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We investigated constituent of triterpenoid saponins ofAlbizzia, two new compounds together with two known compounds were isolated from Albizzia julibrissin Durazz. by using column chromatography (macroreticular resin, silica gel, Sephadex gel, reverse phase silica gel),preparative HPLC methods et al.On the basis of spectroscopic analysis, including IR,ESI-MS,~1H-NMR,~(13)C-NMR,HMBC,HMQC,~1H-~1HCOSY and chemical methods, the structure of two new compounds were identified as 3 - O -[β-D-xylopyranosyl(1→2)-β-D-fucopyranosyl (1→6)-β- D -2- deoxy - 2 - acetoamidoglucopyranosyl] -21-O-[(6S)-2- trans- 2,6-dimethyl - 6 - O-β- D - quinovopyranosyl -2,7- octadienoyl] - acacic acid- 28 - O-β-D-glucopyranosyl(1→3)[α-L-arabinofuranosyl(1→4)]-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside acacic acid 3- O -β- D- glucopyranosy(1→3)-β- D- fucopyranosl(1→6) [β-D- xylopyranosyl (1→2)]-β-D-glucopyranoside ;two known compounds were acacic acid lactone 3- O -β-D- xylopyranosyl-(1→2)-β-D-fucopyranosl (1→6)- 2-deoxy -2 -acetoamido -β-D- glucopyranoside ; acacic acid lactone 3- O-β-D-xylopyranosyl(1→2)-α-L- arabinopyranosl (1→6)- 2- deoxy - 2- acetoamido -β-D-glucopyranoside . The study lays chemical foundation and chemical reference substance for enhancing quality standard of Albizzia julibrissin Durazz.

本研究论文在综述国内外对合欢属Albizzia三萜皂苷化学成分和药理作用研究进展的基础上,利用传统植化分离手段和现代分离技术,包括大孔树脂、硅胶、葡聚糖凝胶、反相硅胶等柱色谱,制备高效液相色谱法等技术从中药合欢皮中分离得到了4个化合物,其中,2个新化合物和2个己知化合物,并进一步通过现代分析技术IR,ESI-MS,~1H-NMR,~(13C-NMR,HMBC,HMQC,~1H-~1HCOSY等和化学方法鉴定了2个新化合物的结构分别是:3-O-[β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖基]-21-O-[(6S)-2-反式-2,6-二甲基-6-O-β-D-吡喃鸡纳糖基-2,7-辛二烯酸基]-金合欢酸-28-O-α-L-呋喃阿拉伯糖基(1→4)[β-D-吡喃葡萄糖基(1→3)]-α-L-吡喃鼠李糖基(1→2)-β-D-吡喃葡萄糖苷,金合欢酸3-O-β-D-吡喃葡萄糖基(1→3)-β-D-吡喃夫糖基(1→6)[β-D-吡喃木糖基(1→2)]-β-D-吡喃葡萄糖苷;2个已知化合物结构分别是:金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷,金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-α-L-吡喃阿拉伯糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷。

My company can provide pesticide, medicine, veterinary medicine intermediates, have 48 kinds of products (p-Bromo-p-Bromotoluene bromoform 1 - bromo-heptane Triethyl Citrate 1,2,3 - three Bromopropane 3 - Chlorine -4 - fluoro bromobenzene Bromotoluene ethylbenzene 4 - bromo -2 - bromo-ethyl-Chloroaniline 2 - bromo--5 - chloro-toluene 3 - bromo-C methyl 1,6 - dibromo-hexane 1 - bromo --4 - p-methoxy benzaldehyde o-bromo-acetic acid propyl bromide p-fluorotoluene dodecane four bromoethane of iodine bromide toluene tert-butane Tributyl Citrate 2 - bromo-p inter - Hydroxybenzaldehyde bromine butane 2 - bromo-propionic acid bromide veratryl aldehyde inter-bromo-trifluoro-n-hexane of toluene on Bromoxynil Bromotoluene toluene ethylbenzene o-bromophenol bromide Cyclohexane Cyclopentane bran bromate bromide Malay Dibutyl Ethyl Lactate Propylene between bromine bromine bromine between aniline o-anisidine o-fluorophenol difluorobenzonitrile to aminobenzaldehyde Bromotoluene aniline on Bromobenzaldehyde Bromotoluene acid) expressed the hope that customers contact us!

我公司可提供农药,医药,兽药中间体,有四十八种产品(对溴苯酚对溴甲苯溴仿 1-溴庚烷柠檬酸三乙酯 1,2,3-三溴丙烷 3-氯-4-氟溴苯对溴乙苯 4-溴-2-氯苯胺溴乙酸乙酯 2-溴-5-氯甲苯 3-溴丙酸甲酯 1,6-二溴己烷 1-溴-4-硝基苯邻甲氧基苯甲醛溴乙酸丙酯对氟甲苯溴代十二烷对碘甲苯四溴乙烷溴代叔丁烷柠檬酸三丁酯 2-溴氯苯间羟基苯甲醛溴丁烷 2-溴丙酸黎芦醛溴已烷间溴三氟甲苯对溴苯腈对溴乙苯邻溴甲苯溴代环已烷溴代环戊烷糠溴酸马来酸二丁酯溴丙烯乳酸乙酯间溴苯胺间溴苯甲醚邻氟苯酚邻氟苯腈对氨基苯甲醛对溴苯胺对溴苯甲醛对溴苯甲酸)希望广大客户与我司联系!

The main products are: HH-01 fungicides HH-02 organic dispersant HH-03 cationic starch Wood HH-04 cationic starch Department HH-05 modified starch warp sizing agents also sell German Baker Chemical Co., Ltd. Main Products Defoamer series product: E640, T50 Surface Sizing Agent: A281, A288, K532, pesticides / medicine / veterinary medicine a variety of intermediate products (p-Bromo-p-Bromotoluene bromoform 1 - bromo-heptane triethyl citrate 1,2, 3 - Three Bromopropane 3 - chloro -4 - fluoro bromobenzene Bromotoluene ethylbenzene 4 - bromo -2 - bromo-ethyl-Chloroaniline 2 - bromo--5 - chloro-toluene 3 - bromo-methyl 1,6 C - Dibromo Hexane 1 - bromo -4 - nitrobenzene o-methoxy benzaldehyde acid propyl bromide p-fluorotoluene bromo dodecane toluene four of iodine bromide bromoethane three citric acid tert-butane n-butyl 2 - bromo-p-bromo-butane Hydroxybenzaldehyde between 2 - bromo-propionic acid bromide veratryl aldehyde inter-bromo-trifluoro-n-hexane of toluene on Bromoxynil Bromotoluene toluene ethylbenzene o-bromophenol bromide bromide Cyclohexane Cyclopentane bran acid dibutyl maleate Ethyl Lactate Propylene between bromine bromine bromine between aniline o-anisidine o-fluorophenol difluorobenzonitrile to aminobenzaldehyde Bromotoluene aniline on Bromobenzaldehyde Bromotoluene acid) and other relevant units have been in substantial promotion, and client set up a good relationship of cooperation has been the user's praise.

现主要产品:HH—01杀菌剂 HH—02有机分散剂HH—03阳离子淀粉 HH—04木署阳离子淀粉 HH—05 经纱上浆变性淀粉同时还代理销售德国贝克化学公司系列产品主要产品消泡剂:E640 、T50 表面施胶剂:A281、A288 、K532,农药/医药/兽药中间体多种产品(对溴苯酚对溴甲苯溴仿 1-溴庚烷柠檬酸三乙酯 1,2,3-三溴丙烷 3-氯-4-氟溴苯对溴乙苯 4-溴-2-氯苯胺溴乙酸乙酯 2-溴-5-氯甲苯 3-溴丙酸甲酯 1,6-二溴己烷 1-溴-4-硝基苯邻甲氧基苯甲醛溴乙酸丙酯对氟甲苯溴代十二烷对碘甲苯四溴乙烷溴代叔丁烷柠檬酸三丁酯 2-溴氯苯间羟基苯甲醛溴丁烷 2-溴丙酸黎芦醛溴已烷间溴三氟甲苯对溴苯腈对溴乙苯邻溴甲苯溴代环已烷溴代环戊烷糠溴酸马来酸二丁酯溴丙烯乳酸乙酯间溴苯胺间溴苯甲醚邻氟苯酚邻氟苯腈对氨基苯甲醛对溴苯胺对溴苯甲醛对溴苯甲酸)等在相关单位得到了大量推广,与客户建立了良好的合作关系,得到了用户的赞誉。

Principal cmponent analysis was used for 34 aroma components,and the relsult showed that the 34 aroma components could be represented asssumably by butanoic acid methylester, butanoic acid ethylester, propylalcohol, butylalcohol, 2,3-butanediol, decanoic acid ethylester, ethyl 4-hydroxybutanoate, eugenol, palmitic acid ethylester, 9-Octadeceroic acid ethylester.

对定量的34种香气物质进行主成分分析,结果表明:由丁酸甲酯,丁酸乙酯,丙醇,丁醇,2,3-丁二醇,癸酸乙酯,4-羟基丁酸乙酯,丁子香酚,棕榈酸乙酯,油酸乙酯基本可以代表本试验所定量出的34种香气物质呈现出的香气物质所构成的风味特征。

Aroma components of Hexylalcohol,Benzeneethanol,Butylalcohol,Pentylalcohol, ethyl acetate, Lactic acid ethylester, Butanedioic acid,diethylester, isopentylacohol acetate, acetic acid hexylester, acetic acid phenethylester, hexanoic acid ethylester, ethyl caprylate, decanoic acid ethylester, octanoic acid, linalool andα-terpineol were identified in former kiwi wine reports.

本试验首次在猕猴桃酒中发现了油酸乙酯,棕榈酸乙酯,9-癸烯酸,肉豆蔻酸乙酯,月桂酸乙酯,香茅醇,法呢醇,异薄荷酮香气物质,目前国内外资料中报道的猕猴桃酒香气物质—己醇,苯乙醇,丁醇,戊醇,乙酸乙酯,乳酸乙酯,琥珀酸二乙酯,乙酸异戊酯,乙酸己酯,乙酸苯乙酯,己酸乙酯,辛酸乙酯,癸酸乙酯,辛酸,芳樟醇,α-松油醇等均在本试验研究中也检测出,并得到证实。

A series of ABEPS were synthesized from long chain fatty acids, benzene, polyglycol and 1, 3-propane sultone by the procedure of Friedel-Crafts acylation, Huang-Minlon reduction, Williamson and sulfonation reaction, and these compounds had never been reported in the past time.

以长链羧酸、苯、多缩乙二醇和丙烷磺内酯为初始原料,依次经Friedel-Crafts酰基化反应、Huang-Minlon还原、Blank反应、Williamson成醚以及磺化反应等过程,合成了系列未见报道的ABEPS。

In addition, we used a modified MTT 3-(4,5-dimethylthiazol-2-yl-2,5-diphenyltetrazolium bromide assay to examine cell proliferation by dissociating the cell/alginate constructs using trisodium citrate and trypsin/EDTA.

此外,我们用改良的MMT测定被枸橼酸钠-胰蛋白酶-乙二胺四乙酸分离细胞结构的细胞增殖情况。

Acetic acid equipments using material in PTA, PVA, aldehyde oxidation and methyl alcohol carbonyl synthetic four plants in chemical industry and chemical fibre production are analyzed.

对化工化纤生产中的精对笨二甲酸、聚乙烯醇、乙醛氧化生产醋酸与甲醇羰基合成醋酸4个装置醋酸设备用材进行分析,并对含Cl-、含Br-、含I-的醋酸及含Cl-的甲乙混酸对不锈钢、铜、钛与镍基合金等金属材料腐蚀原因作了讨论。

Sythesis and application of chlorostyrene-DVB strongly acidic cation exchange resin ;2. For this study,a series of poly( p -amino styrenes) with various amounts of supported hydrogen chloride,and a series of strongly acidic cation exchange resin s with various exchange capacity were synthesized,and their catalytic property for ketalization of cyclohexanone and glycol were investigated.

通过测定固载了不同量的氯化氢的聚和不同交换量的强酸性阳离子交换树脂催化的环己酮与乙二醇的缩酮化反应缩酮的收率,研究了聚合物固体酸催化剂的疏水性对其催化缩酮化反应性能的影响;发现在一定范围内增加催化剂的疏水性,可提高缩酮化反应的收率。

It is made generally with mixed salt of triethanolamine and ammonium hydroxide, twelve-acid isopropyl alcohol amides, for malde-hyde, polyvinyl chloride, wool oil, spice, pigment and water as raw materials.

一般采用硫酸脂肪醇的乙三醇胺与氢氧化胺的混合盐、十二酸异丙醇酰胺、甲醛、聚氧乙烯、羊毛脂、香料、色料和水作为原料。

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