁基杯[4]芳烃二乙酰氯进行双功能基缩合反应成功地合成了新型的手性杯[4]含氮、硫杂冠醚，并利用〓H NMR、MS等谱图手段对其结构进行了表征。

The resin which was synthesized by the materials of hydroxy silicone oil , 1, 6-hexamethylene diisocyanate, tolylene diisocyanate, pentaerythritol triarylate and 2-hydroxy ethyl acrylate is able to cure rapidly at room temperature by UV.

本实验采用溶液聚合的方法，以端羟基硅油、甲苯二异氰酸酯、六亚甲基二异氰酸酯、丙烯酸—2—羟基乙酯和季戊四醇三丙烯酸酯为原料制备出了新型能够进行快速固化、高效的三官能度封端的光固化反应体系。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。