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These compounds are of substantial interest both inviewpoints of theory and practical applications, mainlyunder the stimulus to achieve synthetic models either foractive sites of iron-sulfur proteins or for transitionmetal catalysts. This thesis describes the synthesis, structures andconformations of 51 new iron-sulfur cluster complexes,which have been characterized by elemental analysis andstandard spectroscopic methods. In addition, single-crystalX-ray diffraction analyses were performed for 4 representa-tive new compounds. Reactivities of μ-〓 with mono- and di- Grig-nard reagents derived intermediates toward various organicelectrophilic substrates were studied, along with complexa-tion of arynyl-containing iron-sulfur clusters by 〓Thus, several bridged, non-bridged, monomeric, dimeric,homonuclear, heteronuclear iron-sullfur and iron-sulfur co-balt-carbon cluster complexes were synthesized. A novelreaction and convenient route for the synthesis in highyield of tetranuclear iron complexes 〓 containing atetracoordinated sulfur atom was discovered, whereas aplausible mechanism based on experimental results was propo-sed for the formation of the new cluster type.

鉴于有机铁硫原子簇化学在基础理论发展和应用方面的重要意义,因此我们开展了这一课题的研究,并取得以下主要成果: 1、本文共合成了51个新有机铁硫及含钴碳簇基的有机铁硫原子簇配合物,除用元素分析,NMR,IR,MS法表征其结构和构象外,还用X-光衍射技术测得四个代表性配合物的单晶结构和构象; 2、我们业已发现炔基Grignard试剂同〓可形成一种&开环&与&闭环&中间物的平衡混合物,研究该平衡混合物同各种亲电试剂的反应; 3、研究发现了一种可高产率地形成〓含〓四配位硫挛合簇的新化学反应并对此反应提出了—种有趣的反应机理; 4、首次由1,4-二溴丁烷双Grignard试剂与〓制得一种新型铁硫簇双硫阴离子活性中间体,并进而研究了它的亲核反应性能; 5、找到了通过〓的光化学反应来合成簇合物〓-〓的一条有实用价值的新路线。

The study results of sediments from Guangzhou water body showed that the main crystalline minerals in sediments were quartz, kaolinite and hydromica, and heavy metals were associated mainly with residual phase, organic phase and iron oxides phase.

而且解吸和吸附过程不是完全可逆的;(6)广州城市水体污染沉积物中的结晶矿物相以石英、高岭石和水云母类矿物为主,重金属元素Pb、Zn、Cu、Ni、Cr、Mn主要以残渣态、有机态和氧化铁结合态存在。

There are different content of Ni, Fe deposed on waste catalysts, which make them receive inequivalent force in magnetic field, catalysts with high content are selected from non- or lower magnetic active mass.

该磁分离方法主要是利用镍、铁等重金属元素在催化剂上沉积量的不同导致它们在磁场中所受的磁力大小不同,可从非磁性或弱磁性催化剂颗粒中选出吸附了较多金属的磁性催化剂颗粒。

This research mainly adopts experiment, survey questionnaire, interview method, the experimental chemistry of several typical topic such as "separation of iodic element of kelp and inspection" and the properties of aluminum compounds "toothpaste and match in some ingredients" sodium nitrite and identification of salt experimental subjects were studied.

本研究主要采用实验法、调查问卷法、访谈法,对《实验化学》中的几个典型课题如&海带中碘元素的分离及检验&&铝及其化合物的性质&&牙膏和火柴头中某些成分的检验&&亚硝酸钠和食盐的鉴别&等实验课题进行研究。

In this paper, preservation characteristics of the viviparous propagule of Kandelia candel and Aegiceras corniculatum, change of nutrient content and caloric values of several mangroves species during winter, cold resistance and salt resistance and the effects of supplemental calcium on the seedling of three mangrove species were studied, the main results showed as follows

本文进行了红树植物对低温和盐度的某些适应生理生态学研究,主要讨论胎生繁殖体的贮藏特性、不同盐度和低温下生理生态指标的变化和补充钙的效应,以及这些处理下,植物体中6种元素和热量的变动特性等。

Main products: DNA Energy, one kind of drinking-water with important microelements and special hexagon structure, which can infiltrate into the karyon quickly.

主要产品:基因能量液,一种富含生命动力元素的六环形结构饮用水,能快速渗透人体细胞核,恢复亚健康。

Software on the horoscopes of the procedure are as follows : 8th Grand Canal, the element score and the preference for God, said kurung life, ancient poems on life Stephen poor coin and three fate will be made on life, the life of uncertainty, life major hurdle, Guiguzi On life unfulfilled by the theory of life, life on dry days, On the date when the mission acquired remedies, character, marriage, siblings, children,'s impossible for the astrologer, fame career, health status, ancestral parents, 80 Bradley leg.

软件的程序如下:8大运河,元素得分占星和上帝的偏爱,说库伦格生活,生命的古诗词斯蒂芬穷人命运的硬币和三将一生的,不确定的生活,生活主要障碍,在生活的生命理论,在干燥的日子生命兑现鬼谷子之日,当团购置的占星家,名利的职业,健康状况,祖先的补救办法,性格,婚姻,兄弟姐妹,子女,的父母不可能80布拉德利腿。

This paper reports the effect of added copper on microbial population in lateritic rice soil.

重金属元素对土壤微生物的作用,国内外已进行了不少研究,国内在这方面的研究则主要体现于&六五&和&七五&攻关项目中的土壤环境容量研究。

Comparison studies on mineralization characteristics of the 414 ore deposit with Limu orefield indicate some similarities in mineralization ,which were resulted from the similarities in evolution of the rare metal-bearing mag-matic rocks.

江西414矿和广酉栗木矿是我国目前钮的主要原料基地。在成固类型上它们同属稀有金属花岗岩型矿床,成矿元素除袒之外,还伴生锯、锡或埋。

There is representative meaning to researching the action of Cr and As in loessial soil.(3) By experiments the paper reveals purification mechanism and ability and its influencing factors of soil to Cr and As.

2分析了由于农事和水事活动所发生的土层入渗水中的污染元素,确定了毒性强、数量大、易迁移的铬、砷作为主要研究对象,研究其在黄土类土中的行为作用有代表性意义。

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And Pharaoh spoke to Joseph, saying, Your father and your brothers have come to you.

47:5 法老对约瑟说,你父亲和你弟兄们到你这里来了。

Additionally, the approximate flattening of surface strip using lines linking midpoints on perpendicular lines between geodesic curves and the unconditional extreme value method are discussed.

提出了用测地线方程、曲面上两点间短程线来计算膜结构曲面测地线的方法,同时,采用测地线间垂线的中点连线和用无约束极值法进行空间条状曲面近似展开的分析。

Hey Big Raven, The individual lies dont matter anymore - its ALL a tissue of lies in support of...

嘿大乌鸦,个别谎言的事不要再-其所有的组织的谎言,在支持。