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In this research project, we have got a series conclusions:(1) there is no excess argon in the high-pressure white micas being in the orthogneiss;(2) The distribution of excess argon in eclogite is positive correlative with the ratio of Mg/, but negative with the ratio of Na/;(3) The in-situ analyses by using the method of laser probe 39Ar-40Ar show that the age radius from central to margin in a single grain of high-pressure white mica in eclogite;(4) There is no any evidence to prove that the excess argon in eclogite comes from fluid;(5) The excess argon in eclogite inherited from primitive rock during high-ultra high pressure metamorphism;(6) There is no excess argon in the eclogite when its surrounding rock is carbonate.

本项目用综合手段,研究了高压白云母中过剩氩的来源、赋存、分布与岩性、产状、矿物元素和矿物显微结构之间的相关关系,以确定过剩氩在高压白云母中赋存的主要控制因素。初步得出了以下结果:1、高压变质的正片麻岩中的白云母中不含过剩氩;2、高压白云母中过剩氩的赋存和Mg/有着正相关关系,而和Na/呈负相关;3、激光微区氩-氩分析表明,榴辉岩中的单颗粒多硅白云母存在年龄梯度;4、初步否定了高压白云母中过剩氩来自于流体的说法;5、初步认定,榴辉岩中多硅白云母中过剩氩主要是在高压-超高压变质过程中由内部继承的;6、在阿尔金及柴北缘等地围岩为碳酸岩的榴辉岩中的高压白云母不含过剩氩。上述研究结果将推动过剩氩成因研究走向深入。

The most parts of thesis as follows:1. Five symmetrical intra-molecular charge transfer oligomeric phenylene vinylene light emitting materials were designed and synthesized using oligomeric phenylene vinylene as a framework.2. The structures of target molecule were characterized by ~1HNMR,~(13)CNMR, IR, MS and element analysis.3. In order to study the influence of the location and numbers of electron-donor and electron-acceptor on their photoelectric performance by changing length of OPV chain, the UV spectra and fluorescence spectra of target compounds has been compared. We have researched into main factors effecting on material emitting red-shift; organic electroluminescence device was prepared using the compound P4. The capability of eletroluminescence was researched.4. The photoelectric properties of P4 was explained by quantum chemical calculation (the Gaussian 98 quantum chemistry program). It is greatly contributed know the whole process of charge transfer to guide the design of red emitters.

本文研究的内容主要包括以下部分:(1)设计并合成5个对称的以齐聚苯乙烯类为骨架的分子内电荷转移型齐聚苯乙烯类发光材料;(2)通过IR,MS,~1H-NMR,~(13)C-NMR和元素分析对所合成的目标化合物进行表征;(3)通过对目标化合物的紫外光谱和荧光光谱比较分析,研究改变OPV的长度,电子给体和电子受体的位置及数量对其光电性能的影响,探讨材料发射红移的主要因素;选取性能良好的目标化合物P4制备成OELD器件,对其电致发光性能进行研究;(4)运用Gaussian98量子化学程序包,采用量子化学方法对目标化合物P4的光电性能从理论加以解释,进一步认识荷移跃迁的整个过程,为红光材料的设计加以指导。

The pillow lava, with affinity of MORB, plots in the field of MORB and IAT, suggesting that the Yushigou ophiolite formed in a tectonic setting like the Middle Ocean Ridge and then were changed by volcanic arc magmatism.

地幔橄榄岩主要是方辉橄榄岩,其主要氧化物成分较为单一,具LREE富集、Eu亏损的U形REE配分模式,亏损强不相容元素;枕状熔岩具典型MORB特征,在构造判别图解上位于MORB和IAT区域,指示蛇绿岩可能形成于类似于洋中脊的构造环境,并受到火山弧岩浆作用的影响。

The temperature of basin was influenced greatly by matle heat conduction, magmatic heat and radioelement decay during the time of Early Permian-Late Permian rifting, while in the down-warped basin from the late stage of Late Permian to the present the temperature has been greatly affected by geothermal gradient and tectogenetic transition heat.

认为早二叠世-晚二叠世早期裂谷作用阶段盆地温度主要受地幔热传导、岩浆体热和放射性元素衰变的影响,晚二叠世晚期至今坳陷盆地阶段主要受地热增温率和构造运动转化热的影响。

Through analyses of ore properties, Huayuan manganese ore is determined to be phosphorus—rich and iron—poor rhodochrosite.

有害元素磷主要以磷灰石独立矿物形式产出,粒度在3~20μm之间,矿样粒度为—45μm时,磷灰石主要以游离形态产出,被包裹在碳酸锰矿物中的磷灰石相对锰矿物明显减少。

The Au background values are generally high in the amphibolitic rocks of the Archean metamorphic series, which is the main source bed of the region. Amphibolite facies is the major Au-bearing lithofacies.

太古宙变质岩系中的&角闪质&岩石的金元素背景值普遍较高,为本区的主要矿源层,角闪岩相是含金的主要岩相。

Or FR4 PCB, bromide exsited mainly in pyrolysis gas and gas products mainly consisted of CO, CO2, propylene, 2-methacrylate, bromomethane, and a small amount of acetone, C1-C3 halogenation alkyls. The pyrolysis gas could be reclaimed as fules after debromide treatment. Pyrolysis liquid products consisted of 8.333% water and 91.667% oil component.

R4板中溴元素主要存在于气体产物中,气体产物主要为CO、CO2、丙烯、2-甲基丙烯、溴甲烷以及其他小分子烯烷烃产物,气体产物可通过除溴无害化处理作可燃气回收;液体产物中含有8.333%的水和油质成分。

The central part of the ring structure may be either carbide with a high W content or carbonitride with a high Ti content.

环状结构心部可以是以钨等重金属元素为主要成分的碳化物,也可以是以钛为主要成分的碳化物和碳氮化物。

These data were used to infer the molecular formula and the elemental compositions of all the fragmental ions through software interpretation and, by further applying fragmentation regularities of mass spectrometry, the majority of ions were fully assigned. A base peak at m/z 402 in the mass spectrum was found as the molecular ion. The fragments were created mainly from the fragmentations of the tetrahydrofuran rings and the hydroxyl group. The most fragment products contain the dimethoxy phenyl group.

利用这些数据通过软件导出了分子式和所有碎片离子的元素组成,由此进一步根据质谱裂解规律对石梓醇分子的电子轰击质谱的主要裂解碎片给出了完全的归属,质谱中发现基峰为分子离子峰(m/z402),裂解碎片主要来自双骈四氢呋喃环的裂解和羟基引起的裂解,绝大部分裂解产物包含二甲氧基苯基基团。

According to the variation in the components of intermediateacid igneous rocks coming from the lower crust, it is possible to restrain the depth of the source area and the minimum thickness of the crust, and thus to provide important information for the study of the deep process of the continental intraplate mineralizationGlobally, many world level porphyry copper deposits and metallogenic systems formed by hypabyssal hot liquid have their close relationship with the synchronous adakite in spacetime and genesis; domestically, the adakitelike rocks have been identified to be related to the metallogenesis in the main metallogenic areas in ChinaThe recognition of adakitelike rocks having no relationship with the process of subduction makes it possible to construct a metallogenic model of continental intraplate porphyry metal deposits by combining other geological evidences, and this model is totally different from the metallogenic model of porphyry copper deposits with Bsubduction setting constructed by Sillitoe (1972)The existence of adakitelike rocks may be the necessary condition but not the sufficient one for forming the largescale porphyry deposits and the hypabyssal hotliquid deposits, whose metallogenic elements mainly came from the mantleThe metallogenic potential of adakitelike rocks is achieved by the entering of the mantle material, and the metallogenic specialization of adakitelike rocks is decided by the distribution characteristics of the metallogenic elements in the upper mantleAn important reason for the adakitelike magma related to subduction being advantageous to mineralization is that there were abundant high pressure and high temperature liquid coming from the subducted platepieces and the magma of high fO2 coming from the melting of subducted platepiecesHowever, for those adakitelike rocks, whose occurrence has continental plate background but does not relate to the subduction, their metallogenic mechanism is not clear yetBased on the concept of modern mineral exploration and combined with the analysis of integrated geological information, we may better realize the practical prospecting significance of the adakitelike rocks

根据起源于下地壳的中酸性岩浆岩的成分变化,可以约束其源区深度以及地壳最小厚度,为大陆板内成矿作用的深部过程研究提供重要信息。全球范围内,许多世界级斑岩铜矿和浅成热液矿化系统与同期的埃达克质岩存在密切的时空与成因联系,在国内主要成矿区带也识别出与金属成矿作用有关的埃达克岩。与俯冲过程无关的埃达克质岩的识别,使我们有可能结合其他地质证据构建完全不同于Sillitoe(1972)B型俯冲环境的斑岩铜矿成矿模式的大陆板内斑岩型金属矿床成矿模式。对于规模巨大、矿质主要源自地幔的热液矿床的形成,埃达克岩可能是必要条件,但不是充分条件。埃达克岩的成矿潜力通过地幔物质加入而获取,埃达克岩的成矿专属性由上地幔成矿元素分布特征决定。与俯冲有关的埃达克质岩浆之所以有利于成矿,重要的原因是存在大量来自俯冲板片的高压、高温流体以及俯冲板片熔融形成高氧逸度(fO2)的熔体,但产出在大陆板内背景、与俯冲无关的埃达克岩的成矿机制还不清楚。根据现代资源勘查理念,结合综合地质信息分析,埃达克质岩具有实际找矿意义。

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